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1 Proforma for information to be provided by the Teaching/ Academic/ Research Staff 1. Name: Roop Shikha Singh 2. Designation: Assistant Professor 3. Academic Qualifications: Sr. Degree Institution Year 1. Ph.D Banaras Hindu University M.Sc. Banaras Hindu University B.Sc. Banaras Hindu University Area of Specialization: I have research interests in two main areas that I specialize in: the one involving design, synthesis and characterization of luminophores based on borondipyrromethenes (BODIPYs), its metal (Ru, Rh and Ir) analogues and donor-acceptor molecules. The other one contemplates the investigation of morphologically controlled self assembly/nano-aggregation and photochemistry of these systems in solution and solid state. Theme of the work lies on the interface of organic/inorganic and organometallic chemistry and relays the significance of structure-property relationship in achieving functional inorganic materials. The broad area of my research work requires extensive experience in organic/organometallic synthesis and characterization. Synthetic versatility, steric hindrance, aromaticity, and asymmetry can be used as effective tools to alter the structural and photophysical properties of such luminophores. In addition, I have also worked on the exploration of coordination driven self assembly and solid sate emission in zinc and cyclometalated iridium complexes for applications in optoelectronics. Currently I am interested in developing multifunctional nanoarchitectures to attain high FRET efficiency and their possible application in artificial light harvesting systems. 5. Contact Information: Mobile No roopshikha22singh@gmail.com, roopshikha.singh1@bhu.ac.in 6. Projects Undertaken as PI/ Co PI: NA 7. Awards/ Recognitions if any:
2 SERB INDO-US Postdoctoral Fellowship-2017 (Host: Prof. J. S. Lindsey, North Carolina State University, USA). National Postdoctoral Fellowship CSIR-UGC NET; qualified Junior Research Fellowship from CSIR, New Delhi, India, (December 2010). Late Sumant Singh Memorial Gold Medal for securing highest marks in B.Sc. (Hons.) Chemistry Exam, (Banaras Hindu University) Late Prof. Sanat Kumar Basu Cash Prize for securing highest percentage of marks in aggregate at the B. Sc. (Hons.) Chemistry Examination, (Banaras Hindu University) BHU Prize for standing First in B.Sc. (Hons.) Part III Chemistry Examination, (Banaras Hindu University) Best Student Award of year (Banaras Hindu University) Certificate of Merit for standing Fourth at the B. Sc. (Hons.) II Examination of (Banaras Hindu University) Certificate of Merit for standing First in Chemistry at the B.Sc. (Hons.) II Examination of (Banaras Hindu University) Certificate of Merit for standing First in Zoology at the B.Sc. (Hons.) I Examination of (Banaras Hindu University) Poster Presentation prize on First Institute Day Celebration (2016), Institute of Science, Banaras Hindu University, Varanasi. 8. List of 10 major Publications: (in order of importance) 1. *An Unconventional Mechanistic Insight on Aggregation Induced Emission in Novel Boron Dipyrromethenes and Their Rational Biological Realizations. Roop Shikha Singh, Ashish Kumar, Sujay Mukhopadhyay, Gunjan Sharma, Biplob Koch and J. Phys. Chem. C., 120, , *Exquisite 1-D assemblies arising from rationally designed asymmetric D A architectures exhibiting aggregation induced emission as a function of auxiliary acceptor strength. Roop shikha Singh, Sujay Mukhopadhyay, Arnab Biswas and Chem. Eur. J., 22, , *Morphological tuning via structural modulations in AIE luminogens with the minimum number of possible variables and their use in live cell imaging. Roop Shikha Singh, Rakesh Kumar Gupta, Rajendra Prasad Paitandi, Mrigendra Dubey, Gunjan Sharma, Biplob Koch, and Chem. Comm., 51, , *Triazole-appended BODIPY piperazine conjugates and their efficacy toward mercury sensing. Roop Shikha Singh, Rakesh Kumar Gupta, Rajendra Prasad Paitandi, Arvind Misra, and New J. Chem., 39, , *Luminescent N,O-chelated chroman-bf2 complexes: structural variants of BODIPY. Roop Shikha Singh, Mahendra Yadav, Rakesh Kumar Gupta, Rampal Pandey, and Dalton Trans., 42, , 2012.
