Spin Transition and Structural Transformation in a
|
|
- Marvin Booker
- 5 years ago
- Views:
Transcription
1 Supporting Information for Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex Ying Guo, Xiu-Long Yang, Rong-Jia Wei, Lan-Sun Zheng, and Jun Tao* State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen , People s Republic of China Tel: ; Fax: taojun@xmu.edu.cn. S1
2 Contents Materials and Synthesis S3 Characterization and Methods S3 Table S1. Crystal Data and Structure Refinements for compounds 2 and 3 S6 Table S2. Selected bond lengths and bond angles for compound 2 HT S7 Table S3. Selected bond lengths and bond angles for compound 2 LT S7 Table S4. Selected bond lengths and bond angles for compound 3 S8 Table S5. Hydrogen bonds and C H π interactions for compounds 2 HT and 2 LT in the ab plane S8 Figure S1. ORTEP diagram of the structural unit of 2 HT S9 Figure S2. ORTEP diagram of the structural unit of 2 LT S9 Figure S3. ORTEP diagram of the structural unit of 3 S10 Figure S4. Intermolecular interactions of 2 HT in the ab plane S10 Figure S5. Intermolecular interactions of 2 LT in the ab plane S11 Figure S6. Intermolecular interactions of 3 in the ac plane S11 Figure S7. Intermolecular interactions of 2 HT in the bc plane S12 Figure S8. Intermolecular interactions of 2 LT in the bc plane S12 Figure S9. Magnetic properties of compound 2. Applied field: 5000 Oe, sweeping rate: 1 K min 1 S13 Figure S10. Magnetic properties of compound 3. Applied field: 5000 Oe, sweeping rate: 1 K min 1 S13 Figure S11. DSC trace for complex 2 upon cooling and warming S14 Figure S12. DSC trace for methanol upon cooling and warming S14 Figure S13. IR spectrum of compound 2 S15 Figure S14. IR spectrum of compound 3 S15 S2
3 Experimental Section Materials. CoCl 2 6H 2 O, KPF 6, 4 -(4 -pyridyl)-2,2 :6,2 -terpyridine (pyterpy), dichloromethane and methanol were purchased from commercial sources and used as received. Synthesis. Method 1) A CH 2 Cl 2 solution (5 ml) of pyterpy ( g, 0.1 mmol) was added dropwise to MeOH solution (5 ml) of CoCl 2 6H 2 O ( g, 0.05 mmol) and KPF 6 ( g, 0.1 mmol) at room temperature, the resulting red solution were sealed and left undisturbed for 5-7 days. Red block crystals of compound 2 and black block crystals of compound 3 suitable for X-ray diffraction analysis were separated and collected by hand. Method 2) A CH 2 Cl 2 solution (5 ml) of pyterpy ( g, 0.2 mmol) was added dropwise to MeOH solution (10 ml) of CoCl 2 6H 2 O ( g, 0.1 mmol) and KPF 6 ( g, 0.2 mmol) at room temperature, the resulting red solution were sealed and left undisturbed for 5-7 days. Red block crystals of compound 2 (without by-product 3) were collected by filtration. Structural transformation. During the synthesis of compounds 2 and 3 (method 1), the crystals of 2 and 3 were left undisturbed in the mother liquor for 3-4 weeks, all crystals of 2 were transformed to crystals of 3. Elemental analysis. Compounds 2 and 3 were unstable in air due to the loss of guest solvent molecules, so elemental analyses were conducted on the desolvated samples. Compounds 2 and 3 were heated at 50 C under vacuum for 48 h. Calcd (%) for the solvent-free sample of 2, C 40 H 28 N 8 P 2 F 12 Co: N, 11.56; C, 49.55; H, Found: N, 11.70; C, 49.36; H, IR (KBr pellet, cm 1 ) of 2: 3440(s, br), 1620(m), 1598(m), 1572(w), 1542(w), 1473(w), 1429(w), 1410(m), 1385(w), 1248(w), 1165(w), 1120(w), 836(vs), 793(w), 562(m). Calcd (%) for the solvent-free sample of 3, C 40 H 28 N 8 P 2 F 12 Co: N, 11.56; C, 49.55; H, Found: N, 11.62; C, 49.43; H, IR (KBr pellet, cm 1 ) of 3: 3433(s, br), 1618(m), 1598(m), S3
