Appendix C (beginning 2004)

Size: px
Start display at page:

Download "Appendix C (beginning 2004)"

Transcription

1 APPENDIX C Syllabus for the theoretical part of the IChO competition Level 1 Level 2 Level 3 These topics are included in the overwhelming majority of secondary school chemistry programs and need not to be mentioned in the preparatory problems. These topics are included in a substantial number of secondary school programs and maybe used without exemplification in the preparatory problems. These topics are not included in the majority of secondary school programs and can only be used in the competition if examples are given in the preparatory problems. 1 The atom 1.1 Introduction Counting of nucleons Isotopes The hydrogen Concept of energy levels Shape of s-orbitals Shape and orientation of p-orbitals Shape and orientation of d-orbitals Understanding the simplest Schrödinger equation Square of the wave function and probability Quantum numbers (n, l, m l ) Radioactivity Types of radioactivity Radioactive decay Nuclear reactions 2 2 Chemical bonding 2.1 VSEPR Simple molecular structures with no more than four electron pairs about central atom with central atom exceeding the octet rule Delocalisation and resonance Hybrid orbital theory? 2.4 Molecular orbital theory Molecular orbital diagram (H 2 molecule) Molecular orbital diagram (N 2 and O 2 molecules) Bond orders in O 2, O - + 2, O Unpaired electrons and paramagnetism 3 3 Chemical calculations 3.1 Balancing equations Stoichiometric calculations Mass and volume relations (including density) Empirical formula Avogadro s number Concentration calculations 1 4 Periodic trends 4.1 Electronic configuration Pauli exclusion principle Hund s rule Main group elements Transition metal elements Lanthanide and actinide metals Electronegativity Electron affinity First ionisation energy Atomic size 1 Page 1 of 8

2 4.6 Ion size Highest oxidation number 1 5 Inorganic chemistry 5.1 Introduction Trends in physical properties of elements (main groups) Melting point Boiling point Metal character Magnetic properties Electrical conductivity Oxidation number Nomenclature Main group compounds Transition metal compounds Simple metal complexes Groups 1 and Trend in reactivity (heavy elements more reactive) Products of reaction with water halogens oxygen Basicity of oxides Properties of hydrides Other compounds, properties and oxidation states Group and hydrogen Binary molecular compounds of hydrogen Formulae Acid-base properties of CH 4, NH 3, H 2 O, H 2 S Other properties Group The oxidation state of boron and aluminium in their oxides and chlorides is The acid-base properties of aluminium oxide / hydroxide Reaction of boron (III) oxide with water Reaction of boron (III) chloride with water Other compounds, properties, and oxidation states Group The oxidation state of silicon in its chloride and oxide is The +2 and +4 oxidation states of carbon, tin, and lead, the acid base and redox properties of the oxides and chlorides Other compounds, properties, and oxidation states Group Phosphorus (+5) oxide and chloride, and their reaction with water Phosphorus (+3) oxide and chloride, and their reaction with water Oxide of nitrogen Reaction of NO to form NO Dimerisation of NO Reaction of NO 2 with water Redox properties of HNO 3 and nitrates HNO 2 and NH 2 NH Bismuth (+5) and bismuth (+3) Other compounds, properties, and oxidation states Group The +4 and +6 oxidation states of sulphur, reaction of their oxides with water, properties of their acids Reaction of thiosulfate anion with I Other compounds, properties, and oxidation states Group 17 (Halogens) Page 2 of 8

3 Reactivity and oxidant strength decreases from F 2 to I Acid-base properties of the hydrogen halides The oxidation state of fluorine and its compounds is The -1, +1, +3, +5, +7 oxidation states of chlorine Mononuclear oxoanions of chlorine Reactions of halogens with water Reaction of Cl 2 O and Cl 2 O 7 with water Other compounds, properties, and oxidation states Group Transition elements Common oxidation states of common transition elements [Cr (+2, +3), Mn (+2, +3, +7), Ag (+1), Fe (+2, +3), Co (+2), Zn (+2), Hg (+1, +2), Cu (+1, +2), Ni (+2)] Colours of ions listed above in aqueous solution Insolubility of Ag, Hg, and Cu in HCl M 2+ arising by dissolution of the other metals in HCl Cr(OH) 3 and Zn(OH) 2 are amphoteric and the other +2 oxides / hydroxides of the metals listed above are basic MnO - 4 and Cr 2 O 2-7 are strong oxidants in acidic solution ph dependence of products of MnO - 4 acting as oxidant Interconversion between CrO and Cr 2 O Other compounds, properties, and oxidation states Lanthanide and actinides Coordination chemistry including stereochemistry Definition of coordination number Writing equations for complexation reactions given all formulae Formulae of common complex ions Ag(NH 3 ) Ag(S 2 O 3 ) FeSCN Cu(NH 3 ) Other complex ions Ligand field theory (e g and t 2g terms, high and low spin) Stereochemistry cis and trans enantiomers Selected industrial processes Preparation of H 2 SO Preparation of NH Preparation of Na 2 CO Preparation of Cl 2 and NaOH Preparation of HNO Physical chemistry 6.1 Gases Ideal gas law van der Wall s gas law Definition of partial pressure Dalton s law Thermodynamics First law Concept of system and surroundings Energy, heat, and work Enthalpy Relationship between internal energy and enthalpy Definition of heat capacity Difference between C P and C V (ideal gas only) Enthalpy is a state property (Hess s law) Born-Haber cycle for ionic compounds Use of standard formation enthalpies Enthalpies of solution and solvation 3 Page 3 of 8