3 6. Solvent-Dependent Self-Assembly and Aggregation-Induced Emission in Zn(II) Complexes Containing Phenothiazine-Based Terpyridine Ligand and Its Efficacy in Pyrophosphate Sensing. Vishwa Deepak Singh, Roop Shikha Singh, Rajendra Prasad Paitandi, Bhupendra Kumar Dwivedi, Biswajit Maiti, and J. Phys. Chem. C, 122, , Fine-Tuning of Saponification Triggered Gelation by Strategic Modification of Peripheral Substituents: Gelation Regulators. Ashish Kumar, Roop Shikha Singh, Amit Kumar, Afsar Ali, Arnab Biswas, and Chem. Eur. J., 22, , Photochemical water oxidation by cyclometalated iridium(iii) complexes: A mechanistic insight. Sujay Mukhopadhyay, Roop Shikha Singh, Arnab Biswas, Chem. Comm., 52, , Time dependent aggregation induced emission enhancement and the study of molecular packing in closely related azo-phenol BODIPY species. Rajendra Prasad Paitandi, Roop Shikha Singh, Bhupendra Kumar Dwivedi, Vishwa Deepak Singh and Dalton Trans., 47, , Spacer length dependent architectural diversity in bis-dipyrrin copper(ii) complexes. Rajendra Prasad Paitandi, Roop Shikha Singh, Sujay Mukhopadhyay, Ashish Kumar, and Dalton Trans, 46, , Additional Information/ Achievements: Postdoctoral Research Experience: 1. SERB INDO-US Postdoctoral Fellow, North Carolina State University, USA (Prof. J.S. Lindsey). 2. Research Associate in SERB sponsored project entitled Designing and synthesis of metal based aggregation induced emission (AIE) luminogens and their properties (Department of Chemistry, Institute of Science, Banaras Hindu University). 10. Full List of Publications: 1. *An Unconventional Mechanistic Insight on Aggregation Induced Emission in Novel Boron Dipyrromethenes and Their Rational Biological Realizations. Roop Shikha Singh, Ashish Kumar, Sujay Mukhopadhyay, Gunjan Sharma, Biplob Koch and J. Phys. Chem. C., 120, , *Exquisite 1-D assemblies arising from rationally designed asymmetric D A architectures exhibiting aggregation induced emission as a function of auxiliary acceptor strength. Roop shikha Singh, Sujay Mukhopadhyay, Arnab Biswas and Chem. Eur. J., 22, , 2016.
4 3. *Morphological tuning via structural modulations in AIE luminogens with the minimum number of possible variables and their use in live cell imaging. Roop Shikha Singh, Rakesh Kumar Gupta, Rajendra Prasad Paitandi, Mrigendra Dubey, Gunjan Sharma, Biplob Koch, and Chem. Comm., 51, , *Triazole-appended BODIPY piperazine conjugates and their efficacy toward mercury sensing. Roop Shikha Singh, Rakesh Kumar Gupta, Rajendra Prasad Paitandi, Arvind Misra, and New J. Chem., 39, , *Luminescent N,O-chelated chroman-bf 2 complexes: structural variants of BODIPY. Roop Shikha Singh, Mahendra Yadav, Rakesh Kumar Gupta, Rampal Pandey, and Daya Shankar Pandey Dalton Trans., 42, , Manipulating metallogel properties by luminogens and their applications in cell imaging. Arnab Biswas, Sujay Mukhopadhyay, Roop Shikha Singh, Ashish Kumar, Nishant Kumar Rana, Biplob Koch, and ACS Omega, 3, , Time dependent aggregation induced emission enhancement and the study of molecular packing in closely related azo-phenol BODIPY species. Rajendra Prasad Paitandi, Roop Shikha Singh, Bhupendra Kumar Dwivedi, Vishwa Deepak Singh and Dalton Trans., 47, , Solvent-Dependent Self-Assembly and Aggregation-Induced Emission in Zn(II) Complexes Containing Phenothiazine-Based Terpyridine Ligand and Its Efficacy in Pyrophosphate Sensing. Vishwa Deepak Singh, Roop Shikha Singh, Rajendra Prasad Paitandi, Bhupendra Kumar Dwivedi, Biswajit Maiti, and J. Phys. Chem. C, 122, , Anticancer Activity of Iridium(III) Complexes Based on a Pyrazole Appended Quinoline- BODIPY Rajendra Prasad Paitandi, Sujay Mukhopadhyay, Roop Shikha Singh, Vinay Sharma, Shaikh M Mobin, and Inorg. Chem., 56, , 2017, 10. Polymerization of 1-(2-Propynyl)-3-methylimidazolium Bromide using Cyclometalated Pd(II) Catalysts and Study of the Interaction of Ensuing Oligomer with BSA. Sujay Mukhopadhyay, Kheyanath Mitra, Rajendra Prasad Paitandi, Roop Shikha Singh, Shikha Singh, Biswajit Ray and ChemistrySelect, 2, , Influence of substituents on DNA and protein binding of cyclometalated Ir(III) complexes and anticancer activity Sujay Mukhopadhyay, Roop Shikha Singh, Rajendra Prasad Paitandi, Gunjan Sharma, Biplob Koch, and Dalton Trans, 46, , Spacer length dependent architectural diversity in bis-dipyrrin copper(ii) complexes.
