SUPPORTING INFORMATION
|
|
- Jonas Green
- 6 years ago
- Views:
Transcription
1 Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 SUPPORTING INFORMATION Synthesis, Characterization and Biological Activity of Fluorescently Labeled Bedaquiline Analogues Jeroen A. Rombouts, Richard M.P. Veenboer, Cristina Villellas, Ping Lu, Andreas W. Ehlers, Koen Andries, Anil Koul, Holger Lill, Eelco Ruijter, Romano V. A. Orru, Koop Lammertsma, Dirk Bald,* J. Chris Slootweg* TABLE OF CONTENTS Purity Analysis of Fluorescent Bedaquiline Derivatives using HPLC Photochemical Characterization of Fluorescent Bedaquiline Derivatives Photochemical Characterization of Unbound Fluorophore B2 NMR Spectroscopy Data S2 S3 S4 S5 S1
2 Purity Analysis of Fluorescent Bedaquiline Derivatives using HPLC Using a HPLC system equipped with a Dr. Maisch chiral stationary phase, the presence of unreacted Bedaquiline was investigated. A 95:5 heptane:isopropanol solvent system at 0.7 ml min -1 flow rate, using a fixed column temperature of 25 C was found to give good resolution in time between peaks. A calibration curve was prepared in duplo using dilutions of Bedaquiline in the concentration range [0.000, 0.005, 0.025, 0.050, 0.250, 0.500] mol ml -1 to give a total of 12 data points, all within the linear response regime of the instrument. Fitting the instrument response I to the linear equation I = ac + b using linear regression gave I = C with C the Bedaquiline concentration (in mol ml -1 ) and coefficient of determination R 2 = 99.92%. This linear equation has been used to calculate the concentration of unreacted Bedaquiline in the fluorescently labeled compounds. Results are as follows: Calculated concentration Bedaquiline freebase in C1: mol%, n = 4, st. dev. = mol% Calculated concentration Bedaquiline freebase in C2: mol%, n = 4, st. dev. = mol% Retention times under the given HPLC parameters are: Retention time Bedaquiline free base (from J&J, see General Information): 5 minutes 42 seconds Retention time Bedaquiline-butynoxy-BODIPY, C1: 15 minutes 15 seconds Retention time Bedaquiline-pentynoxy-eg 4 -BODIPY, C2: 63 minutes 8 seconds S2
3 Photochemical Characterization of Fluorescent Bedaquiline Derivatives Determination of absorption and emission spectra was performed using a Shimadzu UV-2501PC spectrophotometer (absorption measurements) and a Jobin Yvon Fluorolog spectrophotometer (fluorescence measurements). The solvent used was degassed, HPLC grade acetonitrile. Using measurements on an external standard (Aqueous fluorescein in 0.1 M NaOH), the quantum yield of fluorescence for C1 and C2 was calculated according to the following formula, where is quantum yield, Int is the fluorescence intensity (integrated area under curve of emission intensity, in arbitrary units), A is the sample absorbance at the exciting wavelength and is the refractive index of the solvents used. Superscript ref refers to values for the external standard. Absorbance measurements were performed in the linear regime of the spectrophotometer; emission measurements were checked to avoid emission detector saturation. = ref * Int Int ref * A ref A * ref Table 1: Calculation of Quantum Yield of fluorescence sample for C1 and C2, in acetonitrile sample ref Int (au) Int ref (au) A ref A ref C C To assess the usability of C1 and C2 in protic media, the quantum yield of fluorescence was determined using methanol as the solvent. For these experiments, aqueous Fluorescein 27 (CAS , obtained from Exciton Dye company) was used as external fluorescence standard. For completeness, normalized absorption and emission spectra in methanol are shown in Figure 1. Table 2: Calculation of Quantum Yield of fluorescence sample for C1 and C2, in methanol sample ref Int (au) Int ref (au) A ref A ref C C abs nm em nm QY C C Figure 1: Normalized absorption and emission wavelengths for C1 and C2, recorded in methanol. The inset tabulates absorption and emission wavelength maxima and the quantum yield of fluorescence. S3