4 Bond enthalpies (definition and use) Second law (entropy and free energy) Definition of entropy (q/dt) Entropy and disorder Definition of entropy (S = k ln W) Free energy definition ( G = H - T S) Using G to predict direction of natural change Relationship of G 0 and equilibrium constant K Equilibrium Acid-base Arrhenius definitions of acids and bases Bronsted-Lowry definitions Conjugate acids and bases Definition of ph Definition of K w K a as a measure of acid and base strength Acidity or basicity of ions Calculations of ph from pk a (weak acid) Calculations of ph of a simple buffer solution Gas phase Equilibrium constant in partial pressures Relating K P and K C Solubility Definition of solubility constant (product) (K sp ) Calculation of solubility in water from K sp Compleximetric Complex formation constant (definition) Problems involving compleximetric equilibria Lewis acids and bases Hard and soft Lewis acids and bases Phase Temperature dependence of vapour pressure Clausius-Clapeyron equation Single component phase diagrams Triple point Critical point Liquid-vapour system Ideal and non-ideal systems Diagram Use in fractional distillation Henry s law Raoult s law Deviation from Raoult s law Boiling point elevation Freezing point depression Osmotic pressure Solvent extraction Multiple Calculation of ph for multiprotic acids Calculation of ph for weak acid mixtures Electrochemistry Electromotive force (definition) First kind electrodes Standard electrode potential Nernst equation Second kind electrodes Relationship between G and electromotive force 3 7 Chemical kinetics (homogeneous reactions) 7.1 Introduction Page 4 of 8

5 7.1.1 Factors affecting reaction rate Reaction coordinates and the basic idea of a transition state Rate law Differential rate law Concept of reaction order Definition of rate constant First order reactions Dependence of concentration on time Concept of half life Relationship between half life and rate constant Calculation of first order rate constant from Differential rate law Integral rate law Rate constant for second and third order reactions Reaction mechanisms Concept of molecularity Rate-determining step Basic concepts of collision theory Opposing parallel and consecutive reactions Arrhenius s law Definition of activation energy Calculation of activation energy 3 8 Spectroscopy 8.1 UV / Visible Identification of aromatic compound Identification of chromophore Dyes: colour against structure Beer s law Infrared Interpretation using a table of frequencies Recognition of hydrogen bonds X-ray Bragg s law Concept of coordination number unit cell Solid structures NaCl CsCl metals NMR General concepts Chemical shifts Spin-spin coupling and coupling constants Integration Interpretation of a simple 1 H spectrum (like ethanol) Identification of o- and p-disubstituted benzene Interpretation of simple spectra of 13 C (proton decoupled) and other spin (nuclei) Mass spectrometry Recognition of molecular ion Recognition of fragments with the help of a table Recognition of typical isotope distribution 3 9 Organic chemistry 9.1 Introduction Alkane nomenclature (IUPAC) Trends in boiling point of alkanes with structure alcohols against ethers due to hydrogen-bonding 1 Page 5 of 8

6 9.1.3 Geometry at singly, doubly, and triply bonded carbon Identification of common functional groups Isomerism of alkanes cis-trans E/Z Enantiomers Optical activity R/S nomenclature Reactivity Alkanes Reaction with halogens Products Free radical mechanism (initiation, termination) Cycloalkanes Names Strain in small rings Chair/boat conformations of cyclohexane Alkenes Products from Br 2, HBr, and H 2 O/H Markownikoff s rule Mechanism involving carbocations intermediates Relative stability of carbocations ,4 addition to dienes Alkynes Acidity relative to alkenes Differences in chemical properties from alkenes? Benzene Formula Stabilisation by resonance Electrophilic substitution (nitration, halogenation) directing effect of first substituent effect of first substituent on reactivity explanation of substituent effects Halogen compounds Nomenclature of monofunctional Substitution reactions giving alcohols in which halogen is exchanged reactivity primary against secondary against tertiary aliphatic against aromatic S N 1 and S N 2 mechanisms Elimination reactions Competition of elimination and substitution Alcohols Nomenclature of monofunctional Comparison of acidity of alcohols and phenols Dehydration to alkenes Esters with inorganic acid Oxidation reactions Aldehydes and ketones Nomenclature of monofunctional Oxidation of aldehydes Reduction to alcohols (LiAlH 4, NaBH 4 ) Keto / enol tautomerism Nucleophilic addition reactions with HCN RNH 2 (R=alkyl, HO, NH 2 ) enolate anions (aldol condensation) alcohols to form acetals / ketals 3 Page 6 of 8

7 Grignard reagents Carboxylic acids and their derivatives Nomenclature of carboxylic acids and their derivatives (esters, acid halides, amides) Acidity strength related to inductive effects Preparation of carboxylic acids by hydrolysis of esters (including soaps) amides nitriles Reaction of carboxylic acids with alcohols to form esters to form acid chlorides to form anhydrides Reaction of acid chlorides to form amides Mechanism of esterification Multifunctional acids (hydroxyacids, ketoacids) Polycarboxylic acids Amines Nomenclature simple amines recognition of primary, secondary, tertiary Basicity As a property of an amine Comparison of basicity of aliphatic and aromatic Comparison of basicity of amines and amides Preparation of amines from halides from aromatic nitro compounds from amides (by hydrolysis) Diazotisation of aliphatic amines of aromatic amines 3 10 Polymers 10.1 Synthetic Addition polymers polystyrene polyethene chain mechanism of formation Condensation polymers polyesters polyamides Silicones Concept of cross-linking and its effect on properties Natural Silicates Rubber 3 11 Biochemistry 11.1 Carbohydrates Glucose and fructose Chain formulae Fischer projections Haworth formulae Difference between starch and cellulose Difference between α- and β-d glucose Fats Structure of fats in relationship to properties Formula of glycerol Nitrogen-containing compounds of biological importance Page 7 of 8

8 Amino acids Ionic structure Isoelectric point amino acids (classification with structures provided) Separation by electrophoresis The peptide linkage Proteins Primary structure S S bridges Sequence analysis Secondary structure Details of α helix structure Tertiary structure Denaturation (change in ph, temperature, metals, ethanol) Nuclei acids and protein synthesis Pyrimidine and purine Nucleosides and nucleotides Formulae of pyrimidine and purine bases Difference between ribose and 2-deoxyribose Base combination CG and AT (hydrogen-bonding) Difference between DNA and RNA Difference between mrna and trna Enzymes General properties, active centres Nomenclature, kinetics, coenzymes, function of ATP 3 12 Analytical chemistry 12.1 Titrations Acid-base Titration curve; ph (strong and weak acid) Choice of indicators of acidimetry Redox titration Qualitative analysis Ions (inorganic) Identification of Ag +, Ba 2+, Cl - 2-, SO Identification of other anions and cations Organic functional groups Lucas reagent (1, 2, 3 alcohols) Iodoform reaction Identification of primary, secondary, tertiary, quaternary amines in the laboratory Chromatographic methods of separation 3 Page 8 of 8

