Chapter 16 Aldehydes and Ketones Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette
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1 Chapter 16 Aldehydes and Ketones Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
2 Carbonyl Group - Structure and Bonding The carbonyl carbon atom is trigonal planar, with bond angles of 120 o. O is more electronegative than C, so the carbonyl group is polar. The carbonyl O is e rich (δ ) and the carbonyl C is e poor (δ + ). 2
3 Aldehydes and Ketones Abbreviations for aldehydes and ketones: 3
4 Nomenclature A. Naming Aldehydes To name an aldehyde using the IUPAC system: Find the longest chain containing the CHO group. Change the -e ending of the parent alkane to -al. Number the chain to put the CHO group at C1, but omit 1 from the name. Apply all other nomenclature rules. 4
5 Sample Problem 16.1 Nomenclature A. Naming Aldehydes Give the IUPAC name for each aldehyde 5
6 Sample Problem 16.1 Nomenclature A. Naming Aldehydes [1] Find and name the longest chain containing the CHO. a) b) 6
7 Sample Problem 16.1 Nomenclature A. Naming Aldehydes [2] Number and name substituents, making sure the CHO group is at C1. a) b) 7
8 Nomenclature A. Naming Aldehydes Common names are used for simple aldehydes; the names contain the suffix -aldehyde. formaldehyde acetaldehyde benzaldehyde 8
9 Nomenclature B. Naming Ketones To name an ketone using the IUPAC system: Find the longest chain containing the carbonyl group. Change the -e ending of the parent alkane to - one. Number the chain to give the carbonyl carbon the lower number. Apply all other nomenclature rules. 9
10 Sample Problem 16.1 Nomenclature B. Naming Ketones Give the IUPAC name for each ketone. 10
11 Sample Problem 16.1 Nomenclature B. Naming Ketones [1] Find and name the longest chain containing the carbonyl group. a) b) 11
12 Sample Problem 16.1 Nomenclature B. Naming Ketones [2] Number and name substituents, making sure the carbonyl carbon has the lowest possible number. a) b) 12
13 Nomenclature B. Naming Ketones Common names for ketones are formed by naming both alkyl groups, arranging them alphabetically, and adding the word -ketone 13
14 Nomenclature B. Naming Ketones Some widely used common names do not follow the convention: acetone acetophenone benzophenone 14
15 Physical Properties Aldehydes and ketones have higher boiling points than similar hydrocarbons because: they are polar molecules - stronger intermolecular forces than alkanes and alkenes CH 3 CH 2 CH 2 CH 2 CH 3 pentane bp 36 o C CH 3 CH 2 CH 2 CHO butanal bp 76 o C Increasing boiling point 15
16 Physical Properties Aldehydes and ketones have lower boiling points than similar alcohols because: they do not have an O H bond - they do not form intermolecular hydrogen bonds. thus, they have weaker intermolecular forces than alcohols CH 3 CH 2 COCH 3 2-butanone bp 80 o C CH 3 CH 2 CH 2 CH 2 OH 1-butanol bp 118 o C Increasing boiling point 16
17 Physical Properties Aldehydes and ketones are soluble in organic solvents. Those molecules with 6 C s or less are soluble in water. Those molecules with 7 C s or more are insoluble in water. 17
18 Focus on Health & Medicine Interesting Aldehydes and Ketones Formaldehyde (CH 2 O) is the simplest aldehyde: Starting material for synthesis of resins and plastics. Sold as formalin, a 37% aqueous solution used to preserve biological specimens. Acetone [(CH 3 ) 2 C O] is the simplest ketone: Industrial solvent and a starting material for organic polymers. Produced in the breakdown of fatty acids in the body. Unusually high levels are found in diabetic patients. 18
19 Focus on Health & Medicine Interesting Aldehydes and Ketones Cinnamaldehyde, major component of cinnamon bark: Vanillin, primary component of the extract of the vanilla bean: Citral, characteristic odor of lemon grass, used in perfumery and in synthesis of vitamin A: Citronellal, odor of citronella candles, used to repel mosquitoes: 19
20 Reactions of Aldehydes and Ketones 1. Aldehydes can be oxidized to carboxylic acids: 2. Aldehydes and ketones undergo addition reactions: 20
21 Reactions of Aldehydes and Ketones 1. Oxidation of Aldehydes In oxidation, the aldehyde C H bond is converted into a carboxylic acid C OH bond. Ketones cannot be oxidized because there is no C H bond. 21
22 Reactions of Aldehydes and Ketones 1. Oxidation of Aldehydes Aldehydes can be selectively oxidized in the presence of other functional groups using the Tollens reagent. Ketones do not react with the Tollens reagent. 22
23 Reactions of Aldehydes and Ketones 2. Specific Features of Carbonyl Reductions Aldehydes are reduced to 1 o alcohols: [H] is used to represent a general reduction reagent. H 2 gas in the presence of Pd metal is a commonly used reagent. 23
24 Reactions of Aldehydes and Ketones 2. Specific Features of Carbonyl Reductions Ketones are reduced to 2 o alcohols. 24
25 Reactions of Aldehydes and Ketones 2. Specific Features of Carbonyl Reductions Examples: 25
26 Reactions of Aldehydes and Ketones 2. Specific Features of Carbonyl Reductions Focus on the Human Body Biological systems do not have H 2 and Pd to use as a reducing agent. Instead they use the coenzyme NADH in the presence of an enzyme. In acting as a reducing agent the NADH is oxidized to NAD +, which is a biological oxidizing agent. 26
27 Reactions of Aldehydes and Ketones 2. Specific Features of Carbonyl Reductions The Chemistry of Vision The human eye consists of two types of light-sensitive cells the rod and the cone cells. The chemistry of vision in the rod cells centers around the aldehyde 11-cis-retinal. 27
28 Reactions of Aldehydes and Ketones 2. Specific Features of Carbonyl Reductions The Chemistry of Vision The cis double bond is isomerized into the morestable trans double bond when light hits the retina. This process sends a nerve impulse to the brain, which is then converted into a visual image. 28
29 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals Aldehydes and ketones undergo addition reactions with alcohols to form hemiacetals and acetals (in the presence of H 2 SO 4 ). 29
30 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals Addition of one molecule of alcohol to an aldehyde or ketone forms a hemiacetal. A hemiacetal will react with a second molecule of alcohol to form an acetal. 30
31 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals An example of acetal formation using ethanol as the added alcohol: 31
32 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals Cyclic hemiacetals containing 5 or 6 membered rings are stable compounds. Formed by an intramolecular reaction of a compound that contains both an OH group and an aldehyde or ketone. 32
33 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals The most common simple carbohydrate, glucose, exists predominantly as a cyclic hemiacetal. 33
34 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals Cyclic hemiacetals are converted to cyclic acetals by reaction with another alcohol. 34
35 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals Lactose, the main carbohydrate in milk, is composed of both a cyclic hemiacetal and a cyclic acetal. 35
36 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals Acetals can be converted back to aldehydes (or ketones) and alcohols by hydrolysis. 36
37 Reactions of Aldehydes and Ketones 2. Acetals and Hemiacetals Example: 37
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