4 Photochemical Characterization of Unbound Fluorophore B2 Quantum yield of fluorescence of compound B2 was measured to verify that the fluorophore properties are not in any way modified by the covalent attachment of Bedaquiline. For this experiment, aqueous Fluorescein 27 (CAS , obtained from Exciton Dye company) was used as external fluorescence standard. For ompleteness, normalized absorption and emission spectra of B2 recorded in acetonitrile are shown in Figure 2. Table 3: Calculation of Quantum Yield of fluorescence sample for B2, in acetonitrile sample ref Int (au) Int ref (au) A ref A ref B abs em QY nm nm B Figure 2: Normalized absorption and emission wavelengths for B2, recorded in acetonitrile. The inset tabulates absorption and emission wavelength maxima and the quantum yield of fluorescence. S4
5 NMR Spectroscopy Data, 1H NMR; 1H NMR Spectrum of 4-(but-3-ynoxy)benzaldehyde (A1) S5
6 1H NMR Spectrum of Butynoxy-BODIPY (B1) S6
7 1H NMR Spectrum of Bedaquiline-butynoxy-BODIPY (C1) S7
8 1H NMR Spectrum of Pentynoxy-eg4-OH S8
9 1H NMR Spectrum of Pentynoxy-eg4-benzaldehyde (A2) S9
10 1H NMR Spectrum of Pentynoxy-eg4-BODIPY (B2) S10
11 1H NMR Spectrum of Bedaquiline-pentynoxy-eg4-BODIPY (C2) S11
12 NMR Spectroscopy Data, 13C NMR; 13C NMR Spectrum of 4-(but-3-ynoxy)benzaldehyde (A1) S12
13 13C NMR Spectrum of Butynoxy-BODIPY (B1) S13
14 13C NMR Spectrum of Bedaquiline-butynoxy-BODIPY (C1) S14
15 13C NMR Spectrum of Pentynoxy-eg4-OH S15
16 13C NMR Spectrum of Pentynoxy-eg4-benzaldehyde (A2) S16
17 13C NMR Spectrum of Pentynoxy-eg4-BODIPY (B2) S17
18 13C NMR Spectrum of Bedaquiline-pentynoxy-eg4-BODIPY (C2) S18
A Fluorescence Turn-On Sensor for the Detection of Palladium Ions that Operates Through In-Situ Generation of Palladium Nanoparticles
This journal is The Royal Society of Chemistry 214 Supporting Information for A Fluorescence Turn-On Sensor for the Detection of Palladium Ions that Operates Through In-Situ Generation of Palladium Nanoparticles
More informationPhotoinduced Guest Transformation Promotes Translocation of Guest from Hydroxypropyl-β-Cyclodextrin to Cucurbit[7]uril
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Photoinduced Guest Transformation Promotes Translocation of Guest from Hydroxypropyl-β-Cyclodextrin
More informationJ- vs. H-type assembly: pentamethine cyanine (Cy5) as near IR chiroptical. reporter
S1 Supporting Information: J- vs. H-type assembly: pentamethine cyanine (Cy5) as near IR chiroptical reporter Larysa I. Markova, a,b Vladimir L. Malinovskii, a Leonid D. Patsenker b and Robert Häner* a
More informationA mitochondria-targeting fluorescent probe for detection of mitochondrial labile Fe(II) ion
Electronic Supplementary Material (ESI) for Metallomics. This journal is The Royal Society of Chemistry 2018 A mitochondria-targeting fluorescent probe for detection of mitochondrial labile Fe(II) ion
More informationA BODIPY-based fluorescent probe for the differential
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 15 Supporting information A BODIPY-based fluorescent probe for the differential recognition of Hg(II)
More informationA Guide to Recording Fluorescence Quantum Yields
Oa~äëíçåd~êÇÉåëIpí~åãçêÉIjáÇÇäÉëÉñe^TN_nIrh A Guide to Recording Fluorescence Quantum Yields Introduction: When a fluorophore absorbs a photon of light, an energetically excited state is formed. The fate
More informationCyanine Dyes as Ratiometric Fluorescence Standards for the Far-Red Spectral Region
Electronic Supplementary Material (ESI) for Photochemical & Photobiological Sciences. This journal is The Royal Society of Chemistry and Owner Societies 2017 Supplementary Information for: Cyanine Dyes
More informationThe photoluminescent graphene oxide serves as an acceptor rather. than a donor in the fluorescence resonance energy transfer pair of
Supplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry 20XX The photoluminescent graphene oxide serves as an acceptor rather than a donor in the fluorescence
More informationELECTRONIC SUPPLEMENTARY INFORMATION (ESI) variable light emission created via direct ultrasonic exfoliation of