Topic 1: Quantitative chemistry

Topic 1: Quantitative chemistry covered by A-Level Chemistry products Topic 1: Quantitative chemistry 1.1 The mole concept and Avogadro s constant 1.1.1 Apply the mole concept to substances. Moles and Formulae 1.1.2 Determine the number

More information

Keynotes in Organic Chemistry

Keynotes in Organic Chemistry Keynotes in Organic Chemistry Second Edition ANDREW F. PARSONS Department of Chemistry, University of York, UK Wiley Contents Preface xi 1 Structure and bonding 1 1.1 Ionic versus covalent bonds 1 1.2

More information

TUTORIAL LIST 2017/18

TUTORIAL LIST 2017/18 TUTORIAL LIST 2017/18 ATOMIC STRUCTURE & MOLE CALCULATIONS BONDING & INORGANIC CHEMISTRY PHYSICAL CHEMISTRY ORGANIC CHEMISTRY PRACTICAL CHEMISTRY PAST PAPER WALKTHROUGHS ATOMIC STRUCTURE & MOLE CALCULATIONS

More information

Introduction. A1.1 (a) Shell number and number of subshells 1. A1.1 (b) Orbitals 2. A1.1 (c ) Orbital shapes (s, p & d) 2

Introduction. A1.1 (a) Shell number and number of subshells 1. A1.1 (b) Orbitals 2. A1.1 (c ) Orbital shapes (s, p & d) 2 Preface Table of Contents Introduction i A1.1 (a) Shell number and number of subshells 1 A1.1 (b) Orbitals 2 A1.1 (c ) Orbital shapes (s, p & d) 2 A1.1 (d) Relative energies of s,p,d,f sub-shells 4 A 1.1

More information

The Basics of General, Organic, and Biological Chemistry

The Basics of General, Organic, and Biological Chemistry The Basics of General, Organic, and Biological Chemistry By Ball, Hill and Scott Download PDF at https://open.umn.edu/opentextbooks/bookdetail.aspx?bookid=40 Page 5 Chapter 1 Chemistry, Matter, and Measurement

More information

Exam 1 (Monday, July 6, 2015)

Exam 1 (Monday, July 6, 2015) Chem 231 Summer 2015 Assigned Homework Problems Last updated: Friday, July 24, 2015 Problems Assigned from Essential Organic Chemistry, 2 nd Edition, Paula Yurkanis Bruice, Prentice Hall, New York, NY,

More information

UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry

UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry UNIT 4 REVISION CHECKLIST CHEM 4 AS Chemistry Topic 4.1 Kinetics a) Define the terms: rate of a reaction, rate constant, order of reaction and overall order of reaction b) Deduce the orders of reaction

More information

A-LEVEL A-LEVEL CHEMISTRY CHEMISTRY NOTES

A-LEVEL A-LEVEL CHEMISTRY CHEMISTRY NOTES A-LEVEL A-LEVEL CHEMISTRY CHEMISTRY NOTES snaprevise.co.uk I have designed and compiled these beautiful notes to provide a detailed but concise summary of this module. I have spent a lot of time perfecting

More information

Study guide for AP test on TOPIC 1 Matter & Measurement

Study guide for AP test on TOPIC 1 Matter & Measurement Study guide for AP test on IC 1 Matter & Measurement IC 1 Recall a definition of chemistry Understand the process and stages of scientific (logical) problem solving Recall the three states of matter, their

More information

Level I Course Units Offered by The Department of Chemistry For

Level I Course Units Offered by The Department of Chemistry For Level I Course Units Offered by The Department of Chemistry For General Degree (3 year) [Bachelor of Science SLQF5] General Degree (4 year-molecular Biology & Biotechnology) [Bachelor of Science (Molecular

More information

ORGANIC CHEMISTRY. Fifth Edition. Stanley H. Pine

ORGANIC CHEMISTRY. Fifth Edition. Stanley H. Pine ORGANIC CHEMISTRY Fifth Edition Stanley H. Pine Professor of Chemistry California State University, Los Angeles McGraw-Hill, Inc. New York St. Louis San Francisco Auckland Bogota Caracas Lisbon London

More information

ADVANCED CHEMISTRY 2

ADVANCED CHEMISTRY 2 ADVANCED CHEMISTRY 2 Philip Matthews ±m±l CAMBRIDGE UNIVERSITY PRESS Acknowledgements How to use this book INORGANIC CHEMISTRY 88 Periodicity of physical properties 88.1 Periodicity of ionisation energies

More information

CHEM 261 HOME WORK Lecture Topics: MODULE 1: The Basics: Bonding and Molecular Structure Text Sections (N0 1.9, 9-11) Homework: Chapter 1:

CHEM 261 HOME WORK Lecture Topics: MODULE 1: The Basics: Bonding and Molecular Structure Text Sections (N0 1.9, 9-11) Homework: Chapter 1: CHEM 261 HOME WORK Lecture Topics: MODULE 1: The Basics: Bonding and Molecular Structure Atomic Structure - Valence Electrons Chemical Bonds: The Octet Rule - Ionic bond - Covalent bond How to write Lewis

More information

Contents. 1 Matter: Its Properties and Measurement 1. 2 Atoms and the Atomic Theory Chemical Compounds Chemical Reactions 111

Contents. 1 Matter: Its Properties and Measurement 1. 2 Atoms and the Atomic Theory Chemical Compounds Chemical Reactions 111 Ed: Pls provide art About the Authors Preface xvii xvi 1 Matter: Its Properties and Measurement 1 1-1 The Scientific Method 2 1-2 Properties of Matter 4 1-3 Classification of Matter 5 1-4 Measurement of

More information

SPECIFIC AIMS. I year (1st semester) A.Y

SPECIFIC AIMS. I year (1st semester) A.Y I year (1st semester) A.Y. 2017-2018 MARINI S. COORDINATOR Scientific Field CHEMISTRY AND INTRODUCTORY BIOCHEMISTRY TUTOR ECTS BIO/10 Chemistry and Introductory Biochemistry Marini Stefano 5 BIO/10 Chemistry

