Supplementary Information
|
|
- Charla Sanders
- 5 years ago
- Views:
Transcription
1 Supplementary Information Ni 2 P(O)/Fe 2 P(O) Interface Can Boost Oxygen Evolution Electrocatalysis Peng Fei Liu, Xu Li, Shuang Yang, Meng Yang Zu, Porun Liu, Bo Zhang, Li Rong Zheng, # Huijun Zhao, and Hua Gui Yang *, Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai , China Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University, Queensland 4222, Australia State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai , China # Institute of High Energy Physics, Chinese Academy of Sciences, Beijing , China * Correspondence and requests for materials should be addressed to H. G. Y. ( hgyang@ecust.edu.cn) (H.G.Y).
2 Experimental Section Chemicals. Ammonium fluoride (NH 4 F), nickel (II) nitrate hexahydrate (Ni(NO 3 ) 2 6H 2 O) and ferric (III) nitrate nonahydrate (Fe(NO 3 ) 3 9H 2 O) were obtained from Sinopharm Chemical Regent Co., Ltd. Urea was purchased from Shanghai Lingfeng Chemical Regent Co., Ltd. Sodium hypophosphite (NaH 2 PO 2 ) was obtained from Aladdin. Nafion (5 wt%) was obtained from Sigma-Aldrich. Iridium (IV) oxide (IrO 2 ) were obtained from Strem Chemicals, Inc. All chemicals were of analytical grade and used without any further purification. Ni foam was washed in 6 M HCl, ethanol and deionized water several times to ensure the surface of the Ni foam was well cleaned before use. Synthesis of Ni(OH) x precursor. The hydroxide precursors were synthesized by a hydrothermal method. For the preparation of Ni(OH) x precursor, urea (10 mmol) and Ni(NO 3 ) 2 6H 2 O (2 mmol) was added into deionized water (40 ml) for continuous stirring of 15 min, and then injected into a 50 ml Teflon-lined stainless steel autoclave. Afterwards, 3 pieces of Ni foam (with area of 3 cm * 0.5 cm) were placed in the autoclave and kept at 100 o C for 10 h. After the autoclave cooled down slowly at room temperature, the samples were collected and washed with water and ethanol several times and then dried at 60 o C for 12 h. Synthesis of S-Ni(OH) x /Fe(OH) x precursor. The synthetic procedure was similar to the synthesis of Ni(OH) x precursor except that the precursors containing urea (10 mmol), NH 4 F (8 mmol) and Fe(NO 3 ) 3 9H 2 O (2 mmol) and being kept at 120 o C for 10 h. Synthesis of M-Ni(OH) x /Fe(OH) x precursor. After synthesis of S-Ni(OH) x /Fe(OH) x precursor, 3 pieces of S-Ni(OH) x /Fe(OH) x decorated Ni foam were placed in the autoclave which containing urea (10 mmol) and Ni(NO 3 ) 2 6H 2 O (2 mmol) dissolved in the deionized water (40 ml). Then the autoclave was kept at 100 o C for 10 h. After the autoclave cooled down slowly at room temperature, the samples were collected and washed with water and ethanol several times and then dried at 60 o C for 12 h. Synthesis of corresponding phosphides. To synthesize phosphides, NaH 2 PO 2 (1.5 g) was placed at the upstream side of the tube furnace and the corresponding hydroxide precursors were placed at the downstream side. Subsequently, the samples were heated to 400 C, and then stayed for 120 min under Ar gas flowing at 75 s.c.c.m. We
3 treated all the hydroxide precursors following the above step, to finally obtain Ni 2 P, S-Ni 2 P/Fe 2 P and M-Ni 2 P/Fe 2 P samples from Ni(OH) x, S-Ni(OH) x /Fe(OH) x and M-Ni(OH) x /Fe(OH) x precursors, respectively. Synthesis of one-pot derived NiFeP. To prepare the hydroxide precursor, the synthetic procedure was similar to the synthesis of Ni(OH) x precursor except that the precursors containing urea (10 mmol), NH 4 F (8 mmol), Ni(NO 3 ) 2 6H 2 O (1 mmol) and Fe(NO 3 ) 3 9H 2 O (1 mmol) and being kept at 120 o C for 10 h. After that, the phosphidation treatment was similar to synthesis of Ni 2 P and other phosphides. Synthesis of corresponding annealed oxides. To obtain oxide samples, the heat treatment was directly performed under air environment and corresponding hydroxide precursors were annealed at 500 o C for 2 h with an increment of 2 o C/min. We treated all the hydroxide precursors following the above step, to finally obtain Ni(OH) x -DO, S-Ni(OH) x /Fe(OH) x -DO and M-Ni(OH) x /Fe(OH) x -DO samples from Ni(OH) x, S-Ni(OH) x /Fe(OH) x and M-Ni(OH) x /Fe(OH) x precursors, respectively. Preparation of IrO 2 decorated electrodes. We firstly prepared the ink solution containing IrO 2 (10 mg), Nafion (40 µl) and ethanol (1 ml) which were under ultrasonic treatment for 30 min. Then the Ni foam (with exposure area of 0.5 cm * 0.5 cm) was immersed into the ink solution for 30 s and dried with evaporation of ethanol. The immersing loading treatment was repeated for 8 times, and the final loading of IrO 2 was about 3.2 mg/cm 2. Electrochemical