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 ELECTRONIC SUPPLEMENTARY INFORMATION (ESI) High quantum-yield luminescent MoS 2 quantum dots
More informationThe ph-responsive behaviour of aqueous solutions of poly(acrylic acid) is dependent on molar mass
Electronic Supplementary Material (ESI) for Soft Matter. This journal is The Royal Society of Chemistry 2016 The ph-responsive behaviour of aqueous solutions of poly(acrylic acid) is dependent on molar
More informationBlending conjugated polymers without phase separation for fluorescent colour tuning of polymeric materials through FRET
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supplementary Information Blending conjugated polymers without phase separation for fluorescent
More informationSupporting information. One-step facile synthesis of novel β-amino alcohol functionalized
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supporting information One-step facile synthesis of novel β-amino alcohol functionalized carbon
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Performance comparison of two cascade reaction models in fluorescence
More informationRed Color CPL Emission of Chiral 1,2-DACH-based Polymers via. Chiral Transfer of the Conjugated Chain Backbone Structure
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Red Color CPL Emission of Chiral 1,2-DACH-based Polymers via Chiral Transfer of the Conjugated
More informationSupporting Information
Supporting Information Photocatalytic H 2 production in aqueous solution with host-guest inclusions formed by insertion of an FeFe-hydrogenase mimic and organic dye into cyclodextrins respectively Xueqiang
More informationElectronic Supplementary Information. Selective detection of Al 3+ and citric acid with a fluorescent amphiphile
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Selective detection of Al 3+ and citric
More informationElectronic Supplementary Material
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Material A Novel Functionalized Pillar[5]arene: Synthesis, Assembly
More informationELECTRONIC SUPPLEMENTARY INFORMATION
Electronic Supplementary Material (ESI) for Photochemical & Photobiological Sciences. This journal is The Royal Society of Chemistry and Owner Societies 2017 ELECTRONIC SUPPLEMENTARY INFORMATION Fabiano
More informationOptical Science of Nano-graphene (graphene oxide and graphene quantum dot) Introduction of optical properties of nano-carbon materials
Optical Science of Nano-graphene (graphene oxide and graphene quantum dot) J Kazunari Matsuda Institute of Advanced Energy, Kyoto University Introduction of optical properties of nano-carbon materials
More informationPhotophysics and redox properties of aza-bodipy dyes with electronwithdrawing
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Photophysics and redox properties
More informationAntibiotic Selectivity for Prokaryotic vs. Eukaryotic Decoding Sites Yun Xie, Andrew Dix, and Yitzhak Tor*
Antibiotic Selectivity for Prokaryotic vs. Eukaryotic Decoding Sites Yun Xie, Andrew Dix, and Yitzhak Tor* Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0358
More informationSupplementary information for. Observation of photovoltaic action from photoacid-modified Nafion due to light-driven ion transport
Supplementary information for Observation of photovoltaic action from photoacid-modified Nafion due to light-driven ion transport William White, a# Christopher D. Sanborn, a# Ronald S. Reiter, a David
More informationElectronic Supplementary Information. An Ultrafast Surface-Bound Photo-active Molecular. Motor
This journal is The Royal Society of Chemistry and wner Societies 2013 Electronic Supplementary Information An Ultrafast Surface-Bound Photo-active Molecular Motor Jérôme Vachon, [a] Gregory T. Carroll,
More informationSupporting Information for. Near infrared-to-blue photon upconversion by exploiting direct. S-T absorption of a molecular sensitizer
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2017 Supporting Information for Near infrared-to-blue photon upconversion by