More information

Chemistry: The Central Science Twelfth Edition, AP* Edition 2012

Chemistry: The Central Science Twelfth Edition, AP* Edition 2012 A Correlation of The Central Science Twelfth Edition, AP* Edition 2012 to the AP* Chemistry Topics I. Structure of Matter A. Atomic theory and atomic structure 1. Evidence for the atomic theory SECTIONS:

More information

Detailed Course Content

Detailed Course Content Detailed Course Content Chapter 1: Carbon Compounds and Chemical Bonds The Structural Theory of Organic Chemistry 4 Chemical Bonds: The Octet Rule 6 Lewis Structures 8 Formal Charge 11 Resonance 14 Quantum

More information

Chemistry: Molecules, Matter, and Change, Fourth Edition Loretta Jones and Peter Atkins Correlated with AP Chemistry, May 2002, May 2003

Chemistry: Molecules, Matter, and Change, Fourth Edition Loretta Jones and Peter Atkins Correlated with AP Chemistry, May 2002, May 2003 Chemistry: Molecules, Matter, and Change, Fourth Edition Loretta Jones and Peter Atkins Correlated with AP Chemistry, May 2002, May 2003 ST=Student textbook I. Structure of Matter A. Atomic theory and

More information

AP Chemistry Common Ion Effect; 16.6 ionization constants, will. Equilibria with Weak Acids and and the preparation of buffer

AP Chemistry Common Ion Effect; 16.6 ionization constants, will. Equilibria with Weak Acids and and the preparation of buffer Instructional Unit Acid-Base Equibria 16.1 Acid-Ionizaation Equilibria; Students will perform Students will distinguish Oral response, written 3.1.12C, 16.2 Polyprotic Acids; 16.3 Base- calculations involving

More information

Organic Chemistry Curriculum Content Outline

Organic Chemistry Curriculum Content Outline Organic Chemistry 2014-15 Curriculum Content Outline CHEM 0203: Organic Structure and Reactivity 1. Structure & Bonding (Brief Review from General Chemistry) a. Ionic & Covalent Bonding b. Lewis Structures

More information

Chemistry Class 11 Syllabus

Chemistry Class 11 Syllabus Chemistry Class 11 Syllabus Course Structure Unit Title Marks I Basic Concepts of Chemistry 11 II Structure of Atom III Classification of Elements & Periodicity in Properties 4 IV Chemical Bonding and

More information

Chapter 25. Organic and Biological Chemistry. Organic and

Chapter 25. Organic and Biological Chemistry. Organic and Chapter 25 Calculate grade: (Add exam1 - exam 4 scores)x1.5 Add 7 best quizzes (each quiz is worth 29) Gives you the # points you have so far. Final (worth 200 points) Grades: 800-4 750-3.5 700-3 650-2.5

More information

DEPARTMENT OF CHEMISTRY KHEMUNDI COLLEGE, DIGAPAHANDI; GANJAM Course Objective and Course Outcome

DEPARTMENT OF CHEMISTRY KHEMUNDI COLLEGE, DIGAPAHANDI; GANJAM Course Objective and Course Outcome 1 DEPARTMENT OF CHEMISTRY KHEMUNDI COLLEGE, DIGAPAHANDI; GANJAM Course Objective and Course Outcome Class: BSc Semester: 1st B.sc. Semester -I (C-1 Inorganic chemistry-1) To make students to know about

More information

GCSE to A-level progression

GCSE to A-level progression . GCSE to A-level progression AQA A-level Chemistry is a natural next stage from the GCSE course and so there are many recognisable topics that are taken a stage further. Some topics, such as atomic structure,

More information

CLASS VIII XI. Month Unit Topic Sub Topic

CLASS VIII XI. Month Unit Topic Sub Topic April- Bridge Some Basic General Introduction : Importance and scope of May Course Concepts of chemistry. Historical approach to particulate Chemistry nature of matter, laws of chemical combination, Dalton

More information

Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers

Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers Chapter Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers Ch 1-Structure and bonding Ch 2-Polar covalent bonds: Acids and bases McMurry, J. (2004) Organic Chemistry 6 th Edition

More information

Pearson Edexcel AS and A level Chemistry

Pearson Edexcel AS and A level Chemistry Pearson Edexcel AS and A level Chemistry What s Changed? Level Topic Spec Points New Content Included Content Not Included in the New Specification Implications of the New Spec 1-5 Greater clarity in terms

More information

CHEMISTRY 263 HOME WORK

CHEMISTRY 263 HOME WORK Lecture Topics: CHEMISTRY 263 HOME WORK Module7: Hydrogenation of Alkenes Hydrogenation - syn and anti- addition - hydrogenation of alkynes - synthesis of cis-alkenes -synthesis of trans-alkenes Text sections:

More information

AP Chemistry Standards and Benchmarks

AP Chemistry Standards and Benchmarks Standard: Understands and applies the principles of Scientific Inquiry Benchmark 1: Scientific Reasoning Course Level Benchmarks A. Formulates and revises scientific explanations and models B. Understands

More information

Boardworks A2 Chemistry

Boardworks A2 Chemistry Boardworks A2 Chemistry Organic Synthesis 34 slides 13 Flash activities Optical isomerism Introduction to light waves Animation illustrating the nature of polarized light Optically active compounds, enantiomers

More information

OCR (A) Chemistry A-level. Module 6: Organic Chemistry and Analysis

OCR (A) Chemistry A-level. Module 6: Organic Chemistry and Analysis OCR (A) Chemistry A-level Module 6: Organic Chemistry and Analysis Organic Synthesis Notes by Adam Robertson DEFINITIONS Heterolytic fission: The breaking of a covalent bond when one of the bonded atoms

More information

About the GRE Chemistry Subject Test p. 1 About the GRE Chemistry Subject Test GRE Chemistry Topics Test Dates Testing Fee Test Format Testing Time

About the GRE Chemistry Subject Test p. 1 About the GRE Chemistry Subject Test GRE Chemistry Topics Test Dates Testing Fee Test Format Testing Time About the GRE Chemistry Subject Test p. 1 About the GRE Chemistry Subject Test GRE Chemistry Topics Test Dates Testing Fee Test Format Testing Time Scoring To Guess or Not to Guess On the Day of the Test

More information

NANYANG TECHNOLOGICAL UNIVERSITY ENTRANCE EXAMINATION SYLLABUS FOR INTERNATIONAL STUDENTS CHEMISTRY

NANYANG TECHNOLOGICAL UNIVERSITY ENTRANCE EXAMINATION SYLLABUS FOR INTERNATIONAL STUDENTS CHEMISTRY NANYANG TECHNOLOGICAL UNIVERSITY ENTRANCE EXAMINATION SYLLABUS FOR INTERNATIONAL STUDENTS OAFA/01/07 STRUCTURE OF EXAMINATION PAPER CHEMISTRY 1. There will be one 2-hour paper consisting of two sections.

