Electrochemistry in Nonaqueous Solutions
|
|
- Rebecca Patterson
- 5 years ago
- Views:
Transcription
1 К. Izutsu Electrochemistry in Nonaqueous Solutions WILEY-VCH
2 Contents Preface V Part I Fundamentals of Chemistry in Non-Aqueous Solutions: Electrochemical Aspects 1 Properties of Solvents and Solvent Classification Properties of Solvents Physical Properties of Solvents Chemical Properties of Solvents Structural Aspects of Solvents Toxicity and Hazardous Properties of Solvents Classification of Solvents Effects of Solvent Properties on Chemical Reactions (an Outline) References 23 2 Solvation and Complex Formation of Ions and Behavior of Electrolytes Influence of Ion Solvation on Electrolyte Dissolution Some Fundamental Aspects of Ion-Solvation Ion-Solvent Interactions Affecting Ion Solvation Structure of Solvated Ions Ultrafast Ion-Solvation Dynamics Comparison of Ionic Solvation Energies in Different Solvents and Solvent Effects on Ionic Reactions and Equilibria Gibbs Energies of Transfer and Transfer Activity Coefficients of Ions Prediction of Solvent Effects by the Use of Transfer Activity Coefficients Solvent Effects on the Complexation of Metal Ions Selective Solvation of Ions in Mixed Solvents Ion Association and Solvent Permittivities References 56
3 X Contents 3 Acid-Base Reactions in Non-Aqueous Solvents Solvent Effects on Acid-Base Reactions Acid-Base Reactions in Amphiprotic Solvents of High Permittivit Acid-Base Reactions in Aprotic Solvents of High Permittivity Acid-Base Reactions in Amphiprotic Solvents of Low Permittivity Acid-Base Reactions in Aprotic Solvents of Low Permittivity ph-scales in Non-Aqueous Solutions Definition of ph in Non-Aqueous Solutions ph Windows in Non-Aqueous Solvents and ph Scales Common to Multi Solvents References 82 4 Redox Reactions in Non-Aqueous Solvents Solvent Effects on Various Types of Redox Reactions Fundamentals of Redox Reactions Solvent Effects on Redox Potentials and Redox Reaction Mechanisms Dynamical Solvent Effects on the Kinetics of Redox Reactions Redox Properties of Solvents and Potential Windows Redox Titrations in Non-Aqueous Solutions Titrations with Oxidizing Agents Titrations with Reducing Agents References 106 Part II Electrochemical Techniques and Their Applications in Non-Aqueous Solutions 5 Overview of Electrochemical Techniques Classification of Electrochemical Techniques Fundamentals of Electrode Reactions and Current-Potential Relations Current-Potential Relation for Electron Transfer at the Electrode Current-Potential Relations and Mass Transport DC Polarography - Methods that Electrolyze Electroactive Species Only Partially (1) New Types of Polarography - Methods that Electrolyze Electroactive Species Only Partially (2) AC Polarography SW Polarography Pulse Polarography Voltammetry and Related New Techniques - Methods that Electrolyze Electroactive Species Only Partially (3) 129
4 Contents XI Linear Sweep Voltammetry Cyclic Voltammetry Voltammetry at Rotating Disk and Rotating Ring-Disk Electrodes Ultramicroelectrodes Modified Electrodes Combination of Voltammetry and Non-Electrochemical Methods Voltammetry at the Interface Between Two Immiscible Electrolyte Solutions Electrogravimetry and Coulometry - Methods that Completely Electrolyze Electroactive Species Controlled-Potential Electrolysis and Controlled-Current Electrolysis Electrogravimetry Coulometry and Coulometric Titrations Potentiometry - A Method that Does Not Electrolyze Electroactive Species Potentiometrie Indicator Electrodes and Reference Electrodes Potentiometrie Titrations Conductimetry - A Method that is Not Based on Electrode Reactions Electrochemical Instrumentation - Roles of Operational Amplifiers and Microcomputers Application of Operational Amplifiers in Electrochemical Instrumentation Applications of Personal Computers in Electrochemical Instrumentation References Potentiometry in Non-Aqueous Solutions Basic