More informationA rapid and highly selective colorimetric method for direct detection of tryptophan in proteins via DMSO acceleration
A rapid and highly selective colorimetric method for direct detection of tryptophan in proteins via DMSO acceleration Yanyan Huang, Shaoxiang Xiong, Guoquan Liu, Rui Zhao Beijing National Laboratory for
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 214 Supporting Information Rapid and sensitive detection of acrylic acid using a novel fluorescence
More informationNew luminescent polynuclear metal. complexes with anticancer properties: towards. structure activity relationships
Supporting Information New luminescent polynuclear metal complexes with anticancer properties: towards structure activity relationships Margot Wenzel, a,d Andreia de Almeida, b Emilia Bigaeva, b Paul Kavanagh,
More informationSUPPORTING INFORMATION. A Sensitive and Selective Ratiometric Near IR Fluorescent Probe for Zinc Ions Based on Distyryl-Bodipy Fluorophore
SUPPORTING INFORMATION A Sensitive and Selective Ratiometric Near IR Fluorescent Probe for Zinc Ions Based on Distyryl-Bodipy Fluorophore Serdar Atilgan,, Tugba Ozdemir, and Engin U. Akkaya * Department
More informationInvestigation of Cation Binding and Sensing by new Crown Ether core substituted Naphthalene Diimide systems
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 218 Supplementary Material Investigation
More informationDETERMINATION OF RELATIVE FLUORESCENCE QUANTUM YIELD USING THE AGILENT CARY ECLIPSE
FOOD ANALYSIS DETERMINATION OF RELATIVE FLUORESCENCE QUANTUM YIELD USING THE AGILENT CARY ECLIPSE Solutions for Your Analytical Business Markets and Applications Programs Authors Sangeetha Ramesan Co-Authors
More informationA selenium-contained aggregation-induced turn-on fluorescent probe for hydrogen peroxide
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI) A selenium-contained aggregation-induced
More informationElectronic Supplementary Information. For. A turn-on-and-off ph sensitive BODIPY fluorescent probe for imaging E. coli cells
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 218 Electronic Supplementary Information
More informationSI0 UV-vis absorption spectra and emission response of 6MQz and 6MQc
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 SI0 UV-vis absorption spectra and emission response of 6MQz and 6MQc The absorption and emission
More informationNovel fluorescent matrix embedded carbon quantum dots enrouting stable gold and silver hydrosols
Novel fluorescent matrix embedded carbon quantum dots enrouting stable gold and silver hydrosols Shouvik Mitra a, Sourov Chandra b, Prasun Patra a, Panchanan Pramanik b *, Arunava Goswami a * a AERU, Biological
More informationElectronic supplementary information. Strategy to Enhance Solid-State Fluorescence and. Aggregation-Induced Emission Enhancement Effect in Pyrimidine
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 Electronic supplementary information Strategy to Enhance Solid-State Fluorescence and
More informationCaspase-1 Specific Light-up Probe with Aggregation-Induced Emission. Characteristics for Inhibitor Screening of Coumarin-Originated Natural.
Supporting Information Caspase-1 Specific Light-up Probe with Aggregation-Induced Emission Characteristics for Inhibitor Screening of Coumarin-Originated Natural Products Hao Lin, ^ Haitao Yang, ^ Shuai
More informationTurn-On Detection of Pesticides via Reversible Fluorescence Enhancement of Conjugated Polymer Nanoparticles and Thin Films
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016 Electronic Supporting Information
More informationExploiting the Interaction of Pyranine-3 with Poly(L-Lysine) to Mediate Nanoparticle Assembly: Fabrication of Dynamic ph-responsive Nanocontainers
Exploiting the Interaction of Pyranine-3 with Poly(L-Lysine) to Mediate Nanoparticle Assembly: Fabrication of Dynamic ph-responsive Nanocontainers Arlin Jose Amali, a Shashi Singh, b Nandini Rangaraj,
More informationA highly reactive chalcogenide precursor for the synthesis of metal chalcogenide quantum dots