More information

General Chemistry (Third Quarter)

General Chemistry (Third Quarter) General Chemistry (Third Quarter) This course covers the topics shown below. Students navigate learning paths based on their level of readiness. Institutional users may customize the scope and sequence

More information

Page 7 of 30 CHEMISTRY

Page 7 of 30 CHEMISTRY Page 7 of 30 2 CHEMISTRY Page 8 of 30 SYLLABUS PHYSICAL CHEMISTRY 1A. Fundamental Concepts A. Define relative atomic, isotopic, molecular and formula masses, based on the 12-C scale B. Explain mole in

More information

Mechanisms. . CCl2 F + Cl.

Mechanisms. . CCl2 F + Cl. Mechanisms 1) Free radical substitution Alkane à halogenoalkane Initiation: Propagation: Termination: Overall: 2) Ozone depletion UV light breaks the C Cl bond releasing chlorine radical CFCl 3 F à. CCl2

More information

Module9. Nuclear Magnetic Resonance Spectroscopy Nuclear Magnetic Resonance (NMR) spectroscopy - Chemical shift - Integration of signal area

Module9. Nuclear Magnetic Resonance Spectroscopy Nuclear Magnetic Resonance (NMR) spectroscopy - Chemical shift - Integration of signal area 1 CHEMISTRY 263 HOME WORK Lecture Topics: Module7. Hydrogenation of Alkenes The Function of the Catalyst - Syn and anti- addition Hydrogenation of Alkynes - Syn- addition of hydrogen: Synthesis of cis-alkenes

More information

Downloaded from

Downloaded from 1 Class XII Chemistry Chapter: Alcohols, Phenols And Ethers Top concepts: 1. Structure of alcohols, phenols and ethers: 2. Preparation of alcohols: 3. Preparation of phenols: 2 4. Physical properties of

More information

AP Chemistry II Curriculum Guide Scranton School District Scranton, PA

AP Chemistry II Curriculum Guide Scranton School District Scranton, PA AP Chemistry II Scranton School District Scranton, PA AP Chemistry II Prerequisite: Honors Chemistry Be in compliance with the SSD Honors and AP Criteria Policy AP Chemistry II is offered in grades 11

More information

Chapter 10: Carboxylic Acids and Their Derivatives

Chapter 10: Carboxylic Acids and Their Derivatives Chapter 10: Carboxylic Acids and Their Derivatives The back of the white willow tree (Salix alba) is a source of salicylic acid which is used to make aspirin (acetylsalicylic acid) The functional group

More information

SPECIFIC AIMS PROGRAM CHEMISTRY. I year (1st semester) A.Y

SPECIFIC AIMS PROGRAM CHEMISTRY. I year (1st semester) A.Y I year (1st semester) A.Y. 2017-2018 MARINI S. COORDINATOR Scientific Field CHEMISTRY AND INTRODUCTORY BIOCHEMISTRY TUTOR CFU BIO/10 Chemistry and Introductory Biochemistry Marini Stefano 5 BIO/10 Chemistry

More information

ALCOHOLS AND PHENOLS

ALCOHOLS AND PHENOLS ALCOHOLS AND PHENOLS ALCOHOLS AND PHENOLS Alcohols contain an OH group connected to a a saturated C (sp3) They are important solvents and synthesis intermediates Phenols contain an OH group connected to

More information

Course Information. Instructor Information

Course Information. Instructor Information Jordan University of Science and Technology Department of Chemistry Course Syllabus Fall 2018/2019 Course Information Course Number: CHEM 108 Course Name: General and Organic Chemistry Credit Hours: 4

More information

Chemistry. Atomic and Molecular Structure

Chemistry. Atomic and Molecular Structure Chemistry Atomic and Molecular Structure 1. The periodic table displays the elements in increasing atomic number and shows how periodicity of the physical and chemical properties of the elements relates

More information

Basic Concepts of Chemistry

Basic Concepts of Chemistry Basic Concepts of Chemistry Malone, L ISBN-13: 9780471741541 Table of Contents PROLOGUE INTRODUCTION TO THE STUDY OF CHEMISTRY A. The Creation of Matter B. The Mystery of Fire C. The Scientific Method

More information

About the Authors Preface Student's Guide to Using this Text Matter-Its Properties and Measurement The Scientific Method Properties of Matter

About the Authors Preface Student's Guide to Using this Text Matter-Its Properties and Measurement The Scientific Method Properties of Matter About the Authors Preface Student's Guide to Using this Text Matter-Its Properties and Measurement The Scientific Method Properties of Matter Classification of Matter Measurement of Matter: SI (Metric)

More information

UNIT 3 CHEMISTRY. Fundamental Principles in Chemistry

UNIT 3 CHEMISTRY. Fundamental Principles in Chemistry UNIT 3 CHEMISTRY NOTE: This list has been compiled based on the topics covered in the 2016 Master Class program. Once all of the 2017 Chemistry program materials have been finalised, this summary will

More information

Chapter 25 Organic and Biological Chemistry

Chapter 25 Organic and Biological Chemistry Chapter 25 Organic and Biological Chemistry Organic Chemistry The chemistry of carbon compounds. Carbon has the ability to form long chains. Without this property, large biomolecules such as proteins,