4 1543(w), 1469(w), 1408(w), 1376(m), 1076(w), 840(s), 793(w), 562(w). Physical techniques. Elemental analyses (C, H, N) were obtained using PerkinElmer 240Q elemental analyzer. IR spectra (KBr pellets) were recorded on a Nicolet 5DX spectrophotometer in the range of cm 1. X-ray crystallographic data collection and structure refinement. Single-crystal XRD data were recorded on Agilent SuperNova CCD diffractometer. The structures were solved by direct methods and refined on F 2 by anisotropic full-matrix least-squares methods using SHELXTL All non-hydrogen atoms were refined anisotropically, while hydrogen atoms were generated by the riding mode. (1) Sheldrick, G. M. SHELXS-97: Programs for crystal structure analysis, University of Göttingen, Göttingen (Germany), Magnetic measurements. Magnetic measurements were performed on freshly isolated samples and were carried out at a sweeping rate of 1 K min 1 on a Quantum Design SQUID XL7 magnetometer. The sample of compound 2 and a drop of methanol were sealed in a quartz tube. Magnetic susceptibilities were calibrated with the sample holder, and diamagnetic corrections were estimated from Pascal s constants. Differential Scanning Calorimetry (DSC) DSC (differential scanning calorimetry) measurement on compound 2 was performed by cooling and heating the sample (3.315mg), instilled a drop of methanol in an aluminum crucible using a NETZSCH DSC 200F3. The measurement was carried out at 10 K min 1 sweeping rate under nitrogen in the temperature range of K. We also measured a drop of methanol in an aluminum crucible under the same condition. From the Figure s11, we found an endothermic peak at 189 K during the warming process and an exothermic peak at 180 K during the cooling process. The DSC data indicated that the complex exhibited a reversible phase transition with a 9 K hysteresis. Figure s12 showed that pure methanol did not have either endothermic or exothermic S4
5 peak in the temperature range of K. It meant that methanol dropped in the sample did not affect the DSC data of the sample. Therefore, we could use the DSC data to estimate the enthalpy and entropy associated with the SCO and crystallographic phase transition upon heating, which are 4.99 kj mol 1 and J mol 1 K 1, respectively. S5
6 Tables Table S1. Crystal Data and Structure Refinements for compounds 2 and Temperature / K 250(2) 100(2) 173(2) Empirical formula C 34 H 36 CoF 12 N 8 O 2 P 2 C 34 H 36 CoF 12 N 8 O 2 P 2 C 43 H 36 Cl 4 CoF 12 N 8 OP 2 Mr / g mol Crystal system monoclinic monoclinic orthorhombic Space group C2/c P2 1 /c Pbca a / Å (10) (6) (4) b / Å (8) (9) (4) c / Å (3) (3) (5) β / (4) (3) V / Å (3) (2) 9617(3) Z D cald / g cm F(000) Index ranges 22 h h h h h h 18 9 h 9 7 h 9 32 h 33 Reflections collected Data / restraints / parameters 3165 / 0 / / 0 / / 0 / 640 Goodness-of-fit on F Final R indices [I > 2σ (I)] R indices (all data) S6
7 Table S2. Selected bond lengths and bond angles for compound 2 HT. Bond lengths of Co in 2 HT Bond angles of Co in 2 HT Co1 N (4) N1 Co1 N (2) Co1 N (6) N1 Co1 N (2) Co1 N (4) N1 Co1 N (2) Co1 N (6) N2 Co1 N (1) N2 Co1 N (0) N4 Co1 N (1) N1 Co1 N1# (1) N1 Co1 N4# 94.80(1) N4 Co1 N4# (1) #) x + 2, y, z + 3/2. Table S3. Selected bond lengths and bond angles for compound 2 LT. Bond lengths of Co in 2 LT Bond angles of Co in 2 LT Co1 N (5) N1 Co1 N (1) Co1 N (5) N1 Co1 N (1) Co1 N (5) N1 Co1 N (1) Co1 N (5) N1 Co1 N (1) Co1 N (5) N1 Co1 N (1) Co1 N (4) N2 Co1 N (1) N2 Co1 N (1) N2 Co1 N (1) N2 Co1 N (1) N3 Co1 N (1) N3 Co1 N (1) N3 Co1 N (1) N5 Co1 N (1) N6 Co1 N (1) S7
8 Table S4. Selected bond lengths and bond angles for compound 3. Bond lengths of Co in 3 Bond angles of Co in 3 Co1 N (2) N1 Co1 N (8) Co1 N (2) N1 Co1 N (7) Co1 N (2) N1 Co1 N (8) Co1 N (2) N1 Co1 N (8) Co1 N (2) N1 Co1 N (8) Co1 N (2) N2 Co1 N (8) N2 Co1 N (8) N2 Co1 N (9) N2 Co1 N (8) N3 Co1 N (8) N3 Co1 N (8) N3 Co1 N (9) N5 Co1 N (8) N6 Co1 N (8) Table S5. Hydrogen bonds and C H π interactions for compounds 2 HT and 2 LT in the ab plane. 2 HT 2 LT O1 F (1) O1 F (1) O1 F (1) O1 F (1) C F (1) O2 F (1) C F (1) O2 F (1) C H π 3.873(1) C F (1) C F (1) C F (1) C F (1) C H π 3.735(1)/ 3.742(1) S8
9 Figures Figure S1. ORTEP diagram of the structural unit of 2 HT. A) x + 2, y, z + 3/2. Figure S2. ORTEP diagram of the structural unit of 2 LT. S9