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 Electronic supplementary information A highly reactive chalcogenide precursor for the synthesis
More informationProtein-based Sensitive, Selective and Rapid Fluorescence Detection of Picric Acid in Aqueous Media
Electronic Supplementary Material (ESI) for Analytical Methods. This journal is The Royal Society of Chemistry 2014 Supplementary information for Protein-based Sensitive, Selective and Rapid Fluorescence
More informationA BODIPY aldoxime-based chemodosimeter for highly selective and rapid detection of hypochlorous acid
Supporting Information A BODIPY aldoxime-based chemodosimeter for highly selective and rapid detection of hypochlorous acid Mustafa Emrullahoğlu,* Muhammed Üçüncü and Erman Karakuş Department of Chemistry,
More informationBODIPY Based Self-healing Fluorescent Gel Formation via Acylhydrazone Linkage
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 BODIPY Based Self-healing Fluorescent Gel Formation via Acylhydrazone Linkage Tugba Ozdemir
More informationDetermination of Particle Size Distribution of Water-Soluble CdTe Quantum Dots by Optical Spectroscopy
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Determination of Particle Size Distribution of Water-Soluble CdTe Quantum Dots by Optical Spectroscopy
More informationDetection of toxic mercury ions using a ratiometric CdSe/ZnS nanocrystal sensor
Supporting Information for Detection of toxic mercury ions using a ratiometric CdSe/ZnS nanocrystal sensor Leah E. Page, Xi Zhang, Ali M. Jawaid, and Preston T. Snee * Department of Chemistry, University
More informationApplication Note: Ocean Optics in the Teaching and Research Laboratories Susquehanna University Department of Chemistry July 2014
Application Note: Ocean Optics in the Teaching and Research Laboratories Susquehanna University Department of Chemistry July 2014 Authors: Dr. Swarna Basu (Associate Professor of Chemistry), Dr. Wade Johnson
More informationSpectroscopy. Page 1 of 8 L.Pillay (2012)
Spectroscopy Electromagnetic radiation is widely used in analytical chemistry. The identification and quantification of samples using electromagnetic radiation (light) is called spectroscopy. Light has
More informationSupporting Information
Supporting Information Activating Room Temperature Long Afterglow of Carbon Dots via Covalent Fixation Kai Jiang,, Yuhui Wang, Congzhong Cai, and Hengwei Lin*, Key Laboratory of Graphene Technologies and
More informationElectronic Supplementary Material (ESI) for Nanoscale This journal is The Royal Society of Chemistry Characterization of CeO2 NP suspensions
% Vol. Electronic Supplementary Material (ESI) for Nanoscale Characterization of CeO2 NP suspensions CeO2 NPs show a strong tendency to aggregate as a function of ph, ionic strength, dilution and sonication
More informationNovel fluorescent cationic benzothiazole dye response to G-quadruplex aptamer as a novel K + sensor
Electronic Supplementary Material (ESI) for Analyst. This journal is The Royal Society of Chemistry 2017 Novel fluorescent cationic benzothiazole dye response to G-quadruplex aptamer as a novel K + sensor
More informationA Temperature Sensor Based on CdTe Quantum Dots/Layered Double. Hydroxide Ultrathin Films via Layer-by-Layer Assembly
# Supplementary Material (ESI) for Chemical Communications # This journal is The Royal Society of Chemistry 2012 A Temperature Sensor Based on CdTe Quantum Dots/Layered Double Hydroxide Ultrathin Films
More informationA Highly Selective Fluorescent Sensor for Glucosamine
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 215 SUPPORTING INFORMATION A Highly Selective Fluorescent Sensor for Glucosamine Tam Minh Tran, Yuksel
More informationSupplementary Figure 1. Structures of substrates tested with 1. Only one enantiomer is shown.
Supplementary Figure 1. Structures of substrates tested with 1. Only one enantiomer is shown. Supplementary Figure 2. CD spectra obtained using 1 and (R)-3 (blue) and (S)-3 (red) Supplementary Figure 3.
