Supplementary Information
|
|
- Jeremy Griffith
- 5 years ago
- Views:
Transcription
1 Supplementary Information Stable aluminum metal-organic frameworks (Al-MOFs) for balanced CO 2 and water selectivity Haiwei Li, Xiao Feng, * Dou Ma, Mengxi Zhang, Yuanyuan Zhang, Yi Liu, Jinwei Zhang, and Bo Wang * Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing , P. R. China. * bowang@bit.edu.cn; fengxiao86@bit.edu.cn Contents Section A. Materials and methods Section B. Experimental section Section C. Crystal structure and supplementary spectra Section D. Supporting references S-1
2 Section A. Materials and method All reagents and starting materials were obtained commercially and were used as received without any further purification. 2-hydrox-1,4-benzendicarboxylicacid (OH-BDC), 2-methyl-1,4-benzendicarboxylicacid (CH 3 -BDC) and 2,5-dimethyl-1,4-benzendicarboxylicacid [(CH 3 ) 2 -BDC] were purchased from Chemsoon Co., Ltd., 2-amino-1,4-benzendicarboxylicacid (NH 2 -BDC) and AlCl 3 6H 2 O were bought from Energy Chemical. DMF and methanol were purchased from Beijing Chemical Works. Powder X-ray diffraction (PXRD) patterns of the samples were recorded on a Bruker Focus D8 diffractometer with Cu-Kα X-ray radiation (λ = nm). The attenuated total reflection Fourier-transform infrared (ATR-FTIR) spectra were recorded in the range cm -1 on Bruker ALPHA spectrometer. N 2 sorption isotherms were measured at 77 K on a Quantachrome Instrument ASiQMVH002-5 after pretreatment (samples were degassed at 150 C for 10 h). The pore size distributions were estimated using nonlocal density functional theory (NLDFT) with N 2-77 K isotherm curves. CO 2 and H 2 O sorption isotherms were measured on the same instrument after pretreatment. Elemental analyses (C, H, N) were obtained using EuroEA Elemental Analyser. Al content was determined by a PLASMA-SPEC (I) ICP atomic emission spectrometer. The thermogravimetric analysis (TGA) of samples was performed on a PerkinElmer STA6000 Simultaneous Thermal Analyzers with a constant heating rate of 10 C min -1 under air in a temperature range from r.t. to 800 C. S-2
3 Section B. Synthetic procedures Preparation of MOFs (a) Synthesis of CAU-1: CAU-1 was synthesized according to the reported literature 1 with slight modification. AlCl 3 6H 2 O (93.0 mg, mmol) and NH 2 -BDC (23.3 mg, mmol) were dissolved in 1.25 ml of methanol in a 4 ml jar with a teflon lined lid. The reaction mixture was heated in an oven at 125 C for 5 h to yield yellow microcrystalline powder. After centrifugation, the remaining solid was stirred in 100 ml deionized water to remove chloride ions, and then washed three times with 500 ml of anhydrous DMF. After that, the product was soaked in CHCl 3 for 3 days with fresh solvent exchanged every 24 h. Finally, the solvent was decanted and the included CHCl 3 was removed under vacuum to give the product CAU-1. (b) Synthesis of BIT-72: AlCl 3 6H 2 O (93.0 mg, mmol) and 2-hydrox-1,4-benzendicarboxylicacid (23.5 mg, mmol) were dissolved in 1.25 ml of methanol in a 4 ml jar with a teflon lined lid. The reaction mixture was heated in an oven at 125 C for 5 h to yield white microcrystalline powder. After centrifugation, the remaining solid was first stirred in deionized water (500 ml per 0.5 g) to remove chloride ions, and then washed three times with 500 ml of anhydrous DMF. After that, the product was soaked in CHCl 3 for 3 days with fresh solvent exchanged every 24 h. Finally, the solvent was decanted and the included CHCl 3 was removed under vacuum to give the product BIT-72. (c) Synthesis of BIT-73: S-3
4 AlCl 3 6H 2 O (93.0 mg, mmol) and 2-methyl-1,4-benzendicarboxylicacid (23.2 mg, mmol) were dissolved in 1.25 ml of methanol in a 4 ml jar with a teflon lined lid. The reaction mixture was heated in an oven at 125 C for 5 h to yield white microcrystalline powder. After centrifugation, the remaining solid was first stirred in deionized water (500 ml per 0.5 g) to remove chloride ions, and then washed three times with 500 ml of anhydrous DMF. After that, the product was soaked in CHCl 3 for 3 days with fresh solvent exchanged every 24 h. Finally, the solvent was decanted and the included CHCl 3 was removed under vacuum to give the product BIT-73. (d) Synthesis of BIT-74: AlCl 3 6H 2 O (98.0 mg, mmol) and 2,5-dimethyl-1,4-benzendicarboxylicacid (26.0 mg, mmol) were dissolved in 1.25 ml of methanol in a 4 ml jar with a teflon lined lid. The reaction mixture was heated in an oven at 125 C for 5 h to yield white microcrystalline powder. After centrifugation, the remaining solid was first stirred in deionized water (500 ml per 0.5 g) to remove chloride ions, and then washed three times with 500 ml of anhydrous DMF. After that, the product was soaked in CHCl 3 for 3 days with fresh solvent exchanged every 24 h. Finally, the solvent was decanted and the included CHCl 3 was removed under vacuum to give the product BIT-74. S-4
5 Section C: Crystal structure and supplementary spectra Figure S1. The crystalline structure of two cages of BIT-72/73/74. In the crystals of BIT-72/73/74, four 8-rings secondary building units (SBUs) form the tetrahedral cage while the octahedral cage is formed by six SBUs. S-5
6 Figure S2. FT-IR spectra of NH 2 -BDC (black) and CAU-1 (red) S-6
7 Figure S3. FT-IR spectra of OH-BDC (black) and BIT-72 (red) S-7
8 Figure S4. FT-IR spectra of CH 3 -BDC (black) and BIT-73 (red) S-8
9 Figure S5. FT-IR spectra of (CH 3 ) 2 -BDC (black) and BIT-74 (red) S-9
10 Table S1. Elemental analysis and inductively-coupled plasma emission spectroscopy (ICP) results Materials Experimental value (wt%) Calculated value (wt%) C H N Al C H N Al CAU BIT BIT BIT S-10
11 Figure S6. TGA curve of CAU-1 under air with a heating rate of 5 K/min S-11
12 Figure S7. TGA curve of BIT-72 under air with a heating rate of 5 K/min S-12
13 Figure S8. TGA curve of BIT-73 under air with a heating rate of 5 K/min S-13
14 Figure S9. TGA curve of BIT-74 under air with a heating rate of 5 K/min S-14
15 Figure S10. Pore size distribution curves of CAU-1 (red), BIT-72 (pink), BIT-73 (navy) and BIT-74 (violet) based on NLDFT from N 2-77 K isotherms S-15
16 Table S2. Data from N 2-77 K isotherm curves Materials 1 S BET V total V mico PSD 2 (m 2 g -1 ) (cm 3 g -1 ) (cm 3 g -1 ) (nm) CAU , 0.86 BIT , 0.86 BIT , 0.86 BIT , : Calculated with the point at P/P 0 = : Pore size distribution based on nonlocal density functional theory (NLDFT) method. S-16
17 Table S3. CO 2 uptake of several selected water stable MOFs at 273 K and 1 bar Materials CO 2 uptake (cm 3 g -1 ) Reference BIT in this work BIT in this work BIT in this work In 2 (OH)(btc)(Hbtc) 0.4 (L) 0.6 3H 2 O 75 Inorg. Chem., 2016, 55, PCP Inorg. Chem., 2015, 54, Bio-MOF Chem. Sci., 2013, 4, Bio-MOF Chem. Sci., 2013, 4, Bio-MOF Chem. Sci., 2013, 4, Ni-4PyC 123 Sci. Adv., 2015, 1:e ZIF Science, 2008, 319, UiO Chem. Eur. J., 2015, 21, MIL-125(Ti) 99 Angew. Chem. Int. Ed., 2012, 51, NH 2 -MIL-125(Ti) 132 Angew. Chem. Int. Ed., 2012, 51, MIL-101(Cr) 75 New J. Chem., 2016,40, PCN J. Am. Chem. Soc., 2015, 137, ZIF-8 37 RSC Adv., 2015, 5, MIL-53(Al) 76 Fuel, 2012, 102, NU J. Am. Chem. Soc., 2013, 135, S-17
18 Figure S11. CO K isotherm curves of CAU-1 S-18
19 Figure S12. CO K isotherm curves of BIT-72 S-19
20 Figure S13. CO K isotherm curves of BIT-73 S-20
21 Figure S14. CO K isotherm curves of BIT-74 S-21
22 Figure S15. N K isotherm curves of CAU-1 (red), BIT-72 (blue), BIT-73 (pink) and BIT-74 (navy) S-22
23 Figure S16. PXRD patterns of CAU-1 simulated (black line), CAU-1 as-synthesized (orange line), after treatment of H 2 O at r.t. for 3 days (blue line), 100 C H 2 O for one hour (green line) and ph = 4 at r.t. for 3 days (pink line) S-23
24 Figure S17. PXRD patterns of CAU-1 simulated (black line), BIT-72 (red line), BIT-73 (blue line), BIT-74 (green line) and CAU-1 as synthesized (pink line) after treatment of ph = 9 basic aqueous at r.t. for 3 days. The good stability of BIT-72/73/74 can be explained by the hard/soft acid-base principle where Al 3+ ions act as hard acid while oxygen donors on carboxylate ligands act as hard base. Thus, relative strong bonds are formed between Al 3+ and carboxylate ligands in these Al-MOFs and lead to good stability in water, acidic and basic conditions. S-24
25 Ideal adsorbed solution theory (IAST) selectivity calculations: Ideal Adsorbed Solution Theory (IAST) of Myers and Prausnitz along with the pure component isotherm fits was applied to determine the molar loadings in the gas mixture for specified partial pressures in the bulk gas phase. The pure component isotherms of CO 2 measured were fitted with the dual-site Langmuir (DSL) model: The pure component isotherms of N 2 measured were fitted with the single-site Langmuir (SSL) model: where q is molar loading of adsorbate (mmol g 1 ), q sat is saturation loading (mmol g 1 ), b is parameter in the pure component Langmuir isotherm (bar 1 ), p is bulk gas phase pressure (bar). Pure-component isotherm fitting parameters were then used for calculating IAST binary-gas adsorption selectivities (S ads ). S ads is defined as: S-25
26 Figure S18. H 2 O-283 K isotherm curves of CAU-1 S-26
27 Figure S19. H 2 O-283 K isotherm curves of BIT-72 S-27
28 Figure S20. H 2 O-283 K isotherm curves of BIT-73 S-28
29 Figure S21. H 2 O-283 K isotherm curves of BIT-74 S-29
30 Section D. Supporting references 1. T. Ahnfeldt, N. Guillou, D. Gunzelmann, I. Margiolaki, T. Loiseau, G. Férey, J. Senker and N. Stock, Angew. Chem. Int. Ed., 2009, 48, S-30
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information A Highly stable Metal- and Nitrogen-doped Nanocomposite derived from Zn/Ni-ZIF-8
More informationSupporting Information
Supporting Information Photoinduced Postsynthetic Polymerization of a Metal Organic Framework toward a Flexible Stand-Alone Membrane** Yuanyuan Zhang, Xiao Feng,* Haiwei Li, Yifa Chen, Jingshu Zhao, Shan
More informationSupporting Information. Rapid synthesis of metal-organic frameworks MIL-101(Cr) without the addition of solvent and hydrofluoric acid
Supporting Information Rapid synthesis of metal-organic frameworks MIL-11(Cr) without the addition of solvent and hydrofluoric acid Kunyue Leng a, Yinyong Sun a *, Xiaolin Li a, Shun Sun a, Wei Xu b a
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) Enhancing stability and porosity of penetrated
More informationSupporting Information
Supporting Information A strategy toward constructing bifunctionalized MF catalyst: post-synthesized modification of MFs on organic ligands and coordinatively unsaturated metal sites Baiyan Li, Yiming
More informationSupplementary Information
Supplementary Information Partitioning MOF-5 into confined and hydrophobic compartments for carbon capture under humid conditions Nan Ding, Haiwei Li, Xiao Feng,* Qianyou Wang, Shan Wang, Li Ma, Junwen
More informationReversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether
Supplementary Information Reversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether Xiao-Ping Zhou, a Zhengtao Xu,*,a Matthias Zeller, b Allen
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2018 Supporting Information 2-Methylimidazole-Assisted Synthesis of Two-Dimensional MOF-5 Catalyst
More informationSupporting Information
Supporting Information Zeolitic Imidzolate Framework-8 as Efficient ph-sensitive Drug Delivery Vehicle Chun-Yi Sun, Chao Qin, Xin-Long Wang,* Guang-Sheng Yang, Kui-Zhan Shao, Ya-Qian Lan, Zhong-Min Su,*
More informationMetal-organic frameworks (MOFs) as precursors towards TiO x /C. composites for photodegradation of organic dye
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supplementary Information Metal-organic frameworks (MOFs) as precursors towards TiO x /C composites
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supporting Information Rare metal-ion metathesis of tetrahedral Zn(II) core of a noncentrosymmetric
More informationElectronic supplementary information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information Heterogeneous nucleation and growth of highly crystalline
More informationElectronic Supplementary Information (ESI) From metal-organic framework to hierarchical high surface-area hollow octahedral carbon cages
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information (ESI) From metal-organic framework to hierarchical high surface-area
More informationSupporting information. Mechanical Properties of Microcrystalline Metal-Organic Frameworks. (MOFs) Measured by Bimodal Amplitude Modulated-Frequency
Supporting information Mechanical Properties of Microcrystalline Metal-Organic Frameworks (MOFs) Measured by Bimodal Amplitude Modulated-Frequency Modulated Atomic Force Microscopy Yao Sun, Zhigang Hu,
More informationSynthesis of homochiral zeolitic imidazolate frameworks via solvent-assisted linker exchange for enantioselective sensing and separation
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2018 Supporting Information Synthesis of homochiral zeolitic imidazolate frameworks via solvent-assisted
More informationA flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases. Supporting Information
A flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases Jingming Zhang, a Haohan Wu, a Thomas J. Emge, a and Jing Li* a a Department of Chemistry and Chemical Biology,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2018 Supporting Information A difunctional metal organic framework with Lewis
More informationSupporting information A Porous Zr-cluster-based Cationic Metal-Organic Framework for Highly Efficient Cr 2 O 7
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting information A Porous Zr-cluster-based Cationic Metal-Organic Framework for Highly Efficient
More informationPreparation of Nanofibrous Metal-Organic Framework Filters for. Efficient Air Pollution Control. Supporting Information
Preparation of Nanofibrous Metal-Organic Framework Filters for Efficient Air Pollution Control Supporting Information Yuanyuan Zhang, Shuai Yuan, Xiao Feng, Haiwei Li, Junwen Zhou, Bo Wang* Contents Section
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 214 Supporting Information Lei Liu, ab Yijie Xia, b Jie Zhang* b a) China Center for Modernization
More informationA new tetrazolate zeolite-like framework for highly selective CO 2 /CH 4 and CO 2 /N 2 separation
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Material (ESI) for ChemComm. Supporting Information A new tetrazolate
More informationElectronic Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supporting Information Amine-functionalized metal-organic framework as a sensing platform
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 Supplementary Information Efficient vapor-assisted aging synthesis of functional and high
More informationSynthesis of 2 ) Structures by Small Molecule-Assisted Nucleation for Plasmon-Enhanced Photocatalytic Activity
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Synthesis of Au@UiO-66(NH 2 ) Structures by Small Molecule-Assisted
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Novel Nanoporous Ferrocenyl Framework for Clean Energy Application Qingquan
More informationElectronic supplementary information (ESI)
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information (ESI) Two novel organic phosphorous-based MOFs:
More informationAn unprecedented 2D 3D metal-organic polyrotaxane. framework constructed from cadmium and flexible star-like
Electronic Supplementary Information An unprecedented 2D 3D metal-organic polyrotaxane framework constructed from cadmium and flexible star-like ligand Hua Wu, a,b Hai-Yan Liu, a Ying-Ying Liu, a Jin Yang,*
More informationSupplementary Information
Site-Selective Cyclometalation of a Metal-Organic Framework Phuong V. Dau, Min Kim, and Seth M. Cohen* Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive,
More informationSupplementary Information for
Supplementary Information for Microwave-Assisted Solvothermal Synthesis of Zirconium Oxide Based Metal-Organic Frameworks Weibin Liang and Deanna M. D Alessandro* School of Chemistry, The University of
More informationA vanadium(iv) pyrazolate metal organic polyhedron with permanent porosity and adsorption selectivity
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic supporting Information A vanadium(iv) pyrazolate metal organic polyhedron with permanent
More informationDepartment of Chemistry, Tianjin University, Tianjin , P. R. China Tel:
Electronic Supplementary Information Analysis of factors governing the formation of single-stranded helical coordination polymers from a macrocyclic metalloligand and Ca 2+, Mn 2+, Fe 2+, Co 2+, Ni 2+,
More informationthe multiple helices
Supporting Information A 3D porous metal-organic framework containing nanotubes based on the multiple helices Lei Hou,* Li-Na Jia, Wen-Juan Shi, Li-Yun Du, Jiang Li, Yao-Yu Wang* and Qi-Zhen Shi Key Laboratory
More informationEfficient Molybdenum (VI) Modified Zr-MOF Catalyst for
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Efficient Molybdenum (VI) Modified Zr-MOF Catalyst for Epoxidation of Olefins Jia Tang, a Wenjun
More informationSupporting Information
A Calcium Coordination Framework Having Permanent Porosity and High CO 2 /N 2 Selectivity Debasis Banerjee, a, * Zhijuan Zhang, b Anna M. Plonka, c Jing Li, b, * and John B. Parise a, c, d, * (a) Department
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Unusual pore structure and sorption behaviour in a hexanodal zinc-organic framework material Jinjie Qian a,b Feilong Jiang, a Linjie Zhang, a,b Kongzhao Su, a,b Jie Pan, a,b Qipeng
More informationFunctionalized flexible MOF as filler in mixed matrix membranes for highly selective separation of CO 2 from CH 4 at elevated pressures
-Supplementary info file- Functionalized flexible MOF as filler in mixed matrix membranes for highly selective separation of CO 2 from CH 4 at elevated pressures Beatriz Zornoza a, Alberto Martinez-Joaristi
More informationElectronic Supplementary Information
Electronic Supplementary Information The directing effect of linking unit on building microporous architecture in tetraphenyladmantane-based poly(schiffbase) networks Guiyang Li, Biao Zhang, Jun Yan and
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Salen(Co(III)) imprisoned within pores of metal-organic framework
More informationFacile Synthesis and Catalytic Properties of CeO 2 with Tunable Morphologies from Thermal Transformation of Cerium Benzendicarboxylate Complexes
Electronic Supplementary Information Facile Synthesis and Catalytic Properties of CeO 2 with Tunable Morphologies from Thermal Transformation of Cerium Benzendicarboxylate Complexes Yuhua Zheng, Kai Liu,
More informationA triazine-based covalent organic polymer for efficient CO 2 adsorption
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Supporting Information A triazine-based covalent organic polymer for efficient CO
More informationShape Assisted Fabrication of Fluorescent Cages of Squarate based Metal-Organic Coordination Frameworks
Supporting Information Shape Assisted Fabrication of Fluorescent Cages of Squarate based Metal-Organic Coordination Frameworks Kolleboyina Jayaramulu, a Katla Sai Krishna, a Subi J. George, b Muthuswamy
More informationDry-gel conversion synthesis of Cr-MIL-101 aided by grinding: High surface area high yield synthesis with minimum purification
Electronic Supporting Informations (ESI): Dry-gel conversion synthesis of Cr-MIL-101 aided by grinding: High surface area high yield synthesis with minimum purification Jun Kim, Yu-Ri Lee and Wha-Seung
More informationA Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties
Supporting information for A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties Suresh Sanda, Srinivasulu Parshamoni and SanjitKonar* Department of
More informationElectronic Supporting Information (ESI)
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Journal of Materials Chemistry A Electronic Supporting Information (ESI)
More informationSupporting Information
Supporting Information An In Situ One-Pot Synthetic Approach towards Multivariate Zirconium MOFs Yujia Sun, Lixian Sun, Dawei Feng,* and Hong-Cai Zhou* anie_201602274_sm_miscellaneous_information.pdf Contents
More informationSupplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient
Supplementary Material (ESI) for CrystEngComm An ideal metal-organic rhombic dodecahedron for highly efficient adsorption of dyes in an aqueous solution Yuan-Chun He, Jin Yang,* Wei-Qiu Kan, and Jian-Fang
More informationCooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks
Supporting Information Cooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks Lin-Bing Sun, Jian-Rong Li, Jinhee Park, and Hong-Cai Zhou* Department of Chemistry, Texas A&M University,
More informationSupporting Information
Supporting Information Highly selective carbon dioxide adsorption in a water-stable Indium-organic framework material Jin-Jie Qian, a,bi Fei-Long Jiang, a Da-Qiang Yuan, a Ming-Yan Wu, a Shu-Quan Zhang,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supporting Information Polystyrene Sulfonate Threaded in MIL-101Cr(III) as Stable and
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Reticular Chemistry at its Best: Directed Assembly of Hexagonal Building Units into the Awaited MOF with the Intricate Polybenzene Topology, pbz-mof Dalal Alezi, Ioannis Spanopoulos,
More informationHigh-Connected Mesoporous Metal Organic Framework
Supporting Information High-Connected Mesoporous Metal Organic Framework Xiaojun Gu, a Zhang-Hui Lu a,b and Qiang Xu* a,b a National Institute of Advanced Industrial Science and Technology (AIST), Ikeda,
More informationElectronic Supporting Information for
Electronic Supporting Information for Microporous metal-organic open framework containing uncoordinated carbonyl groups as postsynthetic modification sites for cation exchange and Tb 3+ sensor Jianwei
More informationRare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Rare double spin canting antiferromagnetic behaviours in a [Co 24 ] cluster Guang-Ming Liang, Qing-Ling
More informationSupporting Information
Supporting Information Exploring the detection of metal ions by tailoring the coordination mode of V-shaped thienylpyridyl ligand in three MOFs Li-Juan Han,, Wei Yan, Shu-Guang Chen, Zhen-Zhen Shi, and
More informationRobust high-connected rare-earth MOFs as efficient heterogeneous catalysts for CO 2 conversion
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Electronic supplementary information Robust high-connected rare-earth MOFs as efficient heterogeneous
More informationElectronic Supplementary Information
Electronic Supplementary Information Designed Copper-amine Complex as an Efficient Template for One-pot Synthesis of Cu-SSZ-13 Zeolite with Excellent Activity for Selective Catalytic Reduction of NOx by
More informationSupplementary Data. Size-controlled synthesis of MIL-101(Cr) nanoparticles with. enhanced selectivity for CO 2 over N 2
Supplementary Data Size-controlled synthesis of MIL-11(Cr) nanoparticles with enhanced selectivity for CO 2 over N 2 Dongmei Jiang, Andrew D. Burrows* and Karen J. Edler Department of Chemistry, University
More informationMOF-76: From Luminescent Probe to Highly Efficient U VI Sorption Material
MOF-76: From Luminescent Probe to Highly Efficient U VI Sorption Material Weiting Yang, a Zhi-Qiang Bai, b Wei-Qun Shi*, b Li-Yong Yuan, b Tao Tian, a Zhi-Fang Chai*, c Hao Wang, a and Zhong-Ming Sun*
More information1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification.
1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification. 2. Experimental procedures Benzo[1,2-c:3,4-c':5,6-c'']trifuran, 1: The synthesis
More informationElectronic Supplementary Information. Selective Sorption of Light Hydrocarbons on a Family of
Electronic Supplementary Information Selective Sorption of Light Hydrocarbons on a Family of Metal-Organic Frameworks with different Imidazolate Pillars Hong-Ru Fu and Jian Zhang* State Key Laboratory
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Rational Design and Synthesis of a Porous, Task-Specific
More information3D Porous Crystalline Polyimide Covalent Organic Frameworks for Drug Delivery
[Supporting Information] 3D Porous Crystalline Polyimide Covalent Organic Frameworks for Drug Delivery Qianrong Fang,, Junhua Wang, Shuang Gu, Robert B. Kaspar, Zhongbin Zhuang, Jie Zheng, Hongxia Guo,,
More informationSupplementary Information. ZIF-8 Immobilized Ni(0) Nanoparticles: Highly Effective Catalysts for Hydrogen Generation from Hydrolysis of Ammonia Borane
Supplementary Information ZIF-8 Immobilized Ni() Nanoparticles: Highly Effective Catalysts for Hydrogen Generation from Hydrolysis of Ammonia Borane Pei-Zhou Li, a,b Kengo Aranishi, a and Qiang Xu* a,b
More informationImmobilization of BiOX (X=Cl, Br) on activated carbon fibers as
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Immobilization of BiOX (X=Cl, Br) on activated carbon fibers as recycled photocatalysts
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary material (ESI) for Nanoscale Electronic Supplementary Information (ESI) Synthesis of Nanostructured Materials by Using Metal-Cyanide Coordination Polymers and Their Lithium Storage
More informationSupplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Mechanochemical and Solvent-free Assembly of Zirconium-Based Metal-organic Frameworks Supplementary
More informationSupporting Information
Supporting Information Unprecedented solvent-dependent sensitivities in highly efficient detection of metal ions and nitroaromatic compounds by a fluorescent Ba MOF Rongming Wang, Xiaobin Liu, Ao Huang,
More informationSupporting Information
Supporting Information Hydrogen Storage in the Dehydrated Prussian Blue Analogues M 3 [Co(CN) 6 ] 2 (M = Mn, Fe, Co, Ni, Cu, Zn) Steven S. Kaye and Jeffrey R. Long* Dept. of Chemistry, University of California,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Micro-crystals of metal-organic frameworks constructed
More informationSupporting Information
Supporting Information Selective Propene Oligomerization with Nickel(II)-Based Metal-Organic Frameworks Anton N. Mlinar, a,+ Benjamin K. Keitz, b,+ David Gygi, b Eric D. Bloch, b Jeffrey R. Long,*,b Alexis
More informationFabrication of COF-MOF Composite Membranes and Their Highly. Selective Separation of H 2 /CO 2
[Supporting Information] Fabrication of COF-MOF Composite Membranes and Their Highly Selective Separation of H 2 /CO 2 Jingru Fu, a Saikat Das, a Guolong Xing, a Teng Ben, a * Valentin Valtchev a,b and
More informationElectronic Supporting Information (ESI) Porous Carbon Materials with Controllable Surface Area Synthsized from Metal-Organic Frameworks
Electronic Supporting Information (ESI) Porous Carbon Materials with Controllable Surface Area Synthsized from Metal-Organic Frameworks Seunghoon Lim, Kyungwon Suh, Yelin Kim, Minyoung Yoon, Hyeran Park,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Cation exchange MOF-derived nitrogen-doped
More informationElectronic Supplementary Information. Pore with Gate: Modulating Hydrogen Storage in Metal Organic. Framework Materials via Cation Exchange
Electronic Supplementary Information Pore with Gate: Modulating Hydrogen Storage in Metal Organic Framework Materials via Cation Exchange Sihai Yang, 1 Samantha K. Callear, 2 Timmy A. J. Ramirez-Cuesta,
More informationSelective aerobic oxidation of biomass-derived HMF to 2,5- diformylfuran using a MOF-derived magnetic hollow Fe-Co
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2016 Selective aerobic oxidation of biomass-derived HMF to 2,5- diformylfuran using a MOF-derived
More informationGrowth inhibition of Microcystic aeruginosa by Metal-organic frameworks: effect of variety, metal ion and organic ligand
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2018 Supporting Information for Growth inhibition of Microcystic aeruginosa by Metal-organic frameworks:
More informationSupporting Information
Supporting Information A 3D Microporous Covalent Organic Framework with exceedingly high C 3 H 8 /CH 4 and C 2 Hydrocarbons/CH 4 Selectivity Heping Ma, a Hao Ren,* a Shuang Meng, a Zhuojun Yan, a Huanyu
More informationPermanently Porous Single Molecule H-Bonded Organic Framework for Selective CO 2 Capture
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supporting information for Permanently Porous Single Molecule H-Bonded Organic Framework for Selective
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Information (ESI) Metal-Organic Framework MIL-100(Fe) for the Adsorption of Malachite Green from Aqueous Solution Shu-Hui Huo, and Xiu-Ping Yan* State Key Laboratory of Medicinal
More informationSupporting Information
Supporting Information For the manuscript Catalyst-free Preparation of Melamine-based Microporous Polymer Networks through Schiff Base Chemistry by Matthias Georg Schwab, + Birgit Faßbender, + Hans Wolfgang
More informationSupporting Information. Graphene Oxide-Palladium Modified Ag-AgBr: A Novel Visible-Light- Responsive Photocatalyst for the Suzuki Coupling Reaction**
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Graphene Oxide-Palladium Modified Ag-AgBr: A Novel Visible-Light- Responsive
More informationGrowth of 2D sheets of a MOF on graphene surfaces to yield composites with novel gas adsorption characteristics
Electronic Supporting Information (ESI) Growth of 2D sheets of a MOF on graphene surfaces to yield composites with novel gas adsorption characteristics Ram Kumar, Kolleboyina Jayaramulu, Tapas Kumar Maji*
More informationExtraction of Rare Earth Elements using Composites
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supplementary Information Extraction of Rare Earth Elements using Magnetite@MOF
More informationAn Anionic Metal Organic Framework For Adsorption and. Separation of Light Hydrocarbons
Supporting Information for An Anionic Metal Organic Framework For Adsorption and Separation of Light Hydrocarbons Jia Li, Hong-Ru Fu, Jian Zhang, Lan-Sun Zheng, and Jun Tao* State Key Laboratory of Physical
More informationSupporting Information
Electronic Supplementary Material (ESI) for Catalysis Science & Technology. This journal is The Royal Society of Chemistry 206 Supporting Information N-heterocyclic carbene based MOFs catalyst for Sonogashira
More informationEthers in a Porous Metal-Organic Framework
Supporting Information Enhanced Isosteric Heat of H 2 Adsorption by Inclusion of Crown Ethers in a Porous Metal-Organic Framework Hye Jeong Park and Myunghyun Paik Suh* Department of Chemistry, Seoul National
More informationConstruction of Superior Visible-Light-Driven Photocatalyst. Platform-Electron Withdrawing Unit Triadic Structure. Covalent Organic Framework
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2017 Construction of Superior Visible-Light-Driven Photocatalyst Based on C 3 N 4 Active
More informationPolydopamine as a promoter layer of MOF deposition on inert polymer surfaces to fabricate hierarchically structured porous films
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Polydopamine as a promoter layer of MOF deposition on inert polymer surfaces to fabricate hierarchically
More informationAlternative Synthetic Methodology for Amide Formation in the Post-Synthetic Modification of Ti-MIL125-NH 2
Supplementary Information Alternative Synthetic Methodology for Amide Formation in the Post-Synthetic Modification of Ti-MIL125-H 2 Adam P. Smalley, a David G. Reid, a Jin Chong Tan, b and Gareth. Lloyd*
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 ucleophilic addition of amines, alcohols, and thiophenol with epoxide/olefin using highly efficient
More informationSupplementary Information
Supplementary Information Fabrication of Novel Rattle-Type Magnetic Mesoporous carbon Microspheres for Removal of Microcystins Xinghua Zhang and Long Jiang* Beijing National Laboratory for Molecular Science
More informationStabilization of a Reactive Polynuclear Silver Carbide Cluster through the Encapsulation within Supramolecular Cage
Supporting Information Stabilization of a Reactive Polynuclear Silver Carbide Cluster through the Encapsulation within Supramolecular Cage Cai-Yan Gao, Liang Zhao,* and Mei-Xiang Wang* The Key Laboratory
More informationLigand-free coupling of phenols and alcohols with aryl halides by a recyclable heterogeneous copper catalyst
Supporting Information Ligand-free coupling of phenols and alcohols with aryl halides by a recyclable heterogeneous copper catalyst Man Wang, Bizhen Yuan, Tongmei Ma, Huanfeng Jiang and Yingwei Li* School
More informationSupporting Information:
Supporting Information: In Situ Synthesis of Magnetically Recyclable Graphene Supported Pd@Co Core-Shell Nanoparticles as Efficient Catalysts for Hydrolytic Dehydrogenation of Ammonia Borane Jun Wang,
More informationElectronic Supplementary Information. Noninvasive Functionalization of Polymers of Intrinsic Microporosity for Enhanced CO 2 Capture
Electronic Supplementary Information Noninvasive Functionalization of Polymers of Intrinsic Microporosity for Enhanced CO 2 Capture Hasmukh A. Patel and Cafer T. Yavuz* Oxide and Organic Nanomaterials
More informationSupporting Information
Supporting Information Photocatalytic Suzuki Coupling Reaction using Conjugated Microporous Polymer with Immobilized Palladium Nanoparticles under Visible Light Zi Jun Wang, Saman Ghasimi, Katharina Landfester
More informationSynthesis of Secondary and Tertiary Amine- Containing MOFs: C-N Bond Cleavage during MOF Synthesis
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Synthesis of Secondary and Tertiary Amine- Containing MFs: C-N Bond
More informationQingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Science,
Supporting information A rht type Metal-Organic Framework based on Small Cubicuboctahedron Supermolecular Building Blocks and Adsorption Properties Liangjun Li a,b, Sifu Tang a, Xiaoxia Lv a,b, Min Jiang
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 15 Supporting Information Co-MOF as sacrificial template: Manifesting new Co
More informationSupplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supplementary Information A Novel Single-Side Azobenzene-Grafted Anderson-Type Polyoxometalate
More information