10 Figure S3. ORTEP diagram of the structural unit of 3. Figure S4. Intermolecular interactions of 2 HT in the ab plane. S10
11 Figure S5. Intermolecular interactions of 2 LT in the ab plane. Figure S6. Intermolecular interactions of 3 in the ac plane. S11
12 Figure S7. Intermolecular interactions of 2 HT in the bc plane. V) offset π π interactions: C centroid = 3.853(1) Å VI) offset π π interactions: centroid centroid = 3.572(1) Å VII) offset π π interactions: N centroid = 4.291(1) Å C centroid = 4.292(1) Å Figure S8. Intermolecular interactions of 2 LT in the bc plane. VI) offset π π interactions: C centroid = 3.812(1)/3.821(1) Å VII) offset π π interactions: centroid centroid = 3.555(1) Å VIII) offset π π interactions: N centroid = 4.213(1)/4.469(1) Å C centroid = 4.263(1)/4.388(1) Å S12
13 Figure S9. Magnetic properties of compound 2. Applied field: 5000 Oe, sweeping rate: 1 K min χ M T / cm 3 K mol complex T / K Figure S10. Magnetic properties of compound 3. Applied field: 5000 Oe, sweeping rate: 1 K min 1. Temperature sequence: K. 1.5 χ M T / cm 3 K mol K K K K T / K S13
14 Figure S11. DSC trace for compound 2 upon cooling and warming (10 K min 1 ). 0.8 Heat flow / mw heating cooling T / K Figure S12. DSC trace for methanol upon cooling and warming (10 K min 1 ) in the temperature range for compound 2 in order to rule out possible contribution from liquid methanol during spin transition and phase transition. 2 1 Heat flow / mw T / K S14
15 Figure S13. Infrared spectrum of compound Transmittance \% Complex Wavenumber / cm -1 Figure S14. Infrared spectrum of compound Transmittance / % Complex Wavenumber / cm -1 S15
An Anionic Metal Organic Framework For Adsorption and. Separation of Light Hydrocarbons
Supporting Information for An Anionic Metal Organic Framework For Adsorption and Separation of Light Hydrocarbons Jia Li, Hong-Ru Fu, Jian Zhang, Lan-Sun Zheng, and Jun Tao* State Key Laboratory of Physical
More informationSupporting Information. Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, and Ming-Liang Tong*
Supporting Information Wheel-shaped nanoscale 3d-4f {Co II 16Ln III 24} clusters (Ln = Dy and Gd) Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, and Ming-Liang
More informationMagnetic Metal-Organic Framework Exhibiting Quick and. Selective Solvatochromic Behavior Along With The Reversible
Magnetic Metal-Organic Framework Exhibiting Quick and Selective Solvatochromic Behavior Along With The Reversible Crystal-to-Amorphous-to-Crystal Transformation Peng Hu,, Lei Yin,, Angelo Kirchon,, Jiangli
More informationRare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Rare double spin canting antiferromagnetic behaviours in a [Co 24 ] cluster Guang-Ming Liang, Qing-Ling
More informationAll materials and reagents were obtained commercially and used without further
Reversible shrinkage and expansion of a blue photofluorescene cadmium coordination polymer and in situ tetrazole ligand synthesis Hong Deng,* a Yong-Cai Qiu, a Ying-Hua Li, a Zhi-Hui liu, a Rong-Hua Zeng,
More informationSupporting Information
Supporting Information ph-controlled Assembly of Organophosphonate-Bridged Dy(III) Single-Molecule Magnets Based on Polyoxometalates Yu Huo, Yan-Cong Chen, Si-Guo Wu, Jian-Hua Jia, Wen-Bin Chen, Jun-Liang
More informationA supramoleculear self-assembled flexible open framework based on coordination honeycomb layers possessing octahedral and tetrahedral Co II geometries
Supporting Information A supramoleculear self-assembled flexible open framework based on coordination honeycomb layers possessing octahedral and tetrahedral Co II geometries Yang Zou,* a Yuanyuan Li, a
More informationElectronic Supplementary Information. Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts
Electronic Supplementary Information Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts Sheng-Li Huang, Ai-Quan Jia and Guo-Xin Jin* Experimental
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Single-Crystal-to-Single-Crystal Transformation of an Anion Exchangeable
More informationObservation of slow relaxation of the magnetization and hysteresis. loop in antiferromagnetic ordered phase of a 2D framework based on
Observation of slow relaxation of the magnetization and hysteresis loop in antiferromagnetic ordered phase of a 2D framework based on Co II magnetic chains Shi-Yuan Zhang, a Wei Shi,* a Yanhua Lan, b Na
More informationSupporting Information for. Remarkably high temperature spin transition exhibited by two new metal-organic frameworks
Supporting Information for Remarkably high temperature spin transition exhibited by two new metal-organic frameworks Xin Bao, a Peng-Hu Guo, a Wei Liu, a Jiri Tucek, b Wei-Xiong Zhang, a Ji-Dong Leng,
More informationAn unprecedented 2D 3D metal-organic polyrotaxane. framework constructed from cadmium and flexible star-like
Electronic Supplementary Information An unprecedented 2D 3D metal-organic polyrotaxane framework constructed from cadmium and flexible star-like ligand Hua Wu, a,b Hai-Yan Liu, a Ying-Ying Liu, a Jin Yang,*
More informationthe multiple helices
Supporting Information A 3D porous metal-organic framework containing nanotubes based on the multiple helices Lei Hou,* Li-Na Jia, Wen-Juan Shi, Li-Yun Du, Jiang Li, Yao-Yu Wang* and Qi-Zhen Shi Key Laboratory
More informationAn Unusual High Thermal Stable 2D 3D Polycatenated. Fe(II) Metal-Organic Framework Showing. Guest-Dependent Spin-Crossover Behavior and High
Supporting Information for Crystal Growth & Design An Unusual High Thermal Stable 2D 3D Polycatenated Fe(II) Metal-Organic Framework Showing Guest-Dependent Spin-Crossover Behavior and High Spin-Transition
More informationFrom Double-Shelled Grids to Supramolecular Frameworks
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 From Double-Shelled Grids to Supramolecular Frameworks Jianfeng Wu, Mei Guo, Xiao-Lei Li, Lang
More informationControllable Growth of Bulk Cubic-Phase CH 3 NH 3 PbI 3 Single Crystal with Exciting Room-Temperature Stability
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Controllable Growth of Bulk Cubic-Phase CH 3 NH 3 PbI
More information[Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents
[Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents Guo-Xia Jin,,a Gui-Ying Zhu,,a Yan-Yan Sun, c Qing-Xiu Shi,
More informationOne-dimensional organization of free radicals via halogen bonding. Supporting information
One-dimensional organization of free radicals via halogen bonding Guillermo Mínguez Espallargas,* a Alejandro Recuenco, a Francisco M. Romero, a Lee Brammer, b and Stefano Libri. b a Instituto de Ciencia
More informationReversible dioxygen binding on asymmetric dinuclear rhodium centres
Electronic Supporting Information for Reversible dioxygen binding on asymmetric dinuclear rhodium centres Takayuki Nakajima,* Miyuki Sakamoto, Sachi Kurai, Bunsho Kure, Tomoaki Tanase* Department of Chemistry,
More informationSupplementary Material
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supplementary Material Spin crossover and reversible single-crystal to single-crystal
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supporting Information Rare metal-ion metathesis of tetrahedral Zn(II) core of a noncentrosymmetric
More informationSupporting Information. for. Angew. Chem. Int. Ed Wiley-VCH 2004
Supporting Information for Angew. Chem. Int. Ed. 246736 Wiley-VCH 24 69451 Weinheim, Germany 1 Challenges in Engineering Spin Crossover. Structures and Magnetic Properties of six Alcohol Solvates of Iron(II)
More informationSupplementary Figure 1 IR Spectroscopy. 1Cu 1Ni Supplementary Figure 2 UV/Vis Spectroscopy. 1Cu 1Ni
Supplementary Figure 1 IR Spectroscopy. IR spectra of 1Cu and 1Ni as well as of the starting compounds, recorded as KBr-pellets on a Bruker Alpha FTIR spectrometer. Supplementary Figure 2 UV/Vis Spectroscopy.
More informationCu(I)-MOF: naked-eye colorimetric sensor for humidity and. formaldehyde in single-crystal-to-single-crystal fashion
Supporting Information for Cu(I)-MOF: naked-eye colorimetric sensor for humidity and formaldehyde in single-crystal-to-single-crystal fashion Yang Yu, Xiao-Meng Zhang, Jian-Ping Ma, Qi-Kui Liu, Peng Wang,
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 A rare case of a dye co-crystal showing better dyeing performance Hui-Fen Qian, Yin-Ge Wang,
More information= (8) V = (8) Å 3 Z =4 Mo K radiation. Data collection. Refinement. R[F 2 >2(F 2 )] = wr(f 2 ) = S = reflections
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 1-(3-Amino-1H-inden-2-yl)ethanone Dong-Yue Hu and Zhi-Rong Qu* Ordered Matter Science Research Center, College
More informationSupplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient
Supplementary Material (ESI) for CrystEngComm An ideal metal-organic rhombic dodecahedron for highly efficient adsorption of dyes in an aqueous solution Yuan-Chun He, Jin Yang,* Wei-Qiu Kan, and Jian-Fang
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Bridging different Co 4 -calix[4]arene building blocks into grids, cages
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Information (ESI) S1 Experimental Section: Materials and methods: All commercially available chemicals were used as supplied without further purification. The Q[5] was synthesized
More informationIron Complexes of a Bidentate Picolyl NHC Ligand: Synthesis, Structure and Reactivity
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supplementary Information for Iron Complexes of a Bidentate Picolyl HC Ligand: Synthesis,
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) Enhancing stability and porosity of penetrated
More informationCollege of Materials Science and Engineering, Nanjing Tech University, Nanjing , P. R. China
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Extra thermostable one-dimensional organic-inorganic hybrid perovskite [N-methyldabconium]PbI 3
More informationStabilizing vitamin D 3 by conformationally selective co-crystallization
Supporting Information for Stabilizing vitamin D 3 by conformationally selective co-crystallization Jian-Rong Wang, Chun Zhou, Xueping Yu and Xuefeng Mei* Pharmaceutical Analytical & Solid-State Chemistry
More information1. X-ray crystallography
From Selenidostannates to Silver-Selenidostannate: Structural Variation of Chalcogenidometallates Synthesized in Ionic Liquids Jian-Rong Li a, Wei-Wei Xiong a, Zai-Lai Xie a, Cheng-Feng Du a, Guo-Dong
More informationSupporting Information
Supporting Information Heteroligand o-semiquinonato-formazanato cobalt complexes Natalia A. Protasenko, Andrey I. Poddel sky,*, Artem S. Bogomyakov, Georgy K. Fukin, Vladimir K. Cherkasov G.A. Razuvaev
More informationSupporting Information Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure
Supporting Information Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure Thais Grancha, Marta Mon, Francesc Lloret, Jesús Ferrando-Soria,* Yves Journaux, Jorge Pasán,
More informationDepartment of Chemistry, Tianjin University, Tianjin , P. R. China Tel:
Electronic Supplementary Information Analysis of factors governing the formation of single-stranded helical coordination polymers from a macrocyclic metalloligand and Ca 2+, Mn 2+, Fe 2+, Co 2+, Ni 2+,
More informationZ =8 Mo K radiation = 0.35 mm 1. Data collection. Refinement. R[F 2 >2(F 2 )] = wr(f 2 ) = S = reflections
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 4-Amino-3-(4-pyridyl)-1,2,4-triazole- 5(4H)-thione Fang Zou, Wei-Min Xuan, Xue-Ming Fang and Hui Zhang* State
More informationSupporting Information
Supporting Information A Sn IV -Porphyrin-Based Metal-Organic Framework for the Selective Photo-Oxygenation of Phenol and Sulfides Ming-Hua Xie, Xiu-Li Yang, Chao Zou and Chuan-De Wu* Department of Chemistry,
More informationImpeller-like dodecameric water clusters in metal organic nanotubes
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Impeller-like dodecameric water clusters in metal organic
More informationPrabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra*
Supporting Information Ferrocenyl BODIPYs: Synthesis, Structure and Properties Prabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra* Department of Chemistry, Indian Institute of Technology
More informationSupporting Information. Table of Contents
Supporting Information Selective Anion Exchange and Tunable Luminescent Behaviors of Metal-Organic Framework Based Supramolecular Isomers Biplab Manna, Shweta Singh, Avishek Karmakar, Aamod V.Desai and
More informationA Ladder type Iron(II) Coordination Polymer with Cooperative Spin Transition
Supporting Information for A Ladder type Iron(II) Coordination Polymer with Cooperative Spin Transition Wolfgang Bauer, a Stephan Schlamp a and Birgit Weber* a a Inorganic Chemistry II, Universität Bayreuth,
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Supporting Information Significant enhancement of conductance for a hybrid layered molybdate semiconductor
More informationSelective Binding and Removal of Organic Molecules in a Flexible Polymeric Material with Stretchable Metallosalen Chains
Selective Binding and Removal of Organic Molecules in a Flexible Polymeric Material with Stretchable Metallosalen Chains Gao Li, Chengfeng Zhu, Xiaobing Xi and Yong Cui* School of Chemistry and Chemical
More informationHeterometallic Strategy to Achieve Large Magnetocaloric Effect. in Polymeric 3d Complexes
. This journal is The Royal Society of Chemistry 2015 Supporting Information for Heterometallic Strategy to Achieve Large Magnetocaloric Effect in Polymeric 3d Complexes Jiong-Peng Zhao, a,b Song-De Han,
More informationA water-stable zwitterionic dysprosium carboxylate metal organic. framework: a sensing platform for Ebolavirus RNA sequences
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 A water-stable zwitterionic dysprosium carboxylate metal organic framework: a sensing platform
More informationSupporting Information
Supporting Information Polyoxometalate-based crystalline tubular microreactor: redox-active inorganic-organic hybrid materials producing gold nanoparticles and catalytic properties Dong-Ying Du, Jun-Sheng
More informationSimultaneously enhancing the solubility and permeability of
Supporting information for Simultaneously enhancing the solubility and permeability of acyclovir by crystal engineering approach Yan Yan, Jia-Mei Chen*, and Tong-Bu Lu* Experimental section General remarks:
More informationSupporting Information for
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2015 Supporting Information for Slow magnetic relaxation in a novel carboxylate/oxalate/hydroxyl
More informationHalogen bonding of N-bromosuccinimide by grinding
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 SUPPORTING INFORMATION Halogen bonding of N-bromosuccinimide by grinding Juraj Mavračić, Dominik
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information (ESI) A Large Spin, Magnetically Anisotropic, Octanuclear
More informationmetal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Dichloridotris(trimethylphosphine)- nickel(ii) Ruixia Cao, Qibao Wang and Hongjian Sun* School of Chemistry
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information A cage-based cationic body-centered tetragonal metal-organic framework:
More information1. General Experiments... S2. 2. Synthesis and Experiments... S2 S3. 3. X-Ray Crystal Structures... S4 S8
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Gate-Opening upon CO 2 Adsorption on a Metal Organic
More informationElectronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented
Electronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented stable microporous metal-imidazolate framework Shui-Sheng Chen, a,c Min Chen, a Satoshi Takamizawa,
More informationElectronic Supplementary Information. Supramolecular approaches to metal-organic gels using. Chevrel-type coordination clusters as building units
Electronic Supplementary Information Supramolecular approaches to metal-organic gels using Chevrel-type coordination clusters as building units Lei Zhang, a Bartosz Marzec, a Rodolphe Clérac, b,c Yanhui
More informationSelective total encapsulation of the sulfate anion by neutral nano-jars
Supporting Information for Selective total encapsulation of the sulfate anion by neutral nano-jars Isurika R. Fernando, Stuart A. Surmann, Alexander A. Urech, Alexander M. Poulsen and Gellert Mezei* Department
More informationSupporting Information
Supporting Information New Hexaphosphane Ligands 1,3,5-C 6 H 3 {p-c 6 H 4 N(PX 2 ) 2 } 3 [X = Cl, F, C 6 H 3 OMe(C 3 H 5 )]: Synthesis, Derivatization and, Palladium(II) and Platinum(II) Complexes Sowmya
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 214 Electronic Supplementary Information (ESI) Dehydration-triggered magnetic phase conversion
More informationin a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)]
Supporting Information Stepwise and Hysteretic Sorption N 2, O 2, CO 2, and H 2 Gases in a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)] Hye Jeong Park and Myunghyun Paik Suh Contribution from
More informationDynamics of Caged Imidazolium Cation Toward Understanding The Order-Disorder Phase Transition and Switchable Dielectric Constant
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electonic Supporting Information Dynamics of Caged Imidazolium Cation Toward Understanding
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Table of Contents S1 1. General materials and methods S2 2. Syntheses of {Pd 84 } and {Pd 17 } S3-S4 3. MS studies of {Pd 84 }, {Pd 17 } and the two-component reactions S5-S6 4.
More informationmetal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 = 86.130 (2) = 81.155 (2) = 76.289 (3) V = 699.69 (4) Å 3 Z =2 Mo K radiation = 1.58 mm 1 T = 293 (2) K
More informationElectronic Supplementary Information
Electronic Supplementary Information Thermally Reversible Single-Crystal to Single-Crystal Transformation of Mononuclear to Dinuclear Zn(II) Complexes By[2+2] Cycloaddition Reaction Raghavender Medishetty,
More informationHeterometallic M II Ln III (M = Co / Zn; Ln = Dy / Y) complexes with pentagonal bipyramidal 3d centres: syntheses, structures, and magnetic properties
Supporting Information for Heterometallic M II Ln III (M = Co / Zn; Ln = Dy / Y) complexes with pentagonal bipyramidal 3d centres: syntheses, structures, and magnetic properties Fu-Xing Shen, Hong-Qing
More informationElectronic Supporting Information for
Electronic Supporting Information for Microporous metal-organic open framework containing uncoordinated carbonyl groups as postsynthetic modification sites for cation exchange and Tb 3+ sensor Jianwei
More informationion, as obtained from a search of the Cambridge Structural database (CSD), December 2013.
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2014 SI Figure S1. The reported bridging modes of the CO 3 2- ion, as obtained from a
More informationOrdnung muss sein: heteroelement order and disorder in polyoxovanadates
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Ordnung muss sein: heteroelement order and disorder in polyoxovanadates M. Wendt a,
More informationSupporting Information. Functionalized 1, 2- and 1, 3-Dithioles
Supporting Information Switching Selectivity of α-enolic dithioesters: One pot Access to Functionalized 1, 2- and 1, 3-Dithioles Suvajit Koley, Tanmoy Chanda, Subhasis Samai and Maya Shankar Singh*, Department
More informationSupporting Information
Supporting Information Unprecedented solvent-dependent sensitivities in highly efficient detection of metal ions and nitroaromatic compounds by a fluorescent Ba MOF Rongming Wang, Xiaobin Liu, Ao Huang,
More informationSupplementary Information. Two Cyclotriveratrylene Metal-Organic Frameworks as Effective Catalysts
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supplementary Information Two Cyclotriveratrylene Metal-Organic Frameworks as Effective
More informationSupporting Information
Selective Hg 2+ sensing behaviors of rhodamine derivatives with extended conjugation based on two successive ring-opening processes Chunyan Wang a,b and Keith Man-Chung Wong a,b * a Department of Chemistry,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2018 Supporting Information A difunctional metal organic framework with Lewis
More informationOrthorhombic, Pbca a = (3) Å b = (15) Å c = (4) Å V = (9) Å 3. Data collection. Refinement
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 N 0 -(3,4-Dimethylbenzylidene)furan-2- carbohydrazide Yu-Feng Li a and Fang-Fang Jian b * a Microscale Science
More informationSupporting Information
Supporting Information The Heptacyanotungstate(IV) Anion: A New 5 d Transition-Metal Member of the Rare Heptacyanometallate Family of Anions Francisco J. Birk, Dawid Pinkowicz, and Kim R. Dunbar* anie_201602949_sm_miscellaneous_information.pdf
More informationSupporting Information
Supporting Information A Diiron Amido-Imido Complex [(Cp*Fe) 2 (µ 2 -NHPh)(µ 2 -NPh)]: Synthesis and a Net Hydrogen Atom Abstraction Reaction to Form a Bis(imido) Complex Shin Takemoto, Shin-ichiro Ogura,
More informationElectronic Supplementary Information
Electronic Supplementary Information Early-Late Heterobimetallic Rh-Ti and Rh-Zr Complexes via Addition of Early Metal Chlorides to Mono- and Divalent Rhodium Dan A. Smith and Oleg V. Ozerov* Department
More informationDavid L. Davies,*, 1 Charles E. Ellul, 1 Stuart A. Macgregor,*, 2 Claire L. McMullin 2 and Kuldip Singh. 1. Table of contents. General information
Experimental Supporting Information for Experimental and DFT Studies Explain Solvent Control of C-H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of eutral and Cationic Heterocycles
More information= (3) V = (4) Å 3 Z =4 Mo K radiation. Data collection. Refinement. R[F 2 >2(F 2 )] = wr(f 2 ) = S = 1.
Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 4,4-Diacetylheptanedinitrile Guo-wei Wang, a Jian Zhang, a Ling-hua Zhuang, b Wen-yuan Wu b and Jin-tang Wang b * a Department of
More informationHydrophobic Ionic Liquids with Strongly Coordinating Anions
Supporting material Hydrophobic Ionic Liquids with Strongly Coordinating Anions Hasan Mehdi, Koen Binnemans*, Kristof Van Hecke, Luc Van Meervelt, Peter Nockemann* Experimental details: General techniques.
More informationSupporting Information. Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008
Supporting Information pyright Wiley-VCH Verlag GmbH &. KGaA, 69451 Weinheim, 2008 Time-Evolving Self-rganization and Autonomous Structural Adaptation of balt(ii) rganic Framework Materials with Nets scu
More informationSupporting Information. Lacunary Polytungstate Ligands
This journal is The Royal Society of Chemistry 0 Supporting Information Heterometallic Appended {MMn III } Cubanes Encapsulated by Lacunary Polytungstate Ligands Hai-Hong Wu, Shuang Yao, Zhi-Ming Zhang,*
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information One 1D anionic coordination polymer showing
More informationSynthesis and structural characterization of homophthalic acid and 4,4-bipyridine
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 2014, 6(4):905-909 Research Article ISSN : 0975-7384 CODEN(USA) : JCPRC5 Synthesis and structural characterization of homophthalic
More informationpowder in good yield (36%) from the reaction of CH 3 (CH 2 ) 8 COONa.2H 2 O with OTf = Trifluoromethanesulfonate by Korendovych [80].
4.2 [Fe 2 (RCOO) 4 (bpy)] The general steps for the syntheses of [Fe(CH 3 (CH 2 ) n COO) 2 (bpy)], where n = 8 (6), 10 (7), 12 (8), and 14 (9), are shown in Scheme 4.2. 2 RCOO - Fe 2+ [Fe(RCOO) 2 ] bpy
More informationExploring the Surfactant Thermal Synthesis of Crystalline Functional Thioarsenates
Electronic Supporting information for: Exploring the Surfactant Thermal Synthesis of Crystalline Functional Thioarsenates Dan-Dan Yang, Ying Song, Bo Zhang, Nan-Nan Shen,, Gui-Lan Xu, Wei-Wei Xiong,*,
More informationSupporting Information
Supporting Information Predictable Self-assembled [2x2] Ln(III) 4 Square Grids (Ln = Dy,Tb) SMM Behaviour in a New Lanthanide Cluster Motif. Muhammad Usman Anwar, a Laurence Kenneth Thompson,* a Louise
More information,
2013. 54, 6. 1115 1120 UDC 548.737:547.12 CHARACTERIZATION AND CRYSTAL STRUCTURES OF SOLVATED N -(4-HYDROXY-3-NITROBENZYLIDENE)-3-METHYLBENZOHYDRAZIDE AND N -(4-DIMETHYLAMINOBENZYLIDENE)-3-METHYLBENZOHYDRAZIDE
More informationBenzene Absorption in a Protuberant-Grid-Type Zinc(II) Organic Framework Triggered by the Migration of Guest Water Molecules
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Benzene Absorption in a Protuberant-Grid-Type Zinc(II)
More informationSynthesis and crystal structure of tris(1,10-phenanthroline)-nickel(ii) diperchlorate
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 2014, 6(4):869-873 Research Article ISSN : 0975-7384 CODEN(USA) : JCPRC5 Synthesis and crystal structure of tris(1,10-phenanthroline)-nickel(ii)
More informationSupporting Information
Supporting Information Wiley-VCH 2006 69451 Weinheim, Germany A New Melt Approach to the Synthesis of catena- Phosphorus Dications to Access the First Derivatives of 2+ ** [P 6 Ph 4 R 4 ] Jan J. Weigand*,
More informationSupplemental Information
Supplemental Information Template-controlled Face-to-Face Stacking of Olefinic and Aromatic Carboxylic Acids in the Solid State Xuefeng Mei, Shuanglong Liu and Christian Wolf* Department of Chemistry,
More informationVerdazyl Radical as Building Block for a Six Spin Centers 2p-3d-4f Single-Molecule Magnet
Supporting Information (SI) for the manuscript: Verdazyl Radical as Building Block for a Six Spin Centers p-d-f Single-Molecule Magnet Ghénadie Novitchi, Sergiu Shova, Yanhua Lan, Wolfgang Wernsdorfer
More informationSupporting Information
Supporting Information One-Pot Access to Benzo[a]carbazoles via Palladium(II)-Catalyzed Hetero- and Carboannulations Moumita Jash, Bimolendu Das, and Chinmay Chowdhury* Organic & dicinal Chemistry Division,
More informationReversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether
Supplementary Information Reversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether Xiao-Ping Zhou, a Zhengtao Xu,*,a Matthias Zeller, b Allen
More informationb = (13) Å c = (13) Å = (2) V = (19) Å 3 Z =2 Data collection Refinement
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 b = 12.4861 (13) Å c = 12.9683 (13) Å = 90.748 (2) V = 1051.10 (19) Å 3 Z =2 Mo K radiation = 3.87 mm 1 T = 193
More informationJuan Manuel Herrera, Enrique Colacio, Corine Mathonière, Duane Choquesillo-Lazarte, and Michael D. Ward. Supporting information
Cyanide-bridged tetradecanuclear Ru II 3M II 11 clusters (M II = Zn II and Cu II ) based on the high connectivity building block [Ru 3 (HAT)(CN) 12 ] 6+ : structural and photophysical properties Juan Manuel
More informationA Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties
Supporting information for A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties Suresh Sanda, Srinivasulu Parshamoni and SanjitKonar* Department of
More informationTransformations: New Approach to Sampagine derivatives. and Polycyclic Aromatic Amides
-1- An Unexpected Rearrangement which Disassembles Alkyne Moiety Through Formal Nitrogen Atom Insertion between Two Acetylenic Carbons and Related Cascade Transformations: New Approach to Sampagine derivatives
More information