More informationSuper-Resolution Monitoring of Mitochondrial Dynamics upon. Time-Gated Photo-Triggered Release of Nitric Oxide
Supporting Information for Super-Resolution Monitoring of Mitochondrial Dynamics upon Time-Gated Photo-Triggered Release of Nitric Oxide Haihong He a, Zhiwei Ye b, Yi Xiao b, *, Wei Yang b, *, Xuhong Qian
More informationHighly Water-soluble BODIPY-based Fluorescent Probes for Sensitive Fluorescent Sensing of Zinc (II)
Supporting Information Highly Water-soluble BODIPY-based Fluorescent Probes for Sensitive Fluorescent Sensing of Zinc (II) Shilei Zhu, [a] Jingtuo Zhang, [a] Jagadeesh Janjanam, [a] Giri Vegesna, [a] Fen-Tair
More informationOMCL Network of the Council of Europe QUALITY MANAGEMENT DOCUMENT
OMCL Network of the Council of Europe QUALITY MANAGEMENT DOCUMENT PA/PH/OMCL (11) 04 QUALIFICATION OF EQUIPMENT ANNEX 1: QUALIFICATION OF HPLC EQUIPMENT Full document title and reference Document type
More informationATTO 565 and ATTO 590
ATTO 565 and ATTO 590 General Information ATTO 565 and ATTO 590 are fluorescent labels belonging to the well known rhodamine dyes. A common feature of all rhodamine dyes is a carboxyphenyl substituent
More information2,5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2- b]pyrrole (AAPP) AIEgens: tunable RIR and TICT characteristics
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 2,5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2- b]pyrrole (AAPP) AIEgens:
More informationSupporting Information
Electronic Supplementary Material (ESI) for Photochemical & Photobiological Sciences. This journal is The Royal Society of Chemistry and Owner Societies 2014 Supporting Information 1. General procedure
More informationHigh Performance Liquid Chromatography
Updated: 3 November 2014 Print version High Performance Liquid Chromatography David Reckhow CEE 772 #18 1 HPLC System David Reckhow CEE 772 #18 2 Instrument Basics PUMP INJECTION POINT DETECTOR COLUMN
More informationHigh Performance Liquid Chromatography
Updated: 3 November 2014 Print version High Performance Liquid Chromatography David Reckhow CEE 772 #18 1 HPLC System David Reckhow CEE 772 #18 2 1 Instrument Basics PUMP INJECTION POINT DETECTOR COLUMN
More informationElectronic supplementary information
Electronic supplementary information Surface plasmon resonance enhanced upconversion luminescence in aqueous media for TNT selective detection Nina Tu and Leyu Wang* State Key Laboratory of Chemical Resource
More informationSolution reduction synthesis of amine terminated carbon quantum dots
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Solution reduction synthesis of amine terminated carbon quantum dots Keith Linehan and Hugh
More informationSupporting Information
Supporting Information A guanidine derivative of naphthalimide with excited-state deprotonation coupled intramolecular charge transfer property and its application Jin Zhou, ac Huiying Liu, b Bing Jin,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2014 Supporting Information 3D Cross-Correlative Matrix Temperature Detection and Non-Invasive
More informationFigure 1. Structures for Vitamin B2 and Vitamin B1.
CH 461 & CH 461H F 18 Name Experiment 2C Integrated Laboratory Experiment DETERMINATION OF RIBOFLAVIN: A COMPARISON OF TECHNIQUES PART C. HIGH PERFORMANCE LIQUID CHROMATOGRAPHY The purpose of this experiment
More informationControllable monobromination of perylene ring system: synthesis of bay-functionalized perylene dyes
Supporting Information Controllable monobromination of perylene ring system: synthesis of bay-functionalized perylene dyes Masaki Takahashi,* a Kyohei Asaba, a Trinh Thi Lua, a Toshiyasu Inuzuka, b Naohiro
More informationSupporting Information. Cells. Mian Wang, Yanglei Yuan, Hongmei Wang* and Zhaohai Qin*
Electronic Supplementary Material (ESI) for Analyst. This journal is The Royal Society of Chemistry 2015 Supporting Information Fluorescent and Colorimetric Probe Containing Oxime-Ether for Pd 2+ in Pure
More informationSupporting Information. Time-Resolved Botulinum Neurotoxin A Activity Monitored using. Peptide-Functionalized Au Nanoparticle Energy Transfer Sensors
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2014 Supporting Information Time-Resolved Botulinum Neurotoxin A Activity Monitored using Peptide-Functionalized
More informationElectronic Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information A fast and selective probe for detection of CN - and F -