More information

75. A This is a Markovnikov addition reaction. In these reactions, the pielectrons in the alkene act as a nucleophile. The strongest electrophile will

75. A This is a Markovnikov addition reaction. In these reactions, the pielectrons in the alkene act as a nucleophile. The strongest electrophile will 71. B SN2 stands for substitution nucleophilic bimolecular. This means that there is a bimolecular rate-determining step. Therefore, the reaction will follow second-order kinetics based on the collision

More information

SYLLABUS OF THE CHEMISTRY PRACTICALS ( ) CLASS-XII

SYLLABUS OF THE CHEMISTRY PRACTICALS ( ) CLASS-XII Experiment 1. SYLLABUS OF THE CHEMISTRY PRACTICALS (28-19) CLASS-XII Qualitative analysis: To analyze the given salt for acidic and basic radicals. (08 marks) Experiment 2. Volumetric analysis: (08 marks)

More information

Students are required to bring these definitions HAND written on separate 3 in X 5 in index cards by chapters, the first week of school

Students are required to bring these definitions HAND written on separate 3 in X 5 in index cards by chapters, the first week of school Students are required to bring these definitions HAND written on separate 3 in X 5 in index cards by chapters, the first week of school 2015-2016 Have a Great Summer!!! Ms. Charles LAB SAFETY/Vocabulary

More information

KOT 222 Organic Chemistry II

KOT 222 Organic Chemistry II KOT 222 Organic Chemistry II Course Objectives: 1) To introduce the chemistry of alcohols and ethers. 2) To study the chemistry of functional groups. 3) To learn the chemistry of aromatic compounds and

More information

21.1 Introduction Carboxylic Acids Nomenclature of Carboxylic Acids. Acids Structure and Properties of Carboxylic Acids.

21.1 Introduction Carboxylic Acids Nomenclature of Carboxylic Acids. Acids Structure and Properties of Carboxylic Acids. 21.1 Introduction Carboxylic Acids Carboxylic acids are abundant in nature and in pharmaceuticals. 21.1 Introduction Carboxylic Acids The US produces over 2.5 million tons of acetic acid per year, which

More information

GSEB CURRICULUM. Standard XI Chemistry Content List

GSEB CURRICULUM. Standard XI Chemistry Content List An ISO 9001-2008 Certified Organization GSEB CURRICULUM Standard XI Content List Designmate (I) PVT LTD Horizon, Swati Society Road, Darpan Circle, Ahmedabad 380014 www.des ignm ate.com Follow us on Reduce

More information

Chapter 20: Carboxylic Acids and Nitriles شیمی آلی 2

Chapter 20: Carboxylic Acids and Nitriles شیمی آلی 2 Chapter 20: Carboxylic Acids and Nitriles شیمی آلی 2 Dr M. Mehrdad University of Guilan, Department of Chemistry, Rasht, Iran m-mehrdad@guilan.ac.ir Based on McMurry s Organic Chemistry, 7 th edition The

More information

Norwich City Schools AP Chemistry

Norwich City Schools AP Chemistry Topic: Structure of Matter Students will use inquiry based methods to investigate scientific concepts Students will examine and investigate the structure, properties, and interactions of matter. Students

More information

Carboxylic Acids and Nitriles

Carboxylic Acids and Nitriles Carboxylic Acids and Nitriles Why this Chapter? Carboxylic acids present in many industrial processes and most biological processes They are the starting materials from which other acyl derivatives are

More information

Alkyl phenyl ketones are usually named by adding the acyl group as prefix to phenone.

Alkyl phenyl ketones are usually named by adding the acyl group as prefix to phenone. Aldehydes, Ketones and Carboxylic Acids Nomenclature of aldehydes and ketones Aldehydes: Often called by their common names instead of IUPAC names. Ketones: Derived by naming two alkyl or aryl groups bonded

More information

Class XII: Chemistry Chapter 13: Amines Top concepts

Class XII: Chemistry Chapter 13: Amines Top concepts Class XII: Chemistry Chapter 13: Amines Top concepts 1. Amines are regarded as derivatives of ammonia in which one, two or all three hydrogen atoms are replaced by alkyl or aryl group 2. Classification

More information

Year 13 Chemistry (NCEA) Student Information

Year 13 Chemistry (NCEA) Student Information Year 13 Chemistry (NCEA) Student Information Science Department Onslow College 2015 Introduction Year 13 Chemistry is a full year course, of five topics, that works towards gaining Level Three credits

More information

Introduction to Chemistry

Introduction to Chemistry Introduction to Chemistry 978-1-63545-054-5 To learn more about all our offerings Visit Knewton.com Source Author(s) (Text or Video) Title(s) Link (where applicable) OpenStax Senior Contributing Authors:

More information

Organic and Biochemical Molecules. 1. Compounds composed of carbon and hydrogen are called hydrocarbons.

Organic and Biochemical Molecules. 1. Compounds composed of carbon and hydrogen are called hydrocarbons. Organic and Biochemical Molecules 1. Compounds composed of carbon and hydrogen are called hydrocarbons. 2. A compound is said to be saturated if it contains only singly bonded carbons. Such hydrocarbons

More information

Concepts of Class-XI which are very often used in Class-XII ( Which needs to be mastered for better performance in Class-XII)

Concepts of Class-XI which are very often used in Class-XII ( Which needs to be mastered for better performance in Class-XII) Downloaded from Concepts of Class-XI which are very often used in Class-XII ( Which needs to be mastered for better performance in Class-XII) Downloaded from Downloaded from ORGANIC CHEMISTRY -- Some Basic

More information

TERMWISE SYLLABUS SESSION CLASS- XI SUBJECT: CHEMISTRY TERM-I

TERMWISE SYLLABUS SESSION CLASS- XI SUBJECT: CHEMISTRY TERM-I TERMWISE SYLLABUS SESSION-2018-19 CLASS- XI SUBJECT: CHEMISTRY TERM-I July-2018 to Sept 2018 CONTENTS Unit I: Some Basic Concepts of Chemistry General Introduction: Importance and scope of chemistry. Nature

More information

Organic Chemistry SL IB CHEMISTRY SL

Organic Chemistry SL IB CHEMISTRY SL Organic Chemistry SL IB CHEMISTRY SL 10.1 Fundamentals of organic chemistry Understandings: A homologous series is a series of compounds of the same family, with the same general formula, which differ