Techniques of Potentiometry in Non-Aqueous Solutions Potentiometrie Indicator Electrodes for Non-Aqueous Solutions Reference Electrodes for Non-Aqueous Solutions Method of Reporting Electrode Potentials in Non-Aqueous Solutions (IUPAC Recommendation) Liquid Junction Potential Between Electrolyte Solutions in the Same Solvent ph Measurements in Non-Aqueous Solutions ph Measurements in Aqueous Solutions Methods of ph Measurements in Non-Aqueous and Mixed Solvents Determination of Autoprotolysis Constants Applications of Potentiometry in Non-Aqueous Solutions Acid-Base Reactions in Non-Aqueous Solvents Precipitation Reactions in Non-Aqueous Solutions Complex Formation Reactions in Non-Aqueous Solutions 186
5 XII Contents Redox Reactions in Non-Aqueous Solutions Potentiometrie Characterization of Solvents Potentiometrie Study of Ion Solvation - Applications that Compare Electrode Potentials in Different Solvents Liquid Junction Potentials between Different Solvents References Conductimetry in Non-Aqueous Solutions Dissociation of Electrolytes and Electrolytic Conductivity Molar Conductivity of Dilute Solutions of Symmetrical Strong Electrolytes Molar Conductivity and Association Constants of Symmetrical Weak Electrolytes Molar Conductivity and the Formation of Triple Ions Conductivity of Solutions of Symmetrical Strong Electrolytes at Moderate to High Concentrations Molar Conductivity and Ion Association of Asymmetric Electrolytes Ionic Conductivities and Solvents Stokes' Law and Walden's Rule - Role of Ultrafast Solvent Dynamics Method for the Determination of Limiting Molar Conductivities of Ions Applications of Conductimetry in Non-Aqueous Solutions Study of the Behavior of Electrolytes (Ionophores) Conductimetric Studies of Acid-Base Equilibria References Polarography and Voltammetry in Non-Aqueous Solutions Basic Experimental Techniques in Non-Aqueous Solutions Experimental Apparatus for Non-Aqueous Systems Solvents and Supporting Electrolytes Polarography and Voltammetry of Inorganic Species Polarographic Reductions of Metal Ions Polarography and Voltammetry of Metal Complexes Polarography and Voltammetry of Anions Electrode Reactions of Dissolved Oxygen, Dissolved Hydrogen, Carbon Dioxide, and Solvated Electrons Polarography and Voltammetry of Organic Compounds Reduction of Organic Compounds Oxidation of Organic Compounds Cyclic Voltammetry for Electrochemical Studies in Non-Aqueous Solutions Digital Simulation in Cyclic Voltammetry Ultramicroelectrodes in Cyclic Voltammetry 262
6 Contents XIII Low Temperature Electrochemistry and Cyclic Voltammetry References Other Electrochemical Techniques in Non-Aqueous Solutions Use of Electrolytic and Coulometric Techniques in Non-Aqueous Solutions Combination of Electrochemical and Nonelectrochemical Techniques Spectroelectrochemistry Electrochemical-ESR Method Electrochemical Mass Spectroscopy Use of Electrochemical Quartz Crystal Microbalance (EQCM) Use of Scanning Electrochemical Microscopy (SECM) References Purification of Solvents and Tests for Impurities Effects of Solvent Impurities on Electrochemical Measurements Procedures for the Purification of Solvents Tests for Purity of Solvents Purification Methods for Solvents in Common Use References Selection and Preparation of Supporting Electrolytes Selection of Supporting Electrolytes for Electrochemical Measurements Solubility and Conductivity of Supporting Electrolytes Potential Windows and Supporting Electrolytes Influences of Supporting Electrolytes on Electrode Reactions in Non-Aqueous Solutions Methods for Preparing and Purifying Supporting Electrolytes References Use of Non-Aqueous Solutions in Modern Electrochemical Technologies New Batteries Using Non-Aqueous Solutions (Lithium Batteries) New Capacitors Using Non-Aqueous Solutions Supercapacitors Aluminum Electrolytic Capacitors Conducting Polymers and Electrochemistry in Non-Aqueous Solutions Electrochemical Reduction of C0 2 in Non-Aqueous Solvents Use of Acetonitrile in Electrowinning and Electrorefining of Copper Electrodeposition of Metals from Non-Aqueous Solutions 324