More informationHigh photostability and enhanced fluorescence of gold nanoclusters by silver doping-supporting information
High photostability and enhanced fluorescence of gold nanoclusters by silver doping-supporting information Size measurements Figure S1 P2 FTIR measurements Figure S2 P2 XPS measurements Figure S3 P3 Photo-physical
More informationColorimetric and fluorescent probe for detection of nanomolar lysine in aqueous medium
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2016 Colorimetric and fluorescent probe for detection of nanomolar lysine in
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Tetraphenylethene-containing supramolecular hyperbranched
More informationSupporting Information. BODIPY-based Ratiometric Fluorescent Probe for Sensitive and Selective Sensing of Cyanide Ion
Supporting Information BODIPY-based Ratiometric Fluorescent Probe for Sensitive and Selective Sensing of Cyanide Ion Jingtuo Zhang, a Shilei Zhu, a Loredana Valenzano, a Fen-Tair Luo, b and Haiying Liu*
More informationSupporting Information
Supporting Information Metal-Cation Recognition in Water by a Tetrapyrazinoporphyrazine-Based Tweezer Receptor Lukas Lochman, [a] Jan Svec, [a] Jaroslav Roh, [b] Kaplan Kirakci, [c] Kamil Lang, [c] Petr
More informationDepressing the hydrogenation and decomposition. nanoparticles on oxygen functionalized. carbon nanofibers. Supporting Information
Electronic Supplementary Material (ESI) for Catalysis Science & Technology. This journal is The Royal Society of Chemistry 2015 Depressing the hydrogenation and decomposition reaction in H 2 O 2 synthesis
More informationZn(II) and Cd(II) based complexes for probing the enzymatic hydrolysis of Na 4 P 2 O 7 by Alkaline phosphatase in physiological condition
Supplementary information Zn(II) and Cd(II) based complexes for probing the enzymatic hydrolysis of Na 4 P 2 O 7 by Alkaline phosphatase in physiological condition Priyadip Das, Sourish Bhattacharya, Sandhya
More informationMismatched changes of the photoluminescence and crystalline structure of a mechanochromic gold(i) isocyanide complex
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Mismatched changes of the photoluminescence and crystalline
More informationElectronic Supporting Information (ESI)
Electronic Supporting Information (ESI) FRET operated sensor for intracellular ph mapping: Strategically improved efficiency on moving from anthracene to naphthalene derivative Arnab Banerjee a, Animesh
More informationCHAPTER 5 SPECTRAL CHARACTERISTICS OF NONLINEAR DYES IN LIQUID MEDIUM
90 CHAPTER 5 SPECTRAL CHARACTERISTICS OF NONLINEAR DYES IN LIQUID MEDIUM 5.1 INTRODUCTION The new nonlinear optical (NLO) materials with high optical nonlinearities are gaining interest both in research
More informationMetal-organic frameworks (MOFs) as precursors towards TiO x /C. composites for photodegradation of organic dye
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supplementary Information Metal-organic frameworks (MOFs) as precursors towards TiO x /C composites
More informationThienopyrrole and Selenophenopyrrole Donor Fused with Benzotriazole Acceptor: Microwave Assisted Synthesis and Electrochemical Polymerization
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Thienopyrrole and Selenophenopyrrole Donor Fused with Benzotriazole
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 218 Supporting Information Multi-Functional Organosilane-Polymerized Carbon Dots Inverse Opals Junchao
More informationSingle Catalyst Electrocatalytic Reduction of CO 2 in Water to H 2 :CO Syngas Mixtures with Water Oxidation to O 2
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Supporting Information Single Catalyst Electrocatalytic Reduction of CO 2
More informationAggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane
Electronic Supplementary Information (ESI) Aggregation-induced emission enhancement based on 11,11,12,12,-tetracyano-9,10-anthraquinodimethane Jie Liu, ab Qing Meng, a Xiaotao Zhang, a Xiuqiang Lu, a Ping
More informationZiessel a* Supporting Information (75 pages) Table of Contents. 1) General Methods S2
S1 Chemistry at Boron: Synthesis and Properties of Red to Near-IR Fluorescent Dyes based on Boron Substituted Diisoindolomethene Frameworks Gilles Ulrich, a, * Sebastien Goeb a, Antoinette De Nicola a,
More information6. A solution of red Kool-Aid transmits light at a wavelength range of nm.
