ELECTRONIC SUPPLEMENTARY INFORMATION. Highly Porous and Robust Scandium-based Metal-Organic. Frameworks for Hydrogen Storage
|
|
- Peter Beasley
- 5 years ago
- Views:
Transcription
1 ELECTRONIC SUPPLEMENTARY INFORMATION Highly Porous nd Roust Scndium-sed Metl-Orgnic Frmeworks for Hydrogen Storge Ilich A. Irr, Sihi Yng, Xing Lin, Alexnder J. Blke, Pierre J. Rizkllh, Hrriott Nowell, c Dvid R. Alln, c Neil R. Chmpness, * Peter Huerstey nd Mrtin Schröder *. School of Chemistry, University of Nottinghm, Nottinghm NG7 2RD, UK. Fx: ; Tel: Emil: Neil.Chmpness@nottinghm.c.uk; M.Schroder@nottinghm.c.uk. STFC Dresury Lortory, Dresury Science nd Innovtion Cmpus, Wrrington, Cheshire, WA4 4AD, UK c. Dimond Light Source, Hrwell Science nd Innovtion Cmpus, Didcot, Oxfordshire, OX11 0DE, UK 1
2 1. Experimentl Section 1.1 Mterils nd Mesurements All regents nd solvents were used s received from commercil suppliers without further purifiction. Elementl micronlyses for C, H nd N were crried out on CE-440 elementl nlyser t the University of Nottinghm. Powder X-ry diffrction (PXRD) dt were collected under oth mient nd in-situ conditions on Bruker AXS D8 Advnce diffrctometer operted t 40 kv nd 40 ma (Cu Kα 1, λ= Å), with heting rte of 2 C/min nd step size of 0.04 /2θ. An MRI TCP-20 with PtRh strip heter ws used for the in-situ vrile temperture PXRD experiments. Thermogrvimetric nlysis (TGA) ws performed under N 2 t scn rte of 2 C/min using TA Universl Anlysis 2000 system. 1.2 Synthesis of {[Sc 2 (BPTC)(OH) 2 ] (H 2 O) 1.25 } NOTT-400 Scndium triflte (0.030g, mmol) nd H 4 BPTC (0.010 g, mmol) were mixed in THF (4.0 ml), DMF (3.0 ml), wter (1.0 ml) nd HCl (36.5 %, 2 drops). The resultnt slurry mixture ws stirred until complete dissolution occurred. The solution ws then plced in pressure tue nd heted in n oil th to 75 o C for 72 h. The tue ws cooled down to room temperture t rte of 0.1 o C/min, nd the colourless crystlline product ws seprted y filtrtion, wshed with DMF (5.00 ml) nd dried in ir. Yield: 67.6 % (sed on lignd). Elementl nlysis corresponds to Sc 2 C 16 H 10.5 O %: Cl: C, 40.66; H: 2.24; found: C, 40.67; H, Synthesis of {[Sc(TDA)(OH)] (H 2 O) 2.6 } NOTT-401 Scndium triflte (0.057 g, mmol) nd thiophene-2,6-dicroxylic cid, H 2 TDA, (0.01 g, mmol) were dispersed in THF (4.0 ml), DMF (3.0 ml), H 2 O (1.0 ml) nd HCl (36.5 %, 2 drops) nd seled in pressure tue. The cler solution ws heted t 90 o C in n oil th for 72 h. The tue ws cooled to room temperture over period of 12 h nd the colourless crystlline product seprted y filtrtion, wshed with DMF (5.00 ml) nd dried in ir. Yield: 71.1 % (sed on lignd). Elementl nlysis dt corresponds to ScO 7.6 C 6 H 8.2 S%: Cl: C, 25.84; H, 2.75; found: C, 25.82; H,
3 1.4 X-Ry Crystllogrphy Single crystl diffrction dt for NOTT-400 were collected on Sttion 9.8 of the Synchrotron Rdition Source t STFC Dresury Lortory. Diffrction dt for NOTT-401 were collected on Bemline I19 t the Dimond Light Source. The detils for dt collection re included in CIF files in the Supplementry Informtion. Structures were solved y direct methods nd developed y difference Fourier techniques using the SHELXTL softwre pckge. 1 The hydrogen toms on the lignd were plced geometriclly nd refined using riding model. The unit cell volumes include lrge region of disordered solvent which could not e modelled s discrete tomic sites. We employed PLATON/SQUEEZE 2 to clculte the contriution to the diffrction from the solvent region nd therey produced set of solvent-free diffrction intensities. The finl formule were clculted from the SQUEEZE 2 results comined with elementl nlyticl dt. Figure S1: () The inucler uilding lock comprising two Sc(III) centres ech with pproximtely octhedrl geometry; () polyhedrl representtion of the two Sc(III) octhedr shring μ 2 -hydroxo group; (c) the inucler uilding lock of NOTT-400 showing the lignd [BPTC] 4- coordinted to Sc(III) centres nd (d) the uilding lock of NOTT-401 showing the lignd [TDA] 2- coordinted to Sc(III) centres (Sc lue, S yellow, O red, C lck, H smll grey spheres). 3