5 Rajendra Prasad Paitandi, Roop Shikha Singh, Sujay Mukhopadhyay, Ashish Kumar, and Dalton Trans, 46, , Fine-Tuning of Saponification Triggered Gelation by Strategic Modification of Peripheral Substituents: Gelation Regulators. Ashish Kumar, Roop Shikha Singh, Amit Kumar, Afsar Ali, Arnab Biswas, and Daya Shankar Pandey Chem. Eur. J., 22, , Strong luminescence behavior of mono- and dimeric imidazoquinazolines: Swift OLED degradation under electrical current Rampal Pandey, Gábor Méhes, Ashish Kumar, Roop Shikha Singh, Amit Kumar, Chihaya Adachi, J. Lumin., 181, , Achieving Molecular-/Nano-aggregation in Cyclometalated Iridium(III) Complexes via Structural Modification Sujay Mukhopadhyay, Roop Shikha Singh, Arnab Biswas, Biswajit Maiti and Daya Shankar Pandey Eur. J. Inorg. Chem., , Heteroleptic arene Ru(II) dipyrrinato complexes: DNA, protein binding and anti-cancer activity against the ACHN cancer cell line. Rakesh Kumar Gupta, Amit Kumar, Rajendra Prasad Paitandi, Roop Shikha Singh, Sujay Mukhopadhyay, Shiv Prakash Verma, Parimal Das and Dalton Trans., 45, , Photochemical water oxidation by cyclometalated iridium(iii) complexes: A mechanistic insight. Sujay Mukhopadhyay, Roop Shikha Singh, Arnab Biswas, Chem. Comm., 52, , Small Organic Non gelators Evincing Radical Control over Morphology and Rheology of a Weak Metallogel. Arnab Biswas, Sujay Mukhopadhyay, Roop Shikha Singh and Prof. Chemistry Select, 1, , Synthesis, characterization, DNA binding and cytotoxicity of fluoro-dipyrrin based arene ruthenium(ii) complexes. Rajendra Prasad Paitandi, Roop Shikha Singh, Sujay Mukhopadhyay, Gunjan Sharma, Biplob Koch, Pratap Vishnoi and Inorganica Chimica Acta, 454, , Interaction of ferrocene appended Ru(II), Rh(III) and Ir(III) dipyrrinato complexes with DNA/protein, molecular docking and antitumor activity. Rajendra Prasad Paitandi, Rakesh Kumar Gupta, Roop Shikha Singh, Gunjan Sharma, Biplob Koch, Eur. J. Med. Chem., 84, 17-29, Heterobimetallic Complexes based on 5-Ferrocenyldipyrromethene and Dithio-carbamates as Co-ligands: Selective Redox and Chromogenic Probes. Rakesh Kumar Gupta, Rampal Pandey, Roop shikha Singh, Nitin Srivastava, Satyen Saha, Biswajit Maiti, Peizhou Li, Qiang Xu, and Inorg. Chem., 51, , 2012.
6 22. Fluorogenic dual click derived bisglycoconjugated triazolocoumarins for selective recognition of Cu(II) ion Divya Kushwaha, Roop Shikha Singh, Vinod K. Tiwari Tetrahedron Lett., 55, , Date: Signature Place: Varanasi
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Contents Personal Details 2 Summary of Research Career 2 Research Interest 2 General Field of Expertise 2 Education 3 Employment History 3 Awards/Grants 4 Selected Journal Publications 4 Referees 6 1 Personal