More information

2/25/2013. Electronic Configurations

2/25/2013. Electronic Configurations 1 2 3 4 5 Chapter 2 Chemical Principles The Structure of Atoms Chemistry is the study of interactions between atoms and molecules The atom is the smallest unit of matter that enters into chemical reactions

More information

UNIT 2 REVISION CHECKLIST. a) understand that reactions are either exothermic or endothermic and apply the sign convention

UNIT 2 REVISION CHECKLIST. a) understand that reactions are either exothermic or endothermic and apply the sign convention UNIT 2 REVISION CHECKLIST Topic 2.1 Energetics a) understand that reactions are either exothermic or endothermic and apply the sign convention b) define the term enthalpy change, recall what standard conditions

More information

VOCABULARY. Set #2. Set #1

VOCABULARY. Set #2. Set #1 VOCABULARY Set #1 1. Absolute zero 2. Accepted value 3. Accuracy 4. Celsius scale 5. Conversion factor 6. Density 7. Dimensional analysis 8. Experimental value 9. Gram 10. International system of units

More information

Unit title: Chemistry for Applied Biologists

Unit title: Chemistry for Applied Biologists Unit title: Chemistry for Applied Biologists Unit code: K/601/0292 QCF level: 5 Credit value: 15 Aim This unit covers bonding, thermodynamics, reaction rates, equilibrium, oxidation and reduction and organic

More information

Chapter 24. Amines. Based on McMurry s Organic Chemistry, 7 th edition

Chapter 24. Amines. Based on McMurry s Organic Chemistry, 7 th edition Chapter 24. Amines Based on McMurry s Organic Chemistry, 7 th edition Amines Organic Nitrogen Compounds Organic derivatives of ammonia, NH 3, Nitrogen atom with a lone pair of electrons, making amines

More information

Chapter 25: The Chemistry of Life: Organic and Biological Chemistry

Chapter 25: The Chemistry of Life: Organic and Biological Chemistry Chemistry: The Central Science Chapter 25: The Chemistry of Life: Organic and Biological Chemistry The study of carbon compounds constitutes a separate branch of chemistry known as organic chemistry The

More information

Course Syllabus. Department: Science & Technology. Date: April I. Course Prefix and Number: CHM 212. Course Name: Organic Chemistry II

Course Syllabus. Department: Science & Technology. Date: April I. Course Prefix and Number: CHM 212. Course Name: Organic Chemistry II Department: Science & Technology Date: April 2012 I. Course Prefix and Number: CHM 212 Course Name: Organic Chemistry II Course Syllabus Credit Hours and Contact Hours: 5 credit hours and 7 (3:3:1) contact

More information

Switching to OCR A from AQA

Switching to OCR A from AQA Switching to OCR A from AQA The content within the OCR Chemistry A specification covers the key concepts of chemistry and will be very familiar. We ve laid it out in a logical progression to support co-teaching

More information

EASTERN ARIZONA COLLEGE General Organic Chemistry I

EASTERN ARIZONA COLLEGE General Organic Chemistry I EASTERN ARIZONA COLLEGE General Organic Chemistry I Course Design 2015-2016 Course Information Division Science Course Number CHM 235 (SUN# CHM 2235) Title General Organic Chemistry I Credits 4 Developed

More information

Amines Reading Study Problems Key Concepts and Skills Lecture Topics: Amines: structure and nomenclature

Amines Reading Study Problems Key Concepts and Skills Lecture Topics: Amines: structure and nomenclature Amines Reading: Wade chapter 19, sections 19-1-19-19 Study Problems: 19-37, 19-39, 19-40, 19-41, 19-44, 19-46, 19-47, 19-48, 19-51, 19-54 Key Concepts and Skills: Explain how the basicity of amines varies

More information

Unit title: Organic Chemistry

Unit title: Organic Chemistry Unit title: Organic Chemistry Unit code: R/601/0352 QCF level: 4 Credit value: 15 Aim This unit develops the principles and practical techniques of organic chemistry. Rationalisation of structure and bonding

More information

DEPARTMENT: Chemistry

DEPARTMENT: Chemistry CODE CHEM 204 TITLE: Organic Chemistry II INSTITUTE: STEM DEPARTMENT: Chemistry COURSE DESCRIPTION: A continuation of CHEM-203, students will extend their studies into topics including aromatic hydrocarbons,

More information

Successful completion of either Pre AP Chemistry or both Integrated Science I and II, and Algebra I.

Successful completion of either Pre AP Chemistry or both Integrated Science I and II, and Algebra I. AP CHEMISTRY SYLLABUS PREREQUISITES: Successful completion of either Pre AP Chemistry or both Integrated Science I and II, and Algebra I. TEXT: Chemistry, Principles and Reactions, 5 th ed., Thomson/Brooks/Cole,

More information

Molecular Geometry: VSEPR model stand for valence-shell electron-pair repulsion and predicts the 3D shape of molecules that are formed in bonding.

Molecular Geometry: VSEPR model stand for valence-shell electron-pair repulsion and predicts the 3D shape of molecules that are formed in bonding. Molecular Geometry: VSEPR model stand for valence-shell electron-pair repulsion and predicts the 3D shape of molecules that are formed in bonding. Sigma and Pi Bonds: All single bonds are sigma(σ), that

More information

MARLBORO CENTRAL SCHOOL DISTRICT-CURRICULUM MAP. Subject: AP Chemistry 2015/16

MARLBORO CENTRAL SCHOOL DISTRICT-CURRICULUM MAP. Subject: AP Chemistry 2015/16 MARLBORO CENTRAL SCHOOL DISTRICT-CURRICULUM MAP Subject: AP Chemistry 205/6 Title or Topics (Unit organizing idea) Concepts (understandings) Tasks (What students actually do) Major Assessments (Tests,

More information

Chemistry PhD Qualifying Exam Paper 1 Syllabus

Chemistry PhD Qualifying Exam Paper 1 Syllabus Chemistry PhD Qualifying Exam Paper 1 Syllabus Preface This document comprises all topics relevant for Paper 1 of the Ph.D. Qualifying Exam in Chemistry at Eastern Mediterranean University, in accordance