4 1.5 Nitrogen nd hydrogen dsorption isotherms. N 2 nd H 2 isotherms were recorded on n IGA system (Hidden Isochem, Wrrington, UK) t the University of Nottinghm under ultr high vcuum in clen system with diphrgm nd turo pumping system. Ultr-pure grde ( %) H 2 ws purchsed from BOC nd purified further using clcium luminosilicte nd ctivted cron dsorents to remove trce mounts of wter nd other impurities efore introducing into the IGA system. The density of H 2 t 77 K in the uoyncy correction ws clculted y the Redlich-Kwong-Sove eqution of stte of H 2 incorported in the IGASWIN softwre of the IGA system. The surfce re ws clculted using the BET method sed on dsorption dt in the prtil pressure (P/Po) rnge 0.06 to The pore size distriution (PSD) ws determined y pplying the Duinin-Astkhov nlysis to the N 2 dsorption dt nlysis to the isotherm dt. 2. TGA plots Figure 2S: TGA nlysis of compounds NOTT-400 nd NOTT
5 3. PXRD Ptterns Figure 3S: Experimentl PXRD dt nd simulted pttern derived from the single crystl structures of () NOTT-400 nd () NOTT-401. Figure 4S: In situ PXRD ptterns for () NOTT-400 nd () NOTT-401. Smples held for 5 mins t ech temperture 5
6 4. Nitrogen dsorption isotherms Figure 5S: N 2 sorption isotherms for () desolvted NOTT-400 nd () desolvted NOTT-401 t 77 K. 5. Pore Size Distriution Anlysis Figure 6S: Pore size distriution for () desolvted NOTT-400 nd () desolvted NOTT-401 (). 6
7 6. Derivtion of the isosteric hets of H 2 dsorption. Grvimetric H 2 dsorption ws mesured from 0-20 r t 77K nd 87K for desolvted NOTT-400 nd NOTT-401. All dt were strictly corrected for the uoyncy of system, smples nd sortes. All the H 2 sorption isotherms show good reversiility nd sence of hysteresis (Figures 7S). The H 2 dsorption kinetic dt confirm tht equilirium is chieved within c. 3 mins of the isotherm pressure step. These suggest typicl H 2 dsorption nd exclude ny significnt effect due to the presence of impurities. Figure 7S: H 2 isotherms for () desolvted NOTT-400 nd () desolvted NOTT-401t 77 nd 87 K. The isosteric hets of H 2 dsorption were determined y fitting viril-type eqution to oth 77 nd 87 K dsorption isotherms. The ln(n/p) vlues for given mount dsored (n) were clculted from the liner regressions from the viril eqution nlysis using the following viril eqution: 3, 4 ln(n/p) = A 0 + A 1 n + A 2 n 2 (1) where p is pressure, n is mount dsored nd A 0, A 1 etc. re viril coefficients. A 0 is relted to dsortedsorent interctions, while A 1 descries dsorte-dsorte interctions. 4 Henry s Lw constnt (K H ) is equl to exp(a 0 ), nd t low surfce coverge, A 2 nd higher terms cn e ignored. A plot of ln(n/p) versus n should give stright line t low surfce coverge. Simultion of H 2 dsorption dt t 77 nd 87 K for NOTT-400 nd NOTT-401 etween 50 nd 400 mr using eqution (1) re presented in Figures 8S nd 9S, respectively. All the regression coefficients 7
8 were lrger thn 0.998, showing tht the model fits the dt very well. The viril method sed on eqution (1) is preferred t low pressure ecuse the linerity in the low pressure prt of the isotherm provides direct confirmtion of the ccurcy of the interpoltions. The isosteric hets of dsorption for H 2 on desolvted NOTT-400 nd NOTT-401 were clculted s function of surfce coverge. The estimted error in the mesured isosteric enthlpies is 0.1 kj/mol. Figure 8S: Viril fitting plot for the dsorption of H 2 on NOTT-400 t 77 K () nd 87 K (). Figure 9S: Viril fitting plot for the dsorption of H 2 on NOTT-400 t 77 K () nd 87 K (). 8
9 Adsorption enthlpy kj/mol Electronic Supplementry Mteril (ESI) for Chemicl Communictions NOTT-400 NOTT H 2 uptke (mol/g) Figure 10S: Vrition of dsorption enthlpy t low loding for NOTT-400 nd NOTT-401. References: 1. G. M. Sheldrick, Act Crystllogr. Sect. A, 2008, 64, A. L. Spek, J. Appl. Crystllogr., 2003, 36, 7; P.v.d. Sluis nd A. L. Spek, Act Crystllogr., Sect. A, 1990, 46, X. Zho, S. Villr-Rodil, A. J. Fletcher nd K. M. Thoms, J. Phys. Chem. B, 2006, 110, 9947; X. Zho, B. Xio, A. J. Fletcher nd K. M. Thoms, J. Phys. Chem. B, 2005, 109, 8880; I. P. Okoye, M. Benhm nd K. M. Thoms, Lngmuir, 1997, 13, 4054; C. R. Reid, I. P. OKoye nd K. M. Thoms, Lngmuir, 1998, 14, 2415; C. R. Reid nd K. M. Thoms, Lngmuir, 1999, 15, 3206; C. R. Reid nd K. M. Thoms, J. Phys. Chem. B, 2001, 105, J. H. Cole, D. H. Everett, C. T. Mrshll, A. R. Pniego, J. C. Powl nd Rodrigue.F, J. Chem. Soc., Frdy Trns. I, 1974, 70,
Construction of right-handed-, left-handed- and racemic helical. coordination polymers. Enantioselective recognition via chiral.