measurements. All the OER electrochemical tests were performed in a conventional three-electrode system at an electrochemical station (CHI 660E), using Ag/AgCl (3.5 M KCl solution) electrode as the reference electrode, a graphite rod (spectral purity, 3 mm in diameter) as the counter electrode and as-synthesized catalysts on Ni foam as the working electrode. The catalyst geometric mass loadings were calculated from the weight increment after catalyst preparation. The mass loadings of Ni 2 P, S-Ni 2 P/Fe 2 P, M-Ni 2 P/Fe 2 P and NiFeP are around 3.0, 3.5, 4.0 and 3.4 mg/cm 2, respectively. Linear sweep voltammetry (LSV) with the backward scan rate of 1 mv/s was conducted in 1 M KOH (ph 13.6) purged by Ar for 30 min at room temperature, to avoid the oxidative peak and possible capacitance current. All potentials were referenced to reversible hydrogen electrode (RHE) by following calculations: E RHE = E Ag/AgCl ph All the LSV curves were not ir-corrected. To obtain the onset overpotential, LSV curves were conducted with the
4 backward scan rate of 1 mv/s, and identify the point of overpotential across the X axis. AC impedance measurements were carried out in the same configuration when the working electrode was biased at a certain overpotential from 10 5 Hz to 0.1 Hz with an AC voltage of 5 mv. The chronopotentiometric curves were corrected with ir-compensation, and the equivalent series resistance (R s ) can be obtained from the EIS Nyquist plot as the first intercept of the main arc with the real axis. The stability test was conducted at the constant current density of 40 ma/cm 2 for motivate OER process. The ECSA was determined by measuring the capacitive current associated with double-layer charging from the scan-rate dependence of cyclic voltammograms (CVs). The potential window of cyclic voltammograms was 1.15 to 1.25 V vs. RHE. The double layer capacitance (C dl ) was estimated by plotting the j = (j a - j c ) 1.25 V against the scan rate, respectively. The liner slope is twice of the double layer capacitance C dl. The ECSA of each sample was calculated according the equation: ECSA = S C dl /C s, in which S stands for the real geometric area of the Ni foam electrode and C s represents the specific capacitance (assuming the value of the catalysts for OER in 1 M KOH is mf/cm 2 ). Electrochemical oxidation treatments. For OER tests, the catalysts were cycled 100 times using cyclic voltammetry (CV) from 1.2 to 1.8 V (vs. RHE) with the scan rate of 50 mv/s, to fully activate the catalyst and generate active oxidized layers at OER condition. For different characterizations, such as FESEM, TEM, and XAFS analysis, the M-Ni 2 P/Fe 2 P-O sample and controlled samples were obtained after treated at the potential of 1.6 V (vs. RHE) for about 2 hours. For XRD and XPS analysis, the M-Ni 2 P/Fe 2 P-O sample and controlled samples were obtained after chronopotentiometric test at the current density of 40 ma/cm 2 for different time. Characterizations. The morphologies and structures of the samples were characterized by scanning electron microscopy (SEM, Hitachi S4800) and transmission electron microscopy (TEM, JEM-2100F and Philips Tecnai F20). The crystal structure was determined by X-ray diffraction (XRD, D/max2550V). Furthermore, the chemical states of the elements in catalysts were studied by X-ray photoelectron spectroscopy (XPS, Kratos Axis Ultra DLD), and the binding energy of C 1s peak at ev was taken as an internal standard.
5 Figure S1. Structure schematic for M-Ni 2 P/Fe 2 P precatalysts in-situ transferring to M-Ni 2 P/Fe 2 P-O postcatalysts, with active oxidized surface layers and conductive bulk phosphide.
6 Figure S2. FESEM images of M-Ni(OH) x /Fe(OH) x at different magnifications.
7 Figure S3. The visual difference between S-Ni 2 P/Fe 2 P and M-Ni 2 P/Fe 2 P, revealing that M-Ni 2 P/Fe 2 P owns more active units, with more Ni 2 P/Fe 2 P interfaces as precatalysts to boost OER.
8 Figure S4. FESEM images of (a),(b) Ni(OH) x and (c),(d) Ni 2 P.
9 Figure S5. FESEM images of (a-c) S-Ni(OH)x/Fe(OH)x and (d-f) S-Ni2P/Fe2P.
10 Figure S6. SEM images of the precursor of NiFeP (NiFe(OH) x ), NiFeP and NiFeP after stability test (NiFeP-O).
11 Figure S7. Cross-section TEM image of M-Ni 2 P/Fe 2 P and corresponding elemental mapping images of Ni, Fe and P.
12 Figure S8. XRD patterns of Ni 2 P, S-Ni 2 P/Fe 2 P and M-Ni 2 P/Fe 2 P samples before OER test, respectively.
13 Figure S9. XRD patterns of (a) Ni(OH) x annealing derived oxides (Ni(OH) x -DO), (b) S-Ni(OH) x /Fe(OH) x annealing derived oxides (S-Ni(OH) x /Fe(OH) x -DO) and (c) M-Ni(OH) x /Fe(OH) x annealing derived oxides (M-Ni(OH) x /Fe(OH) x -DO), respectively.