More information

TOK: The relationship between a reaction mechanism and the experimental evidence to support it could be discussed. See

TOK: The relationship between a reaction mechanism and the experimental evidence to support it could be discussed. See Option G: Further organic chemistry (15/22 hours) SL students study the core of these options and HL students study the whole option (the core and the extension material). TOK: The relationship between

More information

CHEMISTRY Std. XII (Theory)

CHEMISTRY Std. XII (Theory) Unit 1: Solid State CHEMISTRY Std. XII (Theory) Classification of solids based on different forces; molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea),unit

More information

DAMIETTA UNIVERSITY. Energy Diagram of One-Step Exothermic Reaction

DAMIETTA UNIVERSITY. Energy Diagram of One-Step Exothermic Reaction DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE 5 Dr Ali El-Agamey 1 Energy Diagram of One-Step Exothermic Reaction The vertical axis in this graph represents the potential energy. The transition

More information

Chapter 7: Alcohols, Phenols and Thiols

Chapter 7: Alcohols, Phenols and Thiols Chapter 7: Alcohols, Phenols and Thiols 45 -Alcohols have the general formula R-OH and are characterized by the presence of a hydroxyl group, -OH. -Phenols have a hydroxyl group attached directly to an

More information

PhET Interactive Chemistry Simulations Aligned to an Example General Chemistry Curriculum

PhET Interactive Chemistry Simulations Aligned to an Example General Chemistry Curriculum PhET Interactive Chemistry Simulations Aligned to an Example General Chemistry Curriculum Alignment is based on the topics and subtopics addressed by each sim. Sims that directly address the topic area

More information

DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE

DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE 6 Dr Ali El-Agamey 1 Oxidation States Easy for inorganic salts: CrO 4 2- reduced to Cr 2 O 3. KMnO 4 reduced to MnO 2. Oxidation: Gain of O,

More information

CBSE Class 11 Chemistry syllabus

CBSE Class 11 Chemistry syllabus CBSE Class 11 Chemistry syllabus 1 CLASS XI (THEORY) (Total Periods 180) Unit I: Some Basic Concepts of Chemistry (Periods 14) General Introduction: Importance and scope of chemistry. Historical approach

More information

Carboxylic Acids O R C + H + O - Chemistry 618B

Carboxylic Acids O R C + H + O - Chemistry 618B arboxylic Acids R H R + H + - R - Nomenclature - IUPA IUPA names: drop the -e from the parent alkane and add the suffix -oic acid If the compound contains a carbon-carbon double bond, change the infix

More information

Montgomery County Community College CHE 132 Chemistry for Technology II 4-3-3

Montgomery County Community College CHE 132 Chemistry for Technology II 4-3-3 Montgomery County Community College CHE 132 Chemistry for Technology II 4-3-3 COURSE DESCRIPTION: This course will present a brief overview of Nuclear Chemistry. The major portion of the semester will

More information

CHEMISTRY. Time : 3 Hrs. Max. Marks : 70

CHEMISTRY. Time : 3 Hrs. Max. Marks : 70 CHEMISTRY Time : 3 Hrs. Max. Marks : 70 General instructions 1. All questions are compulsory. 2. Q.no. 1-5 are very short answer questions & carry 1 marks each Section-A. 3. Q.no. 6-12 are short answer

More information

Course Title. All students are expected to take the College Board Advanced Placement Exam for Chemistry in May.

Course Title. All students are expected to take the College Board Advanced Placement Exam for Chemistry in May. Course Title ERHS Chemistry A (AP) Description/ Target group This is two-semester laboratory course of inorganic chemistry, designed for college bound students entering the fields of science and engineering,

More information

Department Curriculum and Assessment Outline

Department Curriculum and Assessment Outline Timing Department: Science Year Group: 0 Teaching, learning and assessment during the course: Chemistry (Combined) C/C States of matter/methods of Separating and purifying substances C3 Atomic structure

More information

CHEMISTRY MAJOR PANEL

CHEMISTRY MAJOR PANEL CHEMISTRY MAJOR PANEL Course Approval Criteria Updated Spring 17 5/17/17 An institutionally-approved representative syllabus in electronic format from a recent offering is required for the panel to review.

More information

ORGANIC - EGE 5E CH. 2 - COVALENT BONDING AND CHEMICAL REACTIVITY

ORGANIC - EGE 5E CH. 2 - COVALENT BONDING AND CHEMICAL REACTIVITY !! www.clutchprep.com CONCEPT: HYBRID ORBITAL THEORY The Aufbau Principle states that electrons fill orbitals in order of increasing energy. If carbon has only two unfilled orbitals, why does it like to

More information

Sectional Solutions Key

Sectional Solutions Key Sectional Solutions Key 1. For the equilibrium: 2SO 2 (g) + O 2 (g) 2SO 3 (g) + 188 kj, the number of moles of sulfur trioxide will increase if: a. the temperature of the system is increased (at constant

More information

Calculate a rate given a species concentration change.

Calculate a rate given a species concentration change. Kinetics Define a rate for a given process. Change in concentration of a reagent with time. A rate is always positive, and is usually referred to with only magnitude (i.e. no sign) Reaction rates can be

More information

Alabama. Department of. Postsecondary Education

Alabama. Department of. Postsecondary Education Date Adopted: July 1, 1998 Date Reviewed: December 1, 1999 Date Revised: 1999, 2007, 2011, 2013 Alabama Department of Postsecondary Education Representing Alabama s Public Two-Year College System Jefferson

More information

Organic Chemistry I Dr Alex Roche Organic chemistry is the chemistry of Carbon and its compounds. Organic molecules constitute the essence of life (fats, sugars, proteins, DNA), and also permeate our everyday

More information

Chapter 19: Amines. Introduction

Chapter 19: Amines. Introduction Chapter 19: Amines Chap 19 HW: (be able to name amines); 37, 39, 41, 42, 44, 46, 47, 48, 53-55, 57, 58 Introduction Organic derivatives of ammonia. Many are biologically active. Chap 19: Amines Slide 19-2

More information