7 XIV Contents 12.7 Electrochemical Use of Supercritical Fluids and Ionic Liquids as Benign Solvents Supercritical Fluid Solvents Room-temperature Ionic Liquids References 329 Index 331
Principles and Applications of Electrochemistry
Principles and Applications of Electrochemistry Fourth edition D. R. CROW Professor of Electrochemistry and Dean of Research University of Wolverhampton BLACKIE ACADEMIC & PROFESSIONAL An Imprint of Chapman
More informationAIMALYTICAL CHEMISTRY
Fundamentals of AIMALYTICAL CHEMISTRY Seventh Edition Douglas A. Skoog Stanford University Donald M. West San Jose State University F. James Holler University ;of Kentucky W r SAUNDERS COLLEGE PUBLISHING
More informationKosuke Izutsu Electrochemistry in Nonaqueous Solutions
Electrochemistry in Nonaqueous Solutions. Kosuke Izutsu Copyright 2002 Wiley-VCH Verlag GmbH & Co. KGaA ISBNs: 3-527-30516-5 (Hardback); 3-527-60065-5 (Electronic) Kosuke Izutsu Electrochemistry in Nonaqueous
More information8. Draw Lewis structures and determine molecular geometry based on VSEPR Theory
Chemistry Grade 12 Outcomes 1 Quantum Chemistry and Atomic Structure Unit I 1. Perform calculations on wavelength, frequency and energy. 2. Have an understanding of the electromagnetic spectrum. 3. Relate
More informationFUNDAMENTALS OF ELECTRO- ANALYTICAL CHEMISTRY
FUNDAMENTALS OF ELECTRO- ANALYTICAL CHEMISTRY Paul Monk Manchester Metropolitan University, Manchester, UK JOHN WILEY & SONS LTD Chichester New York Weinheim Brisbane Toronto Singapore Contents Series
More informationPrinciples of Electrochemistry Second Edition
Principles of Electrochemistry Second Edition Jiri Koryta Institute of Physiology, Czechoslovak Academy of Sciences, Prague HKJin Dvorak Department of Physical Chemistry, Faculty of Science, Charles University,
More informationStudent Achievement. Chemistry 12
Student Achievement Chemistry 12 Key Elements: Reaction Kinetics Estimated Time: 14 16 hours By the end of this course, students will be able to explain the significance of reaction rates, demonstrate
More informationContents. 1 Matter: Its Properties and Measurement 1. 2 Atoms and the Atomic Theory Chemical Compounds Chemical Reactions 111
Ed: Pls provide art About the Authors Preface xvii xvi 1 Matter: Its Properties and Measurement 1 1-1 The Scientific Method 2 1-2 Properties of Matter 4 1-3 Classification of Matter 5 1-4 Measurement of
More informationCHEM 1310: Review. List of major topics
CHEM 1310: Review List of major topics Chapter 1: Atomic Nature of Matter Atomic theory of matter Atomic masses Moles Elemental analysis Volume & density Chapter 2: Stoichiometry Balancing equations Limiting
More informationElectroanalytical Chemistry techniques covered to date
Electroanalytical Chemistry techniques covered to date Potentiometry based on galvanic cell Controlled Potential Electrolysis electrolytic Chronoamperometry electrolytic cell Chronopotentiometry electrolytic
More informationAn Introduction to Ionic Liquids. Michael Freemantle. RSC Publishing
An to Ionic Liquids Michael Freemantle RSC Publishing Chapter 1 1 1.1 Definition of Ionic Liquids 1 1.2 Synonyms 1 1.3 Attraction of Ionic Liquids 2 1.4 Cations and Anions 3 1.5 Shorthand Notation for
More informationVoltammetry. Voltammetry and Polarograph. Chapter 23. Polarographic curves -- Voltammograms
Chapter 23 Voltammetry Voltammetry and Polarograph Electrochemistry techniques based on current (i) measurement as function of voltage (E appl ) Voltammetry Usually when the working electrode is solid,
More informationCombined Science Chemistry Academic Overview
Combined Science Chemistry Academic Overview 2018-2019 Science Term 1.1 Term 1.2 Term 2.1 Term 2.2 Term 3.1 Term 3.2 Year 9 States of Matter Methods of Separating and Purifying Substances Atomic Structure