I. Multiple Choice (15 pts) 1. FRET stands for a. Fluorescence Recovery Electron Transfer b. Fluorescence Resonance Energy Transfer c. Fluorescence Recovery Energy Transfer 2. Fluorescence involves the
More informationEffect of Addition Au Nanoparticles on Emission Spectra of Laser Dye
International Journal of Applied Engineering Research ISSN 973-462 Volume 2, Number 24 (27) pp. 4833-484 Effect of Addition Au Nanoparticles on Emission Spectra of Laser Dye Sara Ali Razzak, Lazem Hassan
More informationSupporting Information For Asymmetric Trimethine 3H-Indocyanine Dyes: Efficient Synthesis and Protein Labeling
Supporting Information For Asymmetric Trimethine 3HIndocyanine Dyes: Efficient Synthesis and Protein Labeling Fengling Song, a Li Wang, a Jiangli Fan, a Xiaoqiang Qiao, b Bingshuai Wang, a Shiguo Sun,
More informationCobalt-Porphyrin /Dansyl Piperazine Complex Coated Filter. Paper for Turn on Fluorescence Sensing of Ammonia Gas
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 215 Electronic Supplementary Information Cobalt-Porphyrin /Dansyl Piperazine Complex Coated Filter
More informationCHAPTER 19 PARACETAMOL + IBUPROFEN
CHAPTER 19 PARACETAMOL + IBUPROFEN SUMMARY 246 A combination of paracetamol and ibuprofen is marketed in India. Literature survey indicated that one titrimetnc-1-** and one HPLC193 methods are reported
More informationSupplementary Information for
Supplementary Information for Facile transformation of low cost thiourea into nitrogen-rich graphitic carbon nitride nanocatalyst with high visible light photocatalytic performance Fan Dong *a, Yanjuan
More informationFluorescence Spectrophotometry
Chemistry 422L Manual Page 27 I. Introduction Fluorescence Spectrophotometry Ru(bpy) 3 2+, where bpy = 2, 2' bipyridine, has been one of the most widely studied metal complexes in recent years. Interest
More informationSupporting Informations for. 1,8-Naphthyridine-based molecular clips for off-on fluorescence sensing
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Informations for 1,8-aphthyridine-based molecular clips for off-on fluorescence
More information1+2 on GHD (5 µl) Volume 1+2 (µl) 1 on GHD 1+2 on GHD
1+2 on GHD (20 µl) 1+2 on GHD (15 µl) 1+2 on GHD (10 µl) 1+2 on GHD (5 µl) Volume 1+2 (µl) 1 on GHD 1+2 on GHD Supplementary Figure 1 UV-Vis measurements a. UV-Vis spectroscopy of drop-casted volume of
More informationSupporting Information. An AIE active Y-shaped diimidazolylbenzene: aggregation and
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Supporting Information An AIE active Y-shaped diimidazolylbenzene: aggregation
More informationA fluorescent ph probe for acidic organelle in living cells
Electronic Supplementary Material (ESI) for rganic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information for A fluorescent ph probe for acidic organelle in
More informationElectronic supplementary information (ESI)
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information (ESI) Two novel organic phosphorous-based MOFs:
More informationA dual-model and on off fluorescent Al 3+ /Cu 2+ - chemosensor and the detection of F /Al 3+ with in situ prepared Al 3+ /Cu 2+ complex
Supporting Information (SI) A dual-model and on off fluorescent Al 3+ /Cu 2+ - chemosensor and the detection of F /Al 3+ with in situ prepared Al 3+ /Cu 2+ complex Xiaoya Li, Mingming Yu, Faliu Yang, Xingjiang
More informationIn vivo monitoring of hydrogen sulfide using a cresyl violet-based ratiometric fluorescence probe
Electronic Supplementary Information for: In vivo monitoring of hydrogen sulfide using a cresyl violet-based ratiometric fluorescence probe Qiongqiong Wan, Yanchao Song, Zhao Li, Xinghui Gao and Huimin
More informationCHAPTER - 3 ANALYTICAL PROFILE. 3.1 Estimation of Drug in Pharmaceutical Formulation Estimation of Drugs
CHAPTER - 3 ANALYTICAL PROFILE 3.1 Estimation of Drug in Pharmaceutical Formulation 3.1.1 Estimation of Drugs ANALYTICAL PROFILE 84 3.1 ESTIMATION OF DRUG IN PHARMACEUTICAL FORMULATION. Agrawal A et al
More information