Construction of right-hnded-, left-hnded- nd rcemic helicl coordintion polymers. Enntioselective recognition vi chirl helicl crystls Kyung Hwn Prk, Te Hwn Noh, Yoon-Bo
More informationElectronic Supplementary Information. Materials
Electronic Supplementary Information S1 Enhancement of H 2 Adsorption in Li + -Exchanged Co-ordination Framework Materials Sihai Yang, 1 Xiang Lin, 1 Alexander J. Blake, 1 K. Mark Thomas, 2 Peter Hubberstey,
More informationSupporting Information
Supporting Informtion Ultrfst nd Stble CO Cpture Using Alkli Metl Slt-Promoted MgO-CCO 3 Sorbents Hongjie Cui, Qiming Zhng, Yunwu Hu, Chong Peng, Xingchen Fng, Zhenmin Cheng, Vldimir V. Glvit nd Zhiming
More informationElectronic Supplementary Information
Electronic Supplementry Informtion Assemling cron-coted hollow α-fe 2 nnohorns on the CNT ckone for superior lithium storge cpility Corresponding uthor: Xiong Wen (Dvid) Lou* School of Chemicl nd Biomedicl
More informationElectronic Supplementary Information. Pore with Gate: Modulating Hydrogen Storage in Metal Organic. Framework Materials via Cation Exchange
Electronic Supplementary Information Pore with Gate: Modulating Hydrogen Storage in Metal Organic Framework Materials via Cation Exchange Sihai Yang, 1 Samantha K. Callear, 2 Timmy A. J. Ramirez-Cuesta,
More informationEnhanced Photocatalytic CO 2 -Reduction Activity of Anatase TiO 2 by Coexposed {001} and {101} Facets
Supplementry Informtion for the Journl of Americn Chemicl Society The Americn Chemicl Society 04 Enhnced Photoctlytic CO -Reduction Activity of Antse TiO y Coexposed {00} nd {0} Fcets Jiguo Yu,*, Jingxing
More informationSupplementary Information
Supplementry Informtion Lignd exchnge triggered controlled-relese trgeted drug delivery system sed on core shell superprmgnetic mesoporous microspheres cpped with nnoprticles Zhogng Teng, Xingng Zhu, Gengfeng
More informationThe development of nanoscale morphology in polymer:fullerene. photovoltaic blends during solvent casting
Supplementry informtion Supplementry Mteril (ES) for Soft Mtter The development of nnoscle morphology in polymer:fullerene photovoltic lends during solvent csting To Wng, * Aln D. F. Dunr, Pul A. Stniec,
More informationSupporting Information
Electronic Supplementry Mteril (ESI) for Nnoscle. This journl is The Royl Society of Chemistry Supporting Informtion A Dul-Emitting d-f Nnocrystlline Metl-Orgnic Frmework s Self- Clirting Luminescent Sensor
More informationSurfactant-directed assembly of mesoporous metal-organic framework nanoplates in ionic liquid
Electronic supplementry informtion for: Surfctnt-directed ssemly of mesoporous metl-orgnic frmework nnopltes in ionic liquid Li Peng, Jinling Zhng*, Jinshen Li, Buxing Hn*, Zhimin Xue nd Gunying Yng Beijing
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) Enhancing stability and porosity of penetrated
More informationSupplementary Information
Supplementry Informtion Spontneously mplified homochirl orgnic-inorgnic nno-helix complex vi self-prolifertion Hlei Zhi, Yn Qun, Li Li, Xing-Yng Liu, Xurong Xu c nd Ruikng Tng*,c Centre for Biomterils
More informationNitrogen-doped nanoporous carbon nanosheets derived from plant biomass: An. efficient catalyst for oxygen reduction reaction
Electronic Supplementry Mteril (ESI) for Energy & Environmentl Science. This journl is The Royl Society of Chemistry 214 Electronic Supplementry Informtion: Nitrogen-doped nnoporous cron nnosheets derived
More informationElectronic Supplementary Information (ESI) Framework
Electronic Supplementary Information (ESI) Exceptionally High H 2 Storage by a Metal Organic Polyhedral Framework Yong Yan, Xiang Lin, Sihai Yang, Alexander J. Blake, Anne Dailly, Neil R. Champness, Peter
More informationSupporting information for
Supporting informtion for Competitive co-dsorption of with H O, NH 3, SO, NO, NO, N, O, nd CH in M-MOF-7 (M= Mg, Co, Ni): the role of hydrogen onding Kui Tn, Sestin Zulug, Qihn Gong, Yuzhi Go, Nour Nijem,
More informationSupplementary Figures.
Supplementry Figures. c c Supplementry Figure 1 13 C NMR spectrum of representtive smple of PCPC in CDCl 3. The polymer ws purified y using DMS/MeH. CH 2 Cl 2 H 2 DMS Supplementry Figure 2 1 H NMR spectrum
More informationdy ky, dt where proportionality constant k may be positive or negative
Section 1.2 Autonomous DEs of the form 0 The DE y is mthemticl model for wide vriety of pplictions. Some of the pplictions re descried y sying the rte of chnge of y(t) is proportionl to the mount present.