More informationSpecific Curriculum Outcomes (updated September 18, 2016)
1 Chemistry 12 Specific Curriculum Outcomes (updated September 18, 2016) Unit A: Thermochemistry Overview: In this unit, students study energy as it relates to chemical changes and quantify the energy
More informationChemistry 1011 TOPIC TEXT REFERENCE. Electrochemistry. Masterton and Hurley Chapter 18. Chemistry 1011 Slot 5 1
Chemistry 1011 TOPIC Electrochemistry TEXT REFERENCE Masterton and Hurley Chapter 18 Chemistry 1011 Slot 5 1 18.5 Electrolytic Cells YOU ARE EXPECTED TO BE ABLE TO: Construct a labelled diagram to show
More informationChemistry PhD Qualifying Exam Paper 1 Syllabus
Chemistry PhD Qualifying Exam Paper 1 Syllabus Preface This document comprises all topics relevant for Paper 1 of the Ph.D. Qualifying Exam in Chemistry at Eastern Mediterranean University, in accordance
More information************************************************************************************** NSS1 ( )
Yan Oi Tong Tin Ka Ping Secondary School NSS1 Chemistry Teaching Schedule (2018 2021) NSS1 Chemistry (2018 2021) / Teaching Schedule / P.1 **************************************************************************************
More informationCHEM 540 ADVANCED ANALYTICAL CHEMISTRY
CHEM 540 ADVANCED ANALYTICAL CHEMISTRY CHEM 540 KFUPM CHEM 540, Advanced Analytical Chemistry CHEMISTRY DEPT. Credit hours: 3 Fall 2006/2007 ( Term 061) DR A.M.Y. JABER Room 261F, Tel 2611 Office hours
More informationCHAPTER 1. FUNDAMENTAL CONCEPTS OF ELECTROANALYTICAL CHEMISTRY
CHAPTER 1. FUNDAMENTAL CONCEPTS OF ELECTROANALYTICAL CHEMISTRY I. Introduction What is electrochemistry? Fundamental process: charge transfer at an interface FIGURE 1-1. Electrochemistry as an Interdisciplinary
More informationUnit 2 B Voltammetry and Polarography
Unit 2 B Voltammetry and Polarography Voltammetric methods of Analysis What is Voltammetry? A time-dependent potential is applied to an electrochemical cell, and the current flowing through the cell is
More informationMiami Dade College CHM Second Semester General Chemistry
Miami Dade College CHM 1046 - Second Semester General Chemistry Course Description: CHM 1046 is the second semester of a two-semester general chemistry course for science, premedical science and engineering
More informationn. log a ox a red
Amperometry &Voltammetry Non-equilibrium electrochemistry! Based on Electrolytic Cells---apply external voltage to pair of electrodes to force rxn to occur--get current flow---current α [conc] o E elect
More informationChemistry 12 - Learning Outcomes
Chemistry 12 - Learning Outcomes A: Chapt 1. Reaction Kinetics - (Introduction) A1. give examples of reactions proceeding at different rates A2. describe rate in terms of some quantity (produced or consumed)
More informationChapter 24. Electrogravimetry and Coulometry
Chapter 24 Electrogravimetry and Coulometry Dynamic Electrochemical Methods of analysis Electrolysis Electrogravimetric and Coulometric Methods For a cell to do any useful work or for an electrolysis to
More informationChemistry 8155: Advanced Electroanalytical Chemistry 4 Credits Syllabus and Course Information
Chemistry 8155: Advanced Electroanalytical Chemistry Credits Syllabus and Course Information The goal of this course is to familiarize students with electroanalytical techniques and their physicochemical
More informationELECTROCHEMICAL SYSTEMS
ELECTROCHEMICAL SYSTEMS Third Edition JOHN NEWMAN and KAREN E. THOMAS-ALYEA University of California, Berkeley ELECTROCHEMICAL SOCIETY SERIES WILEY- INTERSCIENCE A JOHN WILEY & SONS, INC PUBLICATION PREFACE
More informationAdvanced Analytical Chemistry Lecture 19. Chem 4631
Advanced Analytical Chemistry Lecture 19 Chem 4631 Organic Electrochemistry is a multidisciplinary science overlapping the fields of organic chemistry, biochemistry, physical chemistry and electrochemistry.
More informationCARBON. Electrochemical ond Physicochemicol Properties KIM KINOSHITA. Lawrence Berkeley Laboratory Berkeley, California
CARBON Electrochemical ond Physicochemicol Properties KIM KINOSHITA Lawrence Berkeley Laboratory Berkeley, California A Wiley-Interscience Publicotion JOHN WILEY & SONS New York / Chichester / Brisbane
More information7.1 Electrolyte and electrolytic solution
Out-class reading: Levine, pp. 294-310 Section 10.6 solutions of electrolytes Section 10.9 ionic association pp. 512-515 Section 16.6 electrical conductivity of electrolyte solutions. Contents of solution
More informationContents. Publisher s Foreword. Glossary of Symbols and Abbreviations
Publisher s Foreword Glossary of Symbols and Abbreviations v xiii 1 Equilibrium Electrochemistry and the Nernst Equation 1 1.1 Cell Thermodynamics....................... 1 1.2 The Nernst Equation........................
More informationUniform properties throughout! SOLUTE(S) - component(s) of a solution present in small amounts.
37 SOLUTIONS - a SOLUTION is a HOMOGENEOUS MIXTURE. Uniform properties throughout! - parts of a solution: SOLUTE(S) - component(s) of a solution present in small amounts. SOLVENT - the component of a solution
More information(a) Complete Figure 9 by placing one tick in each row to show whether the salt is soluble or insoluble. salt soluble insoluble.
1 The method used to prepare a salt depends on its solubility in water. (a) Complete Figure 9 by placing one tick in each row to show whether the salt is soluble or insoluble. ammonium chloride salt soluble
More informationRedox Titration. Properties of Umass Boston
Redox Titration Redox Titration Ce 4+ + Fe 2+ Ce 3+ + Fe 3+ Redox titration is based on the redox reaction (oxidation-reduction) between analyte and titrant. Position of the end point Determine the end
More informationCourse Title: Academic chemistry Topic/Concept: Chapter 1 Time Allotment: 11 day Unit Sequence: 1 Major Concepts to be learned:
Course Title: Academic chemistry Topic/Concept: Chapter 1 Time Allotment: 11 day Unit Sequence: 1 1. Nature of chemistry 2. Nature of measurement 1. Identify laboratory equipment found in the lab drawer
More informationToday s Objectives: and an electrolytic cell. standard cell potentials. Section 14.3 (pp )
Today s Objectives: 1. Identify the similarities and differences between a voltaic cell and an electrolytic cell 2. Predict the spontaneity of REDOX reactions based on standard cell potentials. 3. Recognize
More informationRedox Reactions and Electrochemistry
Redox Reactions and Electrochemistry Redox Reactions and Electrochemistry Redox Reactions (19.1) Galvanic Cells (19.2) Standard Reduction Potentials (19.3) Thermodynamics of Redox Reactions (19.4) The
More information2. Define what is meant by an oxidizing and reducing agent. Give a good example of each.
In-class Questions Electrochemistry 1. Define what is meant by oxidation and reduction. 2. Define what is meant by an oxidizing and reducing agent. Give a good example of each. 3. Define what is meant
More informationIndex. Binary molten salt mixture, schematic representation, 15 3
Acid-base equilibria of water in melts, table of equilibrium constant values, 314 Acidity of metal aquo complexes, 132 Acidobasicity of water in molten salts, 311 Acids in dilute solution, pk values, 130
More informationIonic Liquids. Nicolas Bartilla
Ionic Liquids Nicolas Bartilla 03-23-2011 [4]DECHEMA-Meeting, February 2011, Erlangen Technological Applications What are Ionic Liquids? The term ionic liquids refers to compounds consisting entirely of
More informationChemical Metallurgy-II (Theoretical fundamentals of processes for metal production)
University of Miskolc Faculty of Materials Science and Engineering Antal Kerpely Doctoral School of Materials Science & Technology Chemical Metallurgy-II (Theoretical fundamentals of processes for metal
More informationA covalent bond is a shared pair of electrons between atoms of two non-metal elements.
Bonding, Structure and properties Atoms can be held together by chemical bonds. When atoms form bonds, they can achieve a stable electron arrangement (full outer electron shell). To achieve a stable electron
More informationChapter - 8. Summary and Conclusion
Chapter - 8 Summary and Conclusion The present research explains the synthesis process of two transition metal oxide semiconductors SnO 2 and V 2 O 5 thin films with different morphologies and studies
More informationUnit 2 Electrochemical methods of Analysis
Unit 2 Electrochemical methods of Analysis Recall from Freshman Chemistry: Oxidation: Loss of electrons or increase in the oxidation number Fe 2 e - Fe 3 Reduction: Gain of electrons or decreases in the
More informationCHEMISTRY 12 SYLLABUS Online 2010
CHEMISTRY 12 SYLLABUS Online 2010 Mr. Lockwood Email: plockwood@sd43.bc.ca Personal: https://my43.sd43.bc.ca/schools/pinetreesecondary/classes/plockwood/default.aspx UserName: Password: WebCT: http://bb.etc.bc.ca/webct/entrypageins.dowebct
More informationPersonalised Learning Checklists Edexcel Combined: Chemistry Paper 1
Edexcel (combined) Chemistry Topics (1SC0) from 2016 - Paper 1 (Topic 1 parts a&b) Topic Student Checklist R A G Describe how the Dalton model of an atom has changed over time because of the discovery
More informationElectro Analytical Methods
CH 2252 Instrumental Methods of Analysis Unit II Electro Analytical Methods Dr. M. Subramanian Associate Professor Department of Chemical Engineering Sri Sivasubramaniya Nadar College of Engineering Kalavakkam
More informationReference electrode. Calomel electrode Hg in contact with Hg(I) chloride Ag/AgCl 15-2
Potentiometry Potential measurements of electrochemical cells Ion selective methods Reference electrode Indicator electrode Potential measuring device Reference electrode Indicator electrodes Ion specific
More informationCHEMISTRY HIGHER LEVEL
*P15* Pre-Leaving Certificate Examination, 2012 Triailscrúdú na hardteistiméireachta, 2012 CHEMISTRY HIGHER LEVEL TIME: 3 HOURS 400 MARKS Answer eight questions in all These must include at least two questions
More informationElectrochemistry. Part One: Introduction to Electrolysis and the Electrolysis of Molten Salts
Part One: Introduction to Electrolysis and the Electrolysis of Molten Salts What do I need to know about electrochemistry? Electrochemistry Learning Outcomes: Candidates should be able to: a) Describe
More informationChemistry ATOMS FIRST. Julia Burdge. Jason Overby. Mc GraiA/ Hill. Xonnect Learn I Succeed" UNIVERSITY OF IDAHO COLLEGE OF CHARLESTON
Chemistry ATOMS FIRST Julia Burdge UNIVERSITY OF IDAHO Jason Overby COLLEGE OF CHARLESTON Mc GraiA/ Hill Xonnect Learn I Succeed" Contents List of Applications vi Preface vii CHEMISTRY: THE SCIENCE OF
More information1. Introduction. Introduction
1. The chemistry of organometallic compounds represents an important part of organic and pharmaceutical synthesis [1-6]. These compounds are used as catalysts in the stereospecific polymerization of olefins,
More informationSolid State electrochemistry
Solid State electrochemistry edited by Peter G. Bruce Department of Chemistry, University of St Andrews, Scotland IH CAMBRIDGE ^pf UNIVERSITY PRESS 1 1.1 1.2 1.3 1.4 1.5 1.6 Preface Introduction P. G.
More information(c) Na is deposited at the cathode (d) Na appears at the anode
year chemiry n0tes new CHAPTER 10 ELECTROCHEMISTRY MCQS Q.1 Electrolysis is the process in which a chemical reaction takes place at the expense of (a) chemical energy (b) electrical energy (c) heat energy
More information11.3. Electrolytic Cells. Electrolysis of Molten Salts. 524 MHR Unit 5 Electrochemistry
11.3 Electrolytic Cells Section Preview/ Specific Expectations In this section, you will identify the components of an electrolytic cell, and describe how they work describe electrolytic cells using oxidation
More informationClass 12 Important Questions for Chemistry Electrochemistry
Class 12 Important Questions for Chemistry Electrochemistry Multiple Choice Questions (Type-I) 1. Which cell will measure standard electrode potential of copper electrode? o (i) Pt (s) H2 (g,0.1 bar) H
More informationConductivity of Electrolytes in Solution
Conductivity of Electrolytes in Solution Introduction: Electrical current can be thought of as the movement of electrons or ionic charges from an area of high potential to an area of low potential. Materials
More informationELECTROCHEMICAL CELLS
ELECTROCHEMICAL CELLS Electrochemistry 1. Redox reactions involve the transfer of electrons from one reactant to another 2. Electric current is a flow of electrons in a circuit Many reduction-oxidation
More informationAdvanced Chemistry in Creation, 2 nd Edition Table of Contents
Advanced Chemistry in Creation, 2 nd Edition Table of Contents MODULE #1: Units, Chemical Equations, and Stoichiometry Revisited... 1 Introduction... 1 Units Revisited... 1 A New Look at Chemical Equations...
More informationElectrochemistry: Elektrolytic and galvanic cell
Electrochemistry: Elektrolytic and galvanic cell 1/26 Galvanic series (Beketov, cca 1860): Ca, Al, Mn, Cr, Zn, Cd, Fe, Pb, [H 2 ], Cu, Ag, Au Cell = system composed of two electrodes and an electrolyte.
More information4.4.1 Reactivity of metals Metal oxides The reactivity series. Key opportunities for skills development.
4.4 Chemical changes Understanding of chemical changes began when people began experimenting with chemical reactions in a systematic way and organising their results logically. Knowing about these different
More informationThinkwell s Homeschool AP Chemistry Course Lesson Plan: 34 weeks
Thinkwell s Homeschool AP Chemistry Course Lesson Plan: 34 weeks Welcome to Thinkwell s Homeschool AP Chemistry! We re thrilled that you ve decided to make us part of your homeschool curriculum. This lesson
More informationChapter 9. Aqueous Solutions and Chemical Equilibria
Chapter 9 Aqueous Solutions and Chemical Equilibria Classifying Solutions of Electrolytes Electrolytes form ions when dissolved in solvent and thus produce solutions that conduct electricity. Strong electrolytesionize
More informationEnfield Public Schools. Advanced (AP/UCONN) Chemistry (0297) Curriculum Writers: Patrick Smith William Schultz
Enfield Public Schools Advanced (AP/UCONN) Chemistry (0297) Curriculum Writers: Patrick Smith William Schultz November 2007 Lab Safety 1. Basic safety rules must be followed in the Advanced Chemistry laboratory.
More informationDates Syllabus to be covered Remarks
PO LEUNG KUK CENTENARY LI SHIU CHUNG MEMORIAL COLLEGE TEACHING SCHEDULE 2016/2017 FORM: 4 SUBJECT: CHEMISTRY TEXTBOOK: New 21 st Century Chemistry 2 nd Edition (Jing Kung Educational Press) Cycle 1 2 3
More informationIntroduction Oxidation/reduction reactions involve the exchange of an electron between chemical species.
Introduction Oxidation/reduction reactions involve the exchange of an electron between chemical species. The species that loses the electron is oxidized. The species that gains the electron is reduced.
More informationSubject: Chemistry Year: Assessment (Evidence) Quiz. Acids in our daily lives Act 14.1 Acids in the laboratory
Queen Elizabeth School Old Students' Association Secondary School 2013-2014 Chemistry Secondary Form 4 Curriculum Map Textbooks: New 21st Century Chemistry Books 1C; 2A - 2C (Jing Kung Educational Press)
More informationA Problem-Solving Approach to Aquatic Chemistry
A Problem-Solving Approach to Aquatic Chemistry James N. Jensen University at Buffalo John Wiley & Sons, Inc. Table of Contents Partfc I^damental^^ 1_ Chapter 1: Getting Started with the Fundamental Concepts
More informationBy: C. W. Anderson, K. R. Lung, and Terence A. Nile
Electrochemistry of Homogeneous Catalysts: Correlation of the Electrochemistry and the Ziegler Natta Catalytic Activity of Metal Acetylacetonate Complexes By: C. W. Anderson, K. R. Lung, and Terence A.
More informationFORM 4 CHEMISTRY - SUMMER REVISION WORK
Form 3 Syllabus: FORM 4 CHEMISTRY - SUMMER REVISION WORK Chapter 1: STATES OF MATTER Converting between the 3 states of matter Application of kinetic theory to changes of state Diffusion Physical and chemical
More informationHydrogen redox reactions in 1-ethyl-2,3-dimethylimidazolium
Accepted Manuscript Hydrogen redox reactions in 1-ethyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide on platinum single crystal electrodes Andrea P. Sandoval, Marco F. Suárez-Herrera, Juan
More informationBASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA
BASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA BASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA BRIAN M. TISSUE Virginia Tech Department of Chemistry Blacksburg, VA Cover Design: Wiley Cover
More informationChemistry: The Central Science Twelfth Edition, AP* Edition 2012
A Correlation of The Central Science Twelfth Edition, AP* Edition 2012 to the AP* Chemistry Topics I. Structure of Matter A. Atomic theory and atomic structure 1. Evidence for the atomic theory SECTIONS:
More informationElectrolytic processes Notes
Edexcel GCSE Chemistry Topic 3: Chemical changes Electrolytic processes Notes 3.22 Recall that electrolytes are ionic compounds in the molten state or dissolved in water When an ionic substance is melted
More informationAP Chemistry Common Ion Effect; 16.6 ionization constants, will. Equilibria with Weak Acids and and the preparation of buffer
Instructional Unit Acid-Base Equibria 16.1 Acid-Ionizaation Equilibria; Students will perform Students will distinguish Oral response, written 3.1.12C, 16.2 Polyprotic Acids; 16.3 Base- calculations involving
More informationChemistry 30 Review Test 3 Redox and Electrochemistry /55
Chemistry 30 Review Test 3 Redox and Electrochemistry /55 Part I Multiple choice / Numerical Response Answer the following multiple choice questions on the scantron sheet. Answer the numerical response
More informationINNOVATIVE MATERIALS FOR RESEARCH AND INDUSTRY. Elena-Oana CROITORU 1
INNOVATIVE MATERIALS FOR RESEARCH AND INDUSTRY Elena-Oana CROITORU 1 ABSTRACT Research, development and implementation of products and innovative technologies that aim to reduce or eliminate the use and
More informationLecture 12: Electroanalytical Chemistry (I)
Lecture 12: Electroanalytical Chemistry (I) 1 Electrochemistry Electrochemical processes are oxidation-reduction reactions in which: Chemical energy of a spontaneous reaction is converted to electricity
More informationCHEMISTRY Scientific Inquiry
Chemistry Overview The standards for chemistry establish scientific inquiry skills and core content for all chemistry courses in South Carolina schools. In chemistry, students acquire a fundamental knowledge
More informationElectrochemistry. The study of the interchange of chemical and electrical energy.
Electrochemistry The study of the interchange of chemical and electrical energy. Oxidation-reduction (redox) reaction: involves a transfer of electrons from the reducing agent to the oxidizing agent. oxidation:
More informationAP Questions: Electrochemistry
AP Questions: Electrochemistry I 2 + 2 S 2O 2-3 2 I - + S 4O 2-6 How many moles of I 2 was produced during the electrolysis? The hydrogen gas produced at the cathode during the electrolysis was collected
More informationGeneral and Inorganic Chemistry Made Easy
General and Inorganic Chemistry Made Easy J. Nentwig M. Kreuder K. Morgenstern VCH Contents How to use this book XIII Program 1 1 Introducüon. Chemistry as a natural science - chemical and physical processes
More informationComprehensive Handbook of Calorimetry and Thermal Analysis
Comprehensive Handbook of Calorimetry and Thermal Analysis Michio Sorai Editor-in-Chief The Japan Society of Calorimetry and Thermal Analysis John Wiley & Sons, Ltd Contents Preface xi Acknowