Chem 341. cook.chem.ndsu.nodak.edu/chem341. Organic Chemistry I Fall 2007 Greg Cook Dunbar 360A. Please pick up a syllabus near the entrance

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1 Chem 341 rganic Chemistry I Fall 2007 Greg Cook Dunbar 360A cook.chem.ndsu.nodak.edu/chem341 Please pick up a syllabus near the entrance

2 Syllabus ffice ours Mon, Wed - 9:00-10:00 am or give me a call Dunbar all 360A (back of 362 Lab) Phone gregory.cook@ndsu.edu Supplemental Instruction Carla Sharp - carla.d.sharp@ndsu.edu 2

3 Textbook rganic Chemistry Sixth Edition, J. McMurry Study Guide and Solutions Manual suggested Darling Molecular Models RF PRS transmitter 3

4 Grading Exams three midterm exams (60%) comprehensive final (30%) A % B 75-84% C 60-74% D 45-59% Quizzes (10%) daily quiz question on the screen only at the beginning of class we will use PRS quizzes begin on monday 4

5 Exams We will use more than one room for exams Begin at 7:45 All hats, cell phones, PDAs and calculators, ipods must remain stored away during exams. Please bring a picture ID to the exam Arrange to take the exam ahead of time if you will be absent for an authorized school function 5

6 cook.chem.ndsu.nodak.edu/chem341 6

7 Course utline Chapter 1 - Structure and Bonding Chapter 2 - Polar Covalent Bonds, Acids and Bases Chapter 3 - Alkanes and Cycloalkanes Chapter 4 - Stereochemistry of Alkanes Chapter 5 - rganic Reactions Chapter 6 - Alkenes Structure and Reactivity Chapter 7 - Alkenes Reactions and Synthesis Chapter 8 - Alkynes and rganic Synthesis Chapter 9 - Stereochemistry Chapter 10 - Alkyl alides Chapter 11 - Substitution and Elimination Chapter 12 - Mass Spec and IR Spectroscopy Chapter 13 - MR Spectroscopy 7

8 My Philosphy Toward rganic Chemistry Like a foreign language Vocabulary Terms Structures Functional Groups Grammar Electronic properties Reactivity 8

9 -Chem is T about rote memorization If you depend on rote memorization for passing classes, you will most likely not do well in Chem is about problem solving. We will build a foundation of knowledge. I expect you to be able to reach beyond what you have memorized and make new connections with this knowledge

10 Tips For Learning rganic Chemistry Read ahead before coming to class CME T CLASS Rewrite your notes Do the suggested problems - do them again Flash cards can help SUBSTRATES REAGETS PRDUCTS 10

11 Tips For Learning rganic Chemistry Study with a friend or form a study group A set of molecular models can help D T Fall Behind D T Fall Behind D T Fall Behind rganic Chemistry is an integral part of Materials Science, Biology and Biochemistry. USE SI and TA s 11

12 h Yeah, CME T CLASS Attendance vs Performance 2004 Absent >2 (73 students) Absent <3 (199 students) 12

13 -Chem is a Blackboard Subject I will mostly use the blackboard in lectures. I will write large. If you can t see MVE T TE FRT F TE LECTURE ALL 13

14 What Is rganic Chemistry? rganic Websters Dictionary 1913 Pertaining to, or denoting, any one of the large series of substances which, in nature or origin, Chemistry are connected with vital processes. Merriam-Webster WWW Dictionary A science that deals with the composition, structure, and properties of substances and with the transformations that they undergo. 14

15 rganic Chemistry 18th Century rganic Compounds obtained from Living rganisms which posses the vital force It was thought that rganic Compounds could not be made or manipulated without the influence of this vital force Torbern Bergman

16 rganic Chemistry 19th Century It was demonstrated for the first time that an organic molecule could be synthesized from an inorganic molecule. C heat 2 C 2 Ammonium Cyanate Urea Friederich Wöhler

17 rganic Chemistry 20th Century Amino Acids, Life s Building Blocks, created from simple materials. C e- 2 C C C C C 3 Urey and Miller

18 Biomolecules Carbohydrates / Sugars Glucose Fats / Lipids Amino Acids / Proteins 2 3 R R eterocyclic Bases (DA) C 2 Adenine Guanine Cytosine Thymine Uracil 18

19 atural Products Ac Paclitaxel (Taxol ) anticancer compound isolated from the PhC PhC Ac bark of the pacific yew tree Epibatidine analgesic compound isolated Cl from the skins of an ecuadorian tree frog 19

20 Man-Made (Synthetic) rganic Compounds Polymers * * Ph Ph Ph Ph Ph Ph polystyrene C 3 Dyes a 2 S C 3 methyl orange Pharmaceuticals C 3 acetaminophen (Tylenol ) 20

21 Modern rganic Chemistry The Chemistry of Carbon Compounds Challenges for the 21st century ew efficient tools for making organic compounds - RGAIC SYTESIS SELECTIVITY Chemoselectivity Regioselectivity Stereoselectivity 21

22 Elias A. Zerhouni - I Director ne interesting result of the I Roadmap development process came when we surveyed scientists to find out what the stumbling blocks for biological sciences were. The number one stumbling block turned out to be synthetic organic chemistry. I was shocked because I thought the limiting factor was computational biology. So the I Roadmap really changed my view of the importance of chemistry and chemical engineering. Chemical & Engineering ews, July 3,

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