14 Figure S10. XRD patterns of NiFe(OH) x and M-Ni(OH) x /Fe(OH) x precursors. Notes: The precursor of NiFeP (NiFe(OH) x ) kept the layered double hydroxide structure (PDF# ), in which Ni and Fe element were homogeneously dispersed. For comparison, the precursor of M-Ni 2 P/Fe 2 P (M-Ni(OH) x /Fe(OH) x ) showed relatively bad crystallinity, with diffraction peaks which might correspond to FeOOH (PDF# ). Although we couldn t clearly detect the crystalline structure of M-Ni(OH) x /Fe(OH) x, we conclude that the structure of M-Ni(OH) x /Fe(OH) x is different from NiFe(OH) x.
15 Figure S11. XRD patterns of NiFeP and M-Ni 2 P/Fe 2 P samples, revealing no obvious difference between these two catalysts.
16 Figure S12. XPS spectra of Ni and Fe 2p region for NiFe(OH) x and M-Ni(OH) x /Fe(OH) x precursors.
17 Figure 13. XPS spectra of Ni and Fe 2p region for NiFeP and M-Ni 2 P/Fe 2 P samples.
18 Figure S14. XPS spectra of Ni and Fe 2p region for NiFeP-O-2 and M-Ni 2 P/Fe 2 P-O-2 samples (at j of 40 ma/cm 2 for 2 h). Notes: In Figure S12, we observed that Ni element of NiFe(OH) x underwent a positive shift compared with M-Ni(OH) x /Fe(OH) x, while the Fe element of NiFe(OH) x displayed a negative shift compared with M-Ni(OH) x /Fe(OH) x. In Figure S 13 and 14, XPS spectra for NiFeP, M-Ni 2 P/Fe 2 P, NiFeP-O and M-Ni 2 P/Fe 2 P-O indicated the same tendency for Ni and Fe elements. In recent reports, 1, 2 researchers have proved that the incorporated Fe would synergistically improve the Ni valance because of the strong electronic interaction in the NiFe based catalysts. In our work, the Ni and Fe elements were homogeneously dispersed in the whole for the sample of NiFeP, its precursor and its post-oer samples on the surface, while Ni and Fe elements only interacted on the interfaces for M-Ni 2 P/Fe 2 P, its precursor and its post-oer samples. Based on these results, we would like to think the surface oxidized layers might be trace amount (Fe)Ni doped (Ni)FeOOH, not homogeneously dispersed NiFe based (oxy)hydroxides.
19 Figure S15. The survey XPS spectra of M-Ni 2 P/Fe 2 P before and after OER test for 70 h, illustrating that the content of P element became lower after stability test.
20 Figure S16. XPS spectra of P 2p region for M-Ni 2 P/Fe 2 P sample after different time of stability test (at j of 40 ma/cm 2 for 0 h, 2 h, 70 h and 100 h). Notes: Recently, researchers have systematically studied the influence of P leaching phenomenon of phosphide OER precatalysts. 3, 4 Lee, J. Y. et al. have proved that surface phosphates would be oxidized during the OER and the surface formed oxyhydroxides are real active materials. Excellent and systematic work by Alshareef, H. N. et al. has clearly demonstrated that the surface phosphates would be oxidized at a high j of 30 ma/cm 2 for a longer stability test. We also collected the M-Ni 2 P/Fe 2 P-O samples after different time of stability test (0 h, 2 h, 70 h and 100 h, named as M-Ni 2 P/Fe 2 P-O-0, M-Ni 2 P/Fe 2 P-O-2, M-Ni 2 P/Fe 2 P-O-70 and M-Ni 2 P/Fe 2 P-O-100) and conducted the XPS analysis. In Figure S16, we observed the P leaching phenomenon and negligible phosphide signals on the surface. However, P signals could still be detected as PO 3-4 species after 100 hours stability test. We also found that the OER activity slightly degraded for long time stability test, which might result from the reduction of PO 3-4 species.
21 Figure S17. LSV curves of hydroxides, annealed oxides and phosphides catalysts. The polarization curves were obtained with a backward scan rate of 1 mv/s, which were not ir-corrected.
22 Figure S18. EIS spectra of M-Ni(OH) x /Fe(OH) x, S-Ni 2 P/Fe 2 P-O, and M-Ni 2 P/Fe 2 P-O catalysts, respectively.
23 Figure S19. CVs at different scan rates in a potential window where no Faradaic processes occur (1.15 to 1.25 V vs. RHE) for (a) M-Ni 2 P/Fe 2 P-O, (b) S-Ni 2 P/Fe 2 P-O and (c) Ni 2 P-O, respectively, with the scan rates from 10 to 60 mv/s.
24 Figure S20. Enlarged chronopotentiometric curves in the narrow potential region obtained with the M-Ni 2 P/Fe 2 P-O catalyst with constant current density of 40 ma/cm 2 for about 120 h.
25 Figure S21. Multi-current process of M-Ni 2 P/Fe 2 P-O catalyst in 1 M KOH. The catalyst was stabilized and then started at the current density of 40 ma/cm 2 and ended at 240 ma/cm 2, with 40 ma/cm 2 increment every 500 seconds.
26 Table S1. Comparison of OER performances for Ni 2 P/Fe 2 P-O catalysts and recently reported active catalysts in 1 M KOH solutions. Catalysts η 10 (mv) Tafel slope (mv/dec) Substrates References M-Ni 2 P/Fe 2 P-O a Ni foam this work S-Ni 2 P/Fe 2 P-O a Ni foam this work G-FeCoW a 191 / gold coated Ni foam Science 352, (2016) NiFe LDH b Ni foam Nature Commun. 6, 6616 (2015) CoSn(OH) / GCE Energy Environ. Sci. 9, (2016) b Na 0.08 Ni 0.9 Fe 0.1 O GCE Energy Environ. Sci. 10, (2017) NiCeO x -Au b 271 / GCE Nature Energy 1, (2016) NiTi-MMO b GCE J. Am. Chem. Soc (2016) NiCo-UMOFNs b 189 / Cu foam Nature Energy 1, (2016) b Ni 3 S / Ni foam J. Am. Chem. Soc (2015) Co-S b carbon paper/carbon tubes ACS Nano 10, (2016) b Ni x Fe 1-x Se Ni foam Nature Commun. 7, 12324, (2016) (Ni, Co) 0.85 Se b carbon fabric collector Adv. Mater. 28, (2016) CoN b Ni foam Angew. Chem., Int. Ed. 55, (2016) Co 4 N b GCE Angew. Chem., Int. Ed. 54, (2016) Ni 3 N-COF b GCE Adv. Energy Mater. 6, (2016) Ni 3 FeN b Ni foam Adv. Energy Mater. 10, (2016) Ni 2 P GCE Energy Environ. Sci. 8, (2015) CoNi-P b Ni foam Energy Environ. Sci. 10, 893 (2017) b MnCoPO x GCE Angew. Chem., Int. Ed. 56, (2017) Notes: a the potential was not ir-corrected; b the potential was ir-corrected; η 10 means the overpotential needed to drive the current density of 10 ma/cm 2 ; GCE was abbreviation for glassy carbon electrode.
27 References (1) Zhu, K.; Wu, T.; Zhu, Y.; Li, X.; Li, M.; Lu, R.; Wang, J.; Zhu, X.; Yang, W. Layered Fe-Substituted LiNiO 2 Electrocatalysts for High-Efficiency Oxygen Evolution Reaction. ACS Energy Lett. 2017, 2, (2) Li, Y. B.; Zhao, C. Iron-Doped Nickel Phosphate as Synergistic Electrocatalyst for Water Oxidation. Chem. Mater. 2016, 28, (3) Zhan, Y.; Lu, M.; Yang, S.; Liu, Z.; Lee, J. Y. The Origin of Catalytic Activity of Nickel Phosphate for Oxygen Evolution in Alkaline Solution and its Further Enhancement by Iron Substitution. ChemElectroChem 2016, 3, (4) Liang, H.; Gandi, A. N.; Xia, C.; Hedhili, M. N.; Anjum, D. H.; Schwingenschlögl, U.; Alshareef, H. N. Amorphous NiFe-OH/NiFeP Electrocatalyst Fabricated at Low Temperature for Water Oxidation Applications. ACS Energy Lett. 2017, 2,
Supporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Experimental section Synthesis of Ni-Co Prussian
More informationSupporting Information. High Wettable and Metallic NiFe-Phosphate/Phosphide Catalyst Synthesized by
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information High Wettable and Metallic NiFe-Phosphate/Phosphide
More informationSupplementary Information for
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2017 Supplementary Information for Cu Nanowires Shelled with NiFe Layered Double
More informationAchieving Stable and Efficient Water Oxidation by Incorporating NiFe. Layered Double Hydroxide Nanoparticles into Aligned Carbon.
Electronic Supplementary Material (ESI) for Nanoscale Horizons. This journal is The Royal Society of Chemistry 2015 Achieving Stable and Efficient Water Oxidation by Incorporating NiFe Layered Double Hydroxide
More informationSupporting Information
Supporting Information NiFe-Layered Double Hydroxide Nanosheet Arrays Supported on Carbon Cloth for Highly Sensitive Detection of Nitrite Yue Ma,, Yongchuang Wang,, Donghua Xie,, Yue Gu,, Haimin Zhang,
More informationN-doped Carbon-Coated Cobalt Nanorod Arrays Supported on a Titanium. Mesh as Highly Active Electrocatalysts for Hydrogen Evolution Reaction
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information N-doped Carbon-Coated Cobalt Nanorod
More informationSupporting Information. Electropolymerization of aniline on nickel-based electrocatalysts substantially
Supporting Information Electropolymerization of aniline on nickel-based electrocatalysts substantially enhances their performance for hydrogen evolution Fuzhan Song, Wei Li, Guanqun Han, and Yujie Sun*
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information MoS 2 nanosheet/mo 2 C-embedded N-doped
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Magnesium-Regulated Oxygen Vacancies
More informationElectronic Supporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supporting Information Synthesis of Amorphous Boride Nanosheets
More informationCarbon Quantum Dots/NiFe Layered Double Hydroxide. Composite as High Efficient Electrocatalyst for Water
Supplementary Information Carbon Quantum Dots/NiFe Layered Double Hydroxide Composite as High Efficient Electrocatalyst for Water Oxidation Di Tang, Juan Liu, Xuanyu Wu, Ruihua Liu, Xiao Han, Yuzhi Han,
More informationA Robust and Highly Active Copper-Based Electrocatalyst. for Hydrogen Production at Low Overpotential in Neutral
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting information A Robust and Highly Active Copper-Based Electrocatalyst for Hydrogen Production
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Phosphorus-Doped CoS 2 Nanosheet Arrays as
More informationSupporting Information. Phenolic/resin assisted MOFs derived hierarchical Co/N-doping carbon
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Material (ESI) for Journal of Materials Chemistry
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Nickel Cobalt Phosphides Quasi-Hollow Nanocubes as an Efficient
More informationSupporting Information for. Highly active catalyst derived from a 3D foam of Fe(PO 3 ) 2 /Ni 2 P for extremely efficient water oxidation
Supporting Information for Highly active catalyst derived from a 3D foam of Fe(PO 3 ) 2 /Ni 2 P for extremely efficient water oxidation Haiqing Zhou a,1, Fang Yu a,1, Jingying Sun a, Ran He a, Shuo Chen
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Fig. S1 XRD patterns of a-nifeo x
More informationA General Approach to Ultrathin NiM (M = Fe, Co, Mn) Hydroxide Nanosheets as High-Performance Low-Cost. Electrocatalysts for Overall Water Splitting
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting information for A General Approach to Ultrathin NiM (M = Fe,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information One-step synthesis of cobalt-doped MoS 2 nanosheets as bifunctional
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Experimental section Materials: Ti mesh (TM) was provided
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Synthesis of 1T-MoSe 2 ultrathin
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Experimental Section Materials: Ti
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information One-Dimensional MoO2-Co2Mo3O8@C Nanorods: A Novel and High
More informationHydrogen Evolution Electrocatalysts in Basic Solutions
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting Information for Interlaced NiS 2 -MoS 2 Nanoflake-Nanowires
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Pt-like catalytic behavior of MoNi
More informationNickel Sulfides Freestanding Holey Films as Air-Breathing Electrodes for. Flexible Zn-Air Batteries
Nickel Sulfides Freestanding Holey Films as Air-Breathing Electrodes for Flexible Zn-Air Batteries Kyle Marcus, 1,# Kun Liang, 1,# Wenhan Niu, 1,# Yang Yang 1,* 1 NanoScience Technology Center, Department
More informationSupporting information:
Supporting information: The Role of Anisotropic Structure and Its Aspect Ratio: High-Loading Carbon Nanospheres Supported Pt Nanowires and Their High Performance Toward Methanol Electrooxidation Feng-Zhan
More informationSupporting Information
Supporting Information Hierarchical FeNiP @ Ultrathin Carbon Nanoflakes as Alkaline Oxygen Evolution and Acidic Hydrogen Evolution Catalyst for Efficient Water Electrolysis and Organic Decomposition Bowei
More informationDivision of Physics and Semiconductor Science, Dongguk University, Seoul 04620, South Korea
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supplementary information for Self-assembled Two-dimensional Copper Oxide
More informationCarbon-encapsulated heazlewoodite nanoparticles as highly efficient and durable electrocatalysts for oxygen evolution reactions
Electronic Supplementary Material Carbon-encapsulated heazlewoodite nanoparticles as highly efficient and durable electrocatalysts for oxygen evolution reactions Mohammad Al-Mamun 1, Huajie Yin 1, Porun
More informationSupporting Information
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2016 Supporting Information Single-crystalline Pd square nanoplates enclosed by {100}
More informationHydrogenated CoO x Ni(OH) 2 nanosheet core shell nanostructures for high-performance asymmetric supercapacitors
. Electronic Supplementary Material (ESI) for Nanoscale Electronic Supplementary Information (ESI) Hydrogenated CoO x nanowire @ Ni(OH) 2 nanosheet core shell nanostructures for high-performance asymmetric
More informationof (002) plane on the surfaces of porous N-doped carbon nanotubes for
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Growth of MoSe 2 nanosheet arrays with small size and expanded
More informationη (mv) J (ma cm -2 ) ma cm
J (ma cm -2 ) 250 200 150 100 50 0 253 mv@10 ma cm -2-50 0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 η (mv) Supplementary Figure 1 Polarization curve of NiSe. S1 FeO x Fe-Se Intensity (a. u.) 720 717 714 711
More informationNitrogen and sulfur co-doped porous carbon derived from human hair as. highly efficient metal-free electrocatalyst for hydrogen evolution reaction
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Nitrogen and sulfur co-doped porous
More informationSupporting Information
Supporting Information Defect-Rich 2D Material Networks for Advanced Oxygen Evolution Catalysts Bowei Zhang, Zhiyuan Qi, # Zishan Wu, Yu Hui Lui, Tae-Hoon Kim, # Xiaohui Tang, Lin Zhou, # Wenyu Huang,
More informationSupplementary Information:
Supplementary Information: One-Step and Rapid Synthesis of Clean and Monodisperse Dendritic Pt Nanoparticles and Their High Performance Toward Methanol Oxidation and p-nitrophenol Reduction Jun Wang, Xin-Bo
More informationElectronic Supplementary Information. A Flexible Alkaline Rechargeable Ni/Fe Battery Based on Graphene Foam/Carbon Nanotubes Hybrid Film
Electronic Supplementary Information A Flexible Alkaline Rechargeable Ni/Fe Battery Based on Graphene Foam/Carbon Nanotubes Hybrid Film Jilei Liu,, Minghua Chen, Lili Zhang, Jian Jiang, Jiaxu Yan, Yizhong
More informationElectronic Supplementary Information (ESI )
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI ) Hollow nitrogen-doped carbon spheres as an efficient
More informationSupporting Information
Supporting Information High Performance Electrocatalyst: Pt-Cu Hollow Nanocrystals Xiaofei Yu, a Dingsheng, a Qing Peng a and Yadong Li* a a Department of Chemistry, Tsinghua University, Beijing, 100084
More informationSupplementary Information for. High-performance bifunctional porous non-noble metal phosphide catalyst for overall
Supplementary Information for High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting Yu et al. Supplementary Figure 1. A typical TEM image of as-prepared FeP/Ni
More informationMultiply twinned Pt Pd nanoicosahedrons as highly active electrocatalyst for methanol oxidation
Supporting Information for Multiply twinned Pt Pd nanoicosahedrons as highly active electrocatalyst for methanol oxidation An-Xiang Yin, Xiao-Quan Min, Wei Zhu, Hao-Shuai Wu, Ya-Wen Zhang* and Chun-Hua
More informationFlexible Waterproof Rechargeable Hybrid Zinc Batteries Initiated. by Multifunctional Oxygen Vacancies-Rich Cobalt Oxide
Flexible Waterproof Rechargeable Hybrid Zinc Batteries Initiated by Multifunctional Oxygen Vacancies-Rich Cobalt Oxide Longtao Ma 1, Shengmei Chen 1, Zengxia Pei 1, Hongfei Li 1, Zifeng Wang 1, Zhuoxin
More informationSupporting Information
Supporting Information Bamboo-Like Carbon Nanotube/Fe 3 C Nanoparticle Hybrids and Their Highly Efficient Catalysis for Oxygen Reduction Wenxiu Yang a,b, Xiangjian Liu a,b, Xiaoyu Yue a,b, Jianbo Jia,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Self-supported formation of hierarchical
More informationShape-selective Synthesis and Facet-dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt-Pd Tetrahedrons and Cubes
Supporting Information Shape-selective Synthesis and Facet-dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt-Pd Tetrahedrons and Cubes An-Xiang Yin, Xiao-Quan Min,
More informationSupplemental Information. In Situ Electrochemical Production. of Ultrathin Nickel Nanosheets. for Hydrogen Evolution Electrocatalysis
Chem, Volume 3 Supplemental Information In Situ Electrochemical Production of Ultrathin Nickel Nanosheets for Hydrogen Evolution Electrocatalysis Chengyi Hu, Qiuyu Ma, Sung-Fu Hung, Zhe-Ning Chen, Daohui
More informationSupporting information for
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2018 Supporting information for N-doped Carbon Shelled Bimetallic Phosphates for Efficient Electrochemical
More informationSupporting Information for
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2014 Supporting Information for Metal Nanoparticles Directed NiCo 2 O 4 Nanostructure
More informationSupporting Information. Mixed-Node Metal-Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction
Supporting Information Mixed-Node Metal-Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction Xiaohua Zhao, a Brian Pattengale, b Donghua Fan, c Zehua Zou, a Yongqing Zhao, a Jing
More informationSupporting Information for
Supporting Information for Electronic and Morphological Dual Modulation of Cobalt Carbonate Hydroxides by Mn Doping towards Highly Efficient and Stable Bifunctional Electrocatalysts for Overall Water Splitting
More informationNanomaterials and Chemistry Key Laboratory, Wenzhou University, Wenzhou, (P. R. China).
Electronic Supplementary Material (ESI) for Nanoscale Synergistically enhanced activity of graphene quantum dot/multi-walled carbon nanotube composites as metal-free catalysts for oxygen reduction reaction
More informationMolybdenum compound MoP as an efficient. electrocatalyst for hydrogen evolution reaction
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Molybdenum compound MoP as an efficient electrocatalyst for hydrogen evolution
More informationPt-Ni alloyed nanocrystals with controlled archtectures for enhanced. methanol oxidation
Supplementary Information Pt-Ni alloyed nanocrystals with controlled archtectures for enhanced methanol oxidation Xiao-Jing Liu, Chun-Hua Cui, Ming Gong, Hui-Hui Li, Yun Xue, Feng-Jia Fan and Shu-Hong
More informationElectronic Supplementary Material (ESI) for Chemical Communications This journal is The Royal Society of Chemistry 2011
Supplementary Information for Selective adsorption toward toxic metal ions results in selective response: electrochemical studies on polypyrrole/reduced graphene oxide nanocomposite Experimental Section
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting Information Carbon-Coated Hollow Mesoporous FeP Microcubes:
More informationThe design and construction of 3D rose petal-shape MoS 2. hierarchical nanostructures with structure-sensitive. properties
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 The design and construction of 3D rose petal-shape MoS 2 hierarchical nanostructures
More informationnanowires self-supported on copper foam as a highly efficient 3D
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2016 Rapid synthesis of ultralong Fe(OH) 3 :Cu(OH) 2 core-shell nanowires self-supported
More informationElectronic Supplementary Information. Microwave-assisted, environmentally friendly, one-pot preparation. in electrocatalytic oxidation of methanol
Electronic Supplementary Information Microwave-assisted, environmentally friendly, one-pot preparation of Pd nanoparticles/graphene nanocomposites and their application in electrocatalytic oxidation of
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2019 Electronic Supplementary Information Graphene oxide supported cobalt phosphide nanorods designed
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information NiSe 2 Pyramids Deposited on N-doped Graphene Encapsulated
More informationCo-vacancy-rich Co 1 x S nanosheets anchored on rgo for high-efficiency oxygen evolution
Electronic Supplementary Material Co-vacancy-rich Co 1 x S nanosheets anchored on rgo for high-efficiency oxygen evolution Jiaqing Zhu 1, Zhiyu Ren 1 ( ), Shichao Du 1, Ying Xie 1, Jun Wu 1,2, Huiyuan
More informationShaped Ir-Ni bimetallic nanoparticles for minimizing Ir utilization in oxygen evolution reaction
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2016 Supporting Information Shaped Ir-Ni bimetallic nanoparticles for minimizing Ir utilization
More informationFabrication of Metallic Nickel-Cobalt Phosphide Hollow Microspheres for. High-Rate Supercapacitors
Supporting Information Fabrication of Metallic Nickel-Cobalt Phosphide Hollow Microspheres for High-Rate Supercapacitors Miao Gao, Wei-Kang Wang, Xing Zhang, Jun Jiang, Han-Qing Yu CAS Key Laboratory of
More informationRole of iron in preparation and oxygen reduction reaction activity of nitrogen-doped carbon
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Role of iron in preparation and oxygen reduction reaction
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Hierarchical MoS 2 microboxes constructed
More informationElectronic supplementary information. Amorphous carbon supported MoS 2 nanosheets as effective catalyst for electrocatalytic hydrogen evolution
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Electronic supplementary information Amorphous carbon supported MoS 2 nanosheets as effective
More informationAn extraordinarily stable catalyst: Pt NPs supported on two-dimensional Ti 3 C 2 X 2 (X=OH, F) nanosheets for Oxygen Reduction Reaction
An extraordinarily stable catalyst: Pt NPs supported on two-dimensional Ti 3 X 2 (X=OH, F) nanosheets for Oxygen Reduction Reaction Xiaohong Xie, Siguo Chen*, Wei Ding, Yao Nie, and Zidong Wei* Experimental
More informationDetermination of Electron Transfer Number for Oxygen Reduction Reaction: from Theory to Experiment
Supporting Information Determination of Electron Transfer Number for Oxygen Reduction Reaction: from Theory to Experiment Ruifeng Zhou 1, 2, Yao Zheng 1, Mietek Jaroniec 3 and Shi-Zhang Qiao 1, * 1 School
More informationPt-Cu Hierarchical Quasi Great Dodecahedrons with Abundant
Electronic Supplementary Material Material (ESI) for (ESI) Chemical for ChemComm. Science. This journal is is The The Royal Royal Society Society of Chemistry of Chemistry 2017 2017 Supporting Information
More informationSynthesis of Oxidized Graphene Anchored Porous. Manganese Sulfide Nanocrystal via the Nanoscale Kirkendall Effect. for supercapacitor
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Synthesis of Oxidized Graphene Anchored Porous Manganese Sulfide Nanocrystal
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Two-dimensional CoNi nanoparticles@s,n-doped
More informationElectrodeposited nickel hydroxide on nickel foam with ultrahigh. capacitance
Electrodeposited nickel hydroxide on nickel foam with ultrahigh capacitance Guang-Wu Yang, Cai-Ling Xu* and Hu-Lin Li* College of Chemistry and Chemical Engineering, Lanzhou University, 73 (PR China) 1.
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Supplementary Information Highly efficient and recyclable triple-shelled Ag@Fe 3 O 4 @SiO 2 @TiO
More informationSupporting Information
Supporting Information A General Strategy for the Synthesis of Transition-Metal Phosphide/N-doped Carbon Frameworks for Hydrogen and Oxygen Evolution Zonghua Pu, Chengtian Zhang, Ibrahim Saana Amiinu,
More informationPrecious Metal-free Electrode Catalyst for Methanol Oxidations
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 Supporting information SnO 2 Nanocrystals Decorated-Mesoporous ZSM-5 Spheroidicity
More informationSupporting Information
Supporting Information Mo- and Fe-modified Ni(OH) 2 /NiOOH nanosheets as highly active and stable electrocatalysts for oxygen evolution reaction Yanshuo Jin a, Shangli Huang b, Xin Yue a, Hongyu Du c,
More informationSupporting Information
Supporting Information Universal, In-Situ Transformation of Bulky Compounds into Nanoscale Catalysts by High Temperature Pulse Shaomao Xu 1, (a), Yanan Chen 1, (a), Yiju Li 1, (a), Aijiang Lu 1, Yonggang
More informationElectronic Supplementary Material. Methods. Synthesis of reference samples in Figure 1(b) Nano Res.
Electronic Supplementary Material Shaped Pt Ni nanocrystals with an ultrathin Pt-enriched shell derived from one-pot hydrothermal synthesis as active electrocatalysts for oxygen reduction Jun Gu 1,, Guangxu
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Carbon coated nickel phosphides porous
More informationSupplementary Information. Unusual High Oxygen Reduction Performance in All-Carbon Electrocatalysts
Supplementary Information Unusual High Oxygen Reduction Performance in All-Carbon Electrocatalysts Wei Wei 1, 4,, Ying Tao 1, 4,, Wei Lv 2,, Fang-Yuan Su 2, Lei Ke 2, Jia Li 2, Da-Wei Wang 3, *, Baohua
More informationThree Dimensional Nano-assemblies of Noble Metal. Nanoparticles-Infinite Coordination Polymers as a Specific
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Three Dimensional Nano-assemblies of Noble Metal Nanoparticles-Infinite
More informationSupporting Information
Supporting Information Pt Nanoparticles Anchored Molecular Self-Assemblies of DNA: An Extremely Stable and Efficient HER Electrocatalyst with Ultra-Low Pt Content Sengeni Anantharaj, $ Pitchiah E. Karthik,
More informationJaemin Kim, Xi Yin, Kai-Chieh Tsao, Shaohua Fang and Hong Yang *
Jaemin Kim, Xi Yin, Kai-Chieh Tsao, Shaohua Fang and Hong Yang * Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, 114 Roger Adams Laboratory, MC-712, 600
More informationSchool of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, , Singapore. b
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Dopamine-Mo VI complexation-assisted large-scale aqueous synthesis of single-layer MoS 2 /carbon
More informationElectronic Supplementary Information. Three-Dimensional Carbon Foam/N-doped 2. Hybrid Nanostructures as Effective Electrocatalysts for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Three-Dimensional Carbon Foam/N-doped
More informationSupporting Information
Supporting Information Nest-like NiCoP for Highly Efficient Overall Water Splitting Cheng Du, a Lan Yang, a Fulin Yang, a Gongzhen Cheng a and Wei Luo a,b* a College of Chemistry and Molecular Sciences,
More informationIn-situ Growth of well-ordered NiFe-MOF-74 on Ni foam by Fe 2+ Induction as an Efficient and Stable Electrocatalyst for Water.
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 In-situ Growth of well-ordered NiFe-MOF-74 on Ni foam by Fe 2+ Induction as an Efficient and Stable
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supporting Information Synthesis and Application of Hexagonal Perovskite BaNiO 3 with Quadrivalent
More informationFuel Cell System and Engineering Laboratory, Dalian Institute of Chemical Physics,
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Construction of orderly hierarchical FeOOH/NiFe
More informationP Dopants Triggered New Basal Plane Active Sites. and Enlarged Interlayer Spacing in MoS 2. Evolution
Supporting Information P Dopants Triggered New Basal Plane Active Sites and Enlarged Interlayer Spacing in MoS 2 Nanosheets towards Electrocatalytic Hydrogen Evolution Peitao Liu a, Jingyi Zhu b, Jingyan
More informationSupporting Information
Supporting Information The Design of Hierarchical Ternary Hybrid for Fiber-Shaped Asymmetric Supercapacitor with High Volumetric Energy Density Xunliang Cheng, Jing Zhang, Jing Ren, Ning Liu, Peining Chen,
More informationSupporting Information
Supporting Information Facet-Selective Deposition of FeO x on α-moo 3 Nanobelts for Lithium Storage Yao Yao, 1 Nuo Xu, 2 Doudou Guan, 1 Jiantao Li, 1 Zechao Zhuang, 1 Liang Zhou,*,1 Changwei Shi 1, Xue
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 214 Electronic Supplementary Information Ultrathin and High-Ordered CoO Nanosheet
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Experimental section Materials Sodium
More informationNickel Phosphide-embedded Graphene as Counter Electrode for. Dye-sensitized Solar Cells **
Nickel Phosphide-embedded Graphene as Counter Electrode for Dye-sensitized Solar Cells ** Y. Y. Dou, G. R. Li, J. Song, and X. P. Gao =.78 D 1359 G 163 a =.87 D 138 G 159 b =1.3 D 1351 G 1597 c 1 15 1
More informationHighly Open Rhombic Dodecahedral PtCu Nanoframes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting information for Highly Open Rhombic Dodecahedral PtCu Nanoframes Jiabao Ding, a Xing
More informationSupporting Informantion
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2018 Supporting Informantion Hierarchical Whisker-on-sheet NiCoP with Adjustable Surface structure
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Supporting Information A Cu 2 Se-Cu 2 O Film Electrodeposited on Titanium Foil as a Highly Active
More informationSupporting Information An Interlaced Silver Vanadium Oxide-Graphene Hybrid with High Structural Stability for Use in Lithium Ion Batteries
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information An Interlaced Silver Vanadium Oxide-Graphene Hybrid with High Structural
More information