More informationDeriving hydraulic conductivity function from soil column tests
Deriving hydrulic conductivity function from soil column tests Yvonne Lins, Mri Dtchev & Tom Schnz DFG Fo 444 - TP 4 Experimentelle und theoretische Untersuchungen teilgesättigter Reibungsmterilien Content
More informationSUPPLEMENTARY INFORMATION
SUPPLEMENTARY INFORMATION Synthesis of metl oxide with roomtemperture photoreversile phse trnsition Shin-ichi Ohkoshi 1 *, Yoshihide Tsunouchi, 1 Tomoyuki Mtsud, 1 Kzuhito Hshimoto, 2 Asuk Nmi, 1 Fumiyoshi
More informationCHAPTER 20: Second Law of Thermodynamics
CHAER 0: Second Lw of hermodynmics Responses to Questions 3. kg of liquid iron will hve greter entropy, since it is less ordered thn solid iron nd its molecules hve more therml motion. In ddition, het
More informationMorphology characterization. (a), SEM image of PS template nanospheres showing
b Supplementry Figure 1 Morphology chrcteriztion. (), SEM imge of PS templte nnospheres showing mono-dispersed sphericl shpe with pproximtely 200 nm in dimeter. The scle br is 500 nm. (b), SEM imge of
More informationElectronic Supplementary Information
Electronic Supplementry Mteril (ESI) for ChemComm. This journl is The Royl Society of Chemistry 218 Electronic Supplementry Informtion Nitrogen-free commercil cron cloth with rich defects for electroctlytic
More informationColorimetric detection and separation of chiral tyrosine. based on N-acetyl-L-cysteine modified gold. nanoparticles
Colorimetric detection nd seprtion of chirl tyrosine sed on N-cetyl-L-cysteine modified gold nnoprticles Hiyn Su, Qiuling Zheng nd Hiing Li* Key Lortory of Pesticide nd Chemicl Biology (CCNU), Ministry
More informationSupplementary Figure 1 Supplementary Figure 2
Supplementry Figure 1 Comprtive illustrtion of the steps required to decorte n oxide support AO with ctlyst prticles M through chemicl infiltrtion or in situ redox exsolution. () chemicl infiltrtion usully
More informationSupporting information
Electronic Supplementry Mteril (ESI) for Ctlysis Science & Technology. This journl is The Royl Society of Chemistry 2017 Supporting informtion PdAu imetllic nnoprticles nchored on mine-modified mesoporous
More informationModulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework
Received 19 Jul 2016 Accepted 5 Dec 2016 Pulished 13 Fe 2017 DI: 10.1038/ncomms14212 PEN Modulting suprmoleculr inding of cron dioxide in redox-ctive porous metl-orgnic frmework Zhenzhong Lu 1, Hrry G.W.
More informationLECTURE 14. Dr. Teresa D. Golden University of North Texas Department of Chemistry
LECTURE 14 Dr. Teres D. Golden University of North Texs Deprtment of Chemistry Quntittive Methods A. Quntittive Phse Anlysis Qulittive D phses by comprison with stndrd ptterns. Estimte of proportions of
More informationCalix-Tris-Tröger s Bases A New Cavitand Family
Supplementry Mteril (ESI) for Chemicl Communictions This journl is (c) The Royl Society of Chemistry 200 Clix-Tris-Tröger s Bses A ew Cvitnd Fmily Mrtin Vlík, Jn Čejk, Mrtin vlík, Vldimír Král, Bohumil
More informationSupporting Information
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Single-Crystal-to-Single-Crystal Transformation of an Anion Exchangeable
More informationPsychrometric Applications
Psychrometric Applictions The reminder of this presenttion centers on systems involving moist ir. A condensed wter phse my lso be present in such systems. The term moist irrefers to mixture of dry ir nd
More informationEnergy (kcal mol -1 ) Force (kcal mol -1 Å -1 ) Pore axis (Å) Mixed Mo-only S-only Graphene
Force (kcl mol -1 Å -1 ) Energy (kcl mol -1 ) 3 1-1 - -3 Mixed Mo-only S-only Grphene 6 5 3 1 Mixed Mo-only S-only Grphene - -1-1 1 Pore xis (Å) -1 1 Pore xis (Å) Supplementry Figure 1 Energy Brriers.
More informationThe International Association for the Properties of Water and Steam. Release on the Ionization Constant of H 2 O
IAPWS R-7 The Interntionl Assocition for the Properties of Wter nd Stem Lucerne, Sitzerlnd August 7 Relese on the Ioniztion Constnt of H O 7 The Interntionl Assocition for the Properties of Wter nd Stem
More informationDirect indirect character of the band gap in methylammonium lead iodide perovskite
Direct indirect chrcter of the nd gp in methylmmonium led iodide perovskite Eline M. Hutter 1, Mrí C. Gélvez-Rued 1, Ann Osherov 2, Vldimir Bulović 2, Ferdinnd C. Grozem 1, Smuel D. Strnks 2,3*, nd Tom
More informationDesigning Information Devices and Systems I Fall 2016 Babak Ayazifar, Vladimir Stojanovic Homework 6. This homework is due October 11, 2016, at Noon.
EECS 16A Designing Informtion Devices nd Systems I Fll 2016 Bk Ayzifr, Vldimir Stojnovic Homework 6 This homework is due Octoer 11, 2016, t Noon. 1. Homework process nd study group Who else did you work
More informationa * a (2,1) 1,1 0,1 1,1 2,1 hkl 1,0 1,0 2,0 O 2,1 0,1 1,1 0,2 1,2 2,2
18 34.3 The Reciprocl Lttice The inverse of the intersections of plne with the unit cell xes is used to find the Miller indices of the plne. The inverse of the d-spcing etween plnes ppers in expressions
More informationPHY 140A: Solid State Physics. Solution to Midterm #1
PHY 140A: Solid Stte Physics Solution to Midterm #1 TA: Xun Ji 1 October 24, 2006 1 Emil: jixun@physics.ucl.edu Problem #1 (20pt)Clculte the pcking frction of the body-centered cubic lttice. Solution:
More informationSupplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient
Supplementary Material (ESI) for CrystEngComm An ideal metal-organic rhombic dodecahedron for highly efficient adsorption of dyes in an aqueous solution Yuan-Chun He, Jin Yang,* Wei-Qiu Kan, and Jian-Fang
More informationModelling of chemical vapour deposition of carbon based on detailed surface chemistry
Modelling of chemicl vpour deposition of cron sed on detiled surfce chemistry Aijun Li *, Koyo Noring, Günter Schoch, Sven Lichtenerg, Olf Deutschmnn Institut für Technische Chemie und Polymerchemie, Universität
More informationDesigning Information Devices and Systems I Anant Sahai, Ali Niknejad. This homework is due October 19, 2015, at Noon.
EECS 16A Designing Informtion Devices nd Systems I Fll 2015 Annt Shi, Ali Niknejd Homework 7 This homework is due Octoer 19, 2015, t Noon. 1. Circuits with cpcitors nd resistors () Find the voltges cross
More informationDesigning Information Devices and Systems I Spring 2018 Homework 7
EECS 16A Designing Informtion Devices nd Systems I Spring 2018 omework 7 This homework is due Mrch 12, 2018, t 23:59. Self-grdes re due Mrch 15, 2018, t 23:59. Sumission Formt Your homework sumission should
More informationElectronic supporting information
Electronic supporting informtion Post-polymeriztion functionliztion of liner polyglycidol with diethyl vinylphosphonte Jens Köhler, Helmut Keul* nd Mrtin Möller* Institute of Technicl nd Mcromoleculr Chemistry,
More informationSupplementary Information
Site-Selective Cyclometalation of a Metal-Organic Framework Phuong V. Dau, Min Kim, and Seth M. Cohen* Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive,
More informationSupporting Information. Electrochemical Valorization of Furfural to Maleic Acid
Supporting Informtion Electrochemicl Vloriztion of to Mleic Acid Stephen R. Kuot nd Kyoung-Shin Choi * Deprtment of Chemistry, University of Wisconsin Mdison, Mdison, WI 53706, USA. *Correspondence to:
More informationSelective Hydrogenation of Cinnamaldehyde over Co-based. Intermetallic Compounds Derived from Layered Double Hydroxides
Supporting Informtion Selective Hydrogention of Cinnmldehyde over Co-bsed Intermetllic Compounds Derived from Lyered Double Hydroxides Yusen Yng, 1 Deming Ro, 1,2 Yudi Chen, 3 Siyun Dong, 1 Bin Wng, 4
More informationSupporting Information
Supporting Information A Sn IV -Porphyrin-Based Metal-Organic Framework for the Selective Photo-Oxygenation of Phenol and Sulfides Ming-Hua Xie, Xiu-Li Yang, Chao Zou and Chuan-De Wu* Department of Chemistry,
More informationSection 6: Area, Volume, and Average Value
Chpter The Integrl Applied Clculus Section 6: Are, Volume, nd Averge Vlue Are We hve lredy used integrls to find the re etween the grph of function nd the horizontl xis. Integrls cn lso e used to find
More informationSupporting Information Mesoporous graphitic carbon nanodisks fabricated via catalytic carbonization of coordination polymers
Supporting Informtion Mesoporous grphiti ron nnodisks frited vi tlyti roniztion of oordintion polymers Pnpn Su, Ling Jing, Jio Zho, Jingwng Yn, Cn Li nd Qihu Yng Stte Key Lortory of Ctlysis, Dlin Institute
More informationSUPPLEMENTARY INFORMATION
SUPPLEMENTARY INFORMATION doi: 1.138/nnno.29.451 Aove-ndgp voltges from ferroelectric photovoltic devices S. Y. Yng, 1 J. Seidel 2,3, S. J. Byrnes, 2,3 P. Shfer, 1 C.-H. Yng, 3 M. D. Rossell, 4 P. Yu,
More informationTemperature influence compensation in microbolometer detector for image quality enhancement
.26/qirt.26.68 Temperture influence compenstion in microolometer detector for imge qulity enhncement More info out this rticle: http://www.ndt.net/?id=2647 Astrct y M. Krupiński*, T. Sosnowski*, H. Mdur*
More informationSupporting Information
Copyright WILEY-VCH Verlg GmH & Co. KGA, 69469 Weinheim, Germny, 216. Supporting Informtion for Adv. Mter., DOI: 1.12/dm.2155855 A Highly Efficient Metl-Free Oxygen Reduction Electroctlyst Assemled from
More informationDesigning Information Devices and Systems I Discussion 8B
Lst Updted: 2018-10-17 19:40 1 EECS 16A Fll 2018 Designing Informtion Devices nd Systems I Discussion 8B 1. Why Bother With Thévenin Anywy? () Find Thévenin eqiuvlent for the circuit shown elow. 2kΩ 5V
More informationPorous covalent electron-rich organonitridic frameworks as highly selective sorbents for methane and carbon dioxide
Received 9 My 2011 Accepted 20 Jun 2011 Pulished 19 Jul 2011 DOI: 10.1038/ncomms1405 Porous covlent electron-rich orgnonitridic frmeworks s highly selective sorents for methne nd cron dioxide Pritosh Mohnty
More informationThermal Performance of Electrocaloric Refrigeration using Thermal Switches of Fluid Motion and Changing Contact Conductance
Americn Journl of Physics nd Applictions 2016; 4(5): 134-139 http://www.sciencepublishinggroup.com/j/jp doi:.11648/j.jp.20160405.12 ISSN: 2330-4286 (Print); ISSN: 2330-4308 (Online) Therml Performnce of
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Unusual pore structure and sorption behaviour in a hexanodal zinc-organic framework material Jinjie Qian a,b Feilong Jiang, a Linjie Zhang, a,b Kongzhao Su, a,b Jie Pan, a,b Qipeng
More informationthe multiple helices
Supporting Information A 3D porous metal-organic framework containing nanotubes based on the multiple helices Lei Hou,* Li-Na Jia, Wen-Juan Shi, Li-Yun Du, Jiang Li, Yao-Yu Wang* and Qi-Zhen Shi Key Laboratory
More informationStructural Effect of Thioureas on the Detection of Chemical Warfare Agent Simulants
Structurl Effect of Thioures on the Detection of Chemicl Wrfre Agent Simulnts Seonggyun H, Minhe Lee, Hyun Ook Seo, b Sun Gu Song, Kyung-su Kim, Chn Heum Prk, Il Hee Kim, Young Dok Kim nd Chngsik Song*
More informationAll materials and reagents were obtained commercially and used without further
Reversible shrinkage and expansion of a blue photofluorescene cadmium coordination polymer and in situ tetrazole ligand synthesis Hong Deng,* a Yong-Cai Qiu, a Ying-Hua Li, a Zhi-Hui liu, a Rong-Hua Zeng,
More informationWeb Appendix for: Monetary-Fiscal Policy Interactions and Indeterminacy in Post-War U.S. Data. Saroj Bhattarai, Jae Won Lee and Woong Yong Park
We Appendix for: Monetry-Fiscl Policy Interctions nd Indetermincy in Post-Wr U.S. Dt Sroj Bhttri, Je Won Lee nd Woong Yong Prk Jnury 11, 2012 Approximte model Detrend The technology process A t induces
More informationReversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether
Supplementary Information Reversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether Xiao-Ping Zhou, a Zhengtao Xu,*,a Matthias Zeller, b Allen
More informationAQA Chemistry Paper 2
AQA hemistry Pper 2 1.1 A student is plnning n investigtion into how the concentrtion of hydrochloric cid ffects the rte of the rection with mrle chips. Wht is the independent vrile? Tick one ox. (1 mrk)
More informationCBE 291b - Computation And Optimization For Engineers
The University of Western Ontrio Fculty of Engineering Science Deprtment of Chemicl nd Biochemicl Engineering CBE 9b - Computtion And Optimiztion For Engineers Mtlb Project Introduction Prof. A. Jutn Jn
More informationANALYSIS OF FAST REACTORS SYSTEMS
ANALYSIS OF FAST REACTORS SYSTEMS M. Rghe 4/7/006 INTRODUCTION Fst rectors differ from therml rectors in severl spects nd require specil tretment. The prsitic cpture cross sections in the fuel, coolnt
More informationUnit 3: Direct current and electric resistance Electric current and movement of charges. Intensity of current and drift speed. Density of current in
Unit 3: Direct current nd electric resistnce Electric current nd movement of chrges. ntensity of current nd drift speed. Density of current in homogeneous currents. Ohm s lw. esistnce of homogeneous conductor
More informationTitle of file for HTML: Supplementary Information Description: Supplementary Figures. Title of file for HTML: Peer Review File Description:
Title of file for HTML: Supplementry Informtion Description: Supplementry Figures Title of file for HTML: Peer Review File Description: WTP SST IPO PDO WTP leds IPO PDO Supplementry Figure 1 IPO (or PDO)
More informationCALCULATED POWDER X-RAY DIFFRACTION LINE PROFILES VIA ABSORPTION
16 17 CALCULATED POWDER X-RAY DFFRACTON LNE PROFLES VA ABSORPTON Keji Liu nd Heifen Chen School of Mteril Science nd Engineering, Shnghi nstitute of Technology, Shnghi, Chin 2233 ABSTRACT We hve clculted
More informationQUB XRD Course. The crystalline state. The Crystalline State
QUB XRD Course Introduction to Crystllogrphy 1 The crystlline stte Mtter Gseous Stte Solid stte Liquid Stte Amorphous (disordered) Crystlline (ordered) 2 The Crystlline Stte A crystl is constructed by
More informationWhich of the following describes the net ionic reaction for the hydrolysis. Which of the following salts will produce a solution with the highest ph?
95. Which of the following descries the net ionic rection for the hydrolysis of NH4Cl( s)? A. NH4 ( q) Cl & ( q) NH4Cl( s) B. NH Cl & 4 ( s) NH4 ( q) Cl ( q) C. Cl ( q) H O & 2 ( l) HCl( q) OH ( q) D.
More informationEquations of Motion. Figure 1.1.1: a differential element under the action of surface and body forces
Equtions of Motion In Prt I, lnce of forces nd moments cting on n component ws enforced in order to ensure tht the component ws in equilirium. Here, llownce is mde for stresses which vr continuousl throughout
More informationPhysics 201 Lab 3: Measurement of Earth s local gravitational field I Data Acquisition and Preliminary Analysis Dr. Timothy C. Black Summer I, 2018
Physics 201 Lb 3: Mesurement of Erth s locl grvittionl field I Dt Acquisition nd Preliminry Anlysis Dr. Timothy C. Blck Summer I, 2018 Theoreticl Discussion Grvity is one of the four known fundmentl forces.
More information1B40 Practical Skills
B40 Prcticl Skills Comining uncertinties from severl quntities error propgtion We usully encounter situtions where the result of n experiment is given in terms of two (or more) quntities. We then need
More informationProblems for HW X. C. Gwinn. November 30, 2009
Problems for HW X C. Gwinn November 30, 2009 These problems will not be grded. 1 HWX Problem 1 Suppose thn n object is composed of liner dielectric mteril, with constnt reltive permittivity ɛ r. The object
More informationSupplementary Information for Directional Reflective Surface Formed via Gradient- Impeding Acoustic Meta-surfaces
Supplementry Informtion for Directionl Reflective Surfce Formed vi Grdient- Impeding Acoustic Met-surfces Kyungjun Song 1*, Jedo Kim 2, Hur Shin 1, Jun-Hyuk Kwk 1, Seong-Hyun Lee 3,Tesung Kim 4 1 Deprtment
More informationInterpreting Integrals and the Fundamental Theorem
Interpreting Integrls nd the Fundmentl Theorem Tody, we go further in interpreting the mening of the definite integrl. Using Units to Aid Interprettion We lredy know tht if f(t) is the rte of chnge of
More informationAMPERE CONGRESS AMPERE on Magnetic Resonance and Related Phenomena. Under the auspices of The GROUPEMENT AMPERE
AMPERE 2000 th 30 CONGRESS AMPERE on Mgnetic Resonnce nd Relted Phenomen Lison, Portugl, 23-2 July 2000 Under the uspices of The GROUPEMENT AMPERE Edited y: A.F. MARTINS, A.G. FEIO nd J.G. MOURA Sponsoring
More informationThe Wave Equation I. MA 436 Kurt Bryan
1 Introduction The Wve Eqution I MA 436 Kurt Bryn Consider string stretching long the x xis, of indeterminte (or even infinite!) length. We wnt to derive n eqution which models the motion of the string
More informationElectronic Supplementary Information. Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts
Electronic Supplementary Information Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts Sheng-Li Huang, Ai-Quan Jia and Guo-Xin Jin* Experimental
More informationEthers in a Porous Metal-Organic Framework
Supporting Information Enhanced Isosteric Heat of H 2 Adsorption by Inclusion of Crown Ethers in a Porous Metal-Organic Framework Hye Jeong Park and Myunghyun Paik Suh* Department of Chemistry, Seoul National
More informationJoule-Thomson effect TEP
Joule-homson effect EP elted oics el gs; intrinsic energy; Gy-Lussc theory; throttling; n der Wls eqution; n der Wls force; inverse Joule- homson effect; inversion temerture. Princile A strem of gs is
More informationA REVIEW OF CALCULUS CONCEPTS FOR JDEP 384H. Thomas Shores Department of Mathematics University of Nebraska Spring 2007
A REVIEW OF CALCULUS CONCEPTS FOR JDEP 384H Thoms Shores Deprtment of Mthemtics University of Nebrsk Spring 2007 Contents Rtes of Chnge nd Derivtives 1 Dierentils 4 Are nd Integrls 5 Multivrite Clculus
More informationQUADRATURE is an old-fashioned word that refers to
World Acdemy of Science Engineering nd Technology Interntionl Journl of Mthemticl nd Computtionl Sciences Vol:5 No:7 011 A New Qudrture Rule Derived from Spline Interpoltion with Error Anlysis Hdi Tghvfrd
More information2.57/2.570 Midterm Exam No. 1 March 31, :00 am -12:30 pm
2.57/2.570 Midterm Exm No. 1 Mrch 31, 2010 11:00 m -12:30 pm Instructions: (1) 2.57 students: try ll problems (2) 2.570 students: Problem 1 plus one of two long problems. You cn lso do both long problems,
More informationHomework Assignment 3 Solution Set
Homework Assignment 3 Solution Set PHYCS 44 6 Ferury, 4 Prolem 1 (Griffiths.5(c The potentil due to ny continuous chrge distriution is the sum of the contriutions from ech infinitesiml chrge in the distriution.
More informationPhysics 9 Fall 2011 Homework 2 - Solutions Friday September 2, 2011
Physics 9 Fll 0 Homework - s Fridy September, 0 Mke sure your nme is on your homework, nd plese box your finl nswer. Becuse we will be giving prtil credit, be sure to ttempt ll the problems, even if you
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 15 Supporting Information Co-MOF as sacrificial template: Manifesting new Co
More informationSupporting Information
Supporting Information Unprecedented solvent-dependent sensitivities in highly efficient detection of metal ions and nitroaromatic compounds by a fluorescent Ba MOF Rongming Wang, Xiaobin Liu, Ao Huang,
More informationHigh Hydroxide-Conducting Polymer Electrolyte Membranes from Aromatic ABA Triblock Copolymers
Supporting informtion High Hydroxide-Conducting Polymer Electrolyte Membrnes from Aromtic ABA Triblock Copolymers Qing Li, Lei Liu, Qingqing Mio, b Bngkun Jin* nd Ruke Bi* CAS Key Lbortory of Soft Mtter
More informationDepartment of Mechanical Engineering ME 322 Mechanical Engineering Thermodynamics. Lecture 33. Psychrometric Properties of Moist Air
Deprtment of Mechnicl Engineering ME 3 Mechnicl Engineering hermodynmics Lecture 33 sychrometric roperties of Moist Air Air-Wter Vpor Mixtures Atmospheric ir A binry mixture of dry ir () + ter vpor ()
More informationChapter 4: Techniques of Circuit Analysis. Chapter 4: Techniques of Circuit Analysis
Chpter 4: Techniques of Circuit Anlysis Terminology Node-Voltge Method Introduction Dependent Sources Specil Cses Mesh-Current Method Introduction Dependent Sources Specil Cses Comprison of Methods Source
More informationThermal Diffusivity. Paul Hughes. Department of Physics and Astronomy The University of Manchester Manchester M13 9PL. Second Year Laboratory Report
Therml iffusivity Pul Hughes eprtment of Physics nd Astronomy The University of nchester nchester 3 9PL Second Yer Lbortory Report Nov 4 Abstrct We investigted the therml diffusivity of cylindricl block
More informationRates of chemical reactions
Rtes of chemicl rections Mesuring rtes of chemicl rections Experimentl mesuring progress of the rection Monitoring pressure in the rection involving gses 2 NO( g) 4 NO ( g) + O ( g) 2 5 2 2 n(1 α) 2αn
More informationSUPPORTING INFORMATION
SUPPORTING INFORMATION Table of Contents S1 1. General materials and methods S2 2. Syntheses of {Pd 84 } and {Pd 17 } S3-S4 3. MS studies of {Pd 84 }, {Pd 17 } and the two-component reactions S5-S6 4.
More informationLight and Optics Propagation of light Electromagnetic waves (light) in vacuum and matter Reflection and refraction of light Huygens principle
Light nd Optics Propgtion of light Electromgnetic wves (light) in vcuum nd mtter Reflection nd refrction of light Huygens principle Polristion of light Geometric optics Plne nd curved mirrors Thin lenses
More informationAn Anionic Metal Organic Framework For Adsorption and. Separation of Light Hydrocarbons
Supporting Information for An Anionic Metal Organic Framework For Adsorption and Separation of Light Hydrocarbons Jia Li, Hong-Ru Fu, Jian Zhang, Lan-Sun Zheng, and Jun Tao* State Key Laboratory of Physical
More informationSupporting Information. Integration of accessible secondary metal sites into MOFs for H 2 S removal
Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers. This journal is the Partner Organisations 2014 Supporting Information Integration of accessible secondary metal sites into MOFs
More information1 ST ROUND, SOLUTIONS
ST ROUND, SOLUTIONS Problem (Lithuni) Self destructing pper ( points) Solution ( ) ( ) ( ) [Al HO OH ) ph pk lg [Al H O ( ) ( ) [Al H O OH [Al ( ).9 [Al H O.9.47 [Al ( ) ( ) ( ) [Al H O OH.9 pk ph lg.
More informationA study of fluid flow simulation in convergentdivergent
IOP Conference Series: Mterils Science nd Engineering PAPER OPEN ACCESS A study of fluid flow simultion in convergentdivergent nozzles To cite this rticle: I Olru 2015 IOP Conf. Ser.: Mter. Sci. Eng. 95
More informationSupporting Information
Supporting Information Highly selective carbon dioxide adsorption in a water-stable Indium-organic framework material Jin-Jie Qian, a,bi Fei-Long Jiang, a Da-Qiang Yuan, a Ming-Yan Wu, a Shu-Quan Zhang,
More informationI1 = I2 I1 = I2 + I3 I1 + I2 = I3 + I4 I 3
2 The Prllel Circuit Electric Circuits: Figure 2- elow show ttery nd multiple resistors rrnged in prllel. Ech resistor receives portion of the current from the ttery sed on its resistnce. The split is
More informationA flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases. Supporting Information
A flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases Jingming Zhang, a Haohan Wu, a Thomas J. Emge, a and Jing Li* a a Department of Chemistry and Chemical Biology,
More informationarxiv:hep-ex/ v1 12 Sep 1998
Evidence of the φ ηπ γ decy rxiv:hep-ex/9891v1 12 Sep 1998 Astrct M.N.Achsov, V.M.Aulchenko, S.E.Bru, A.V.Berdyugin, A.V.Bozhenok, A.D.Bukin, D.A.Bukin, S.V.Burdin, T.V.Dimov, S.I.Dolinski, V.P.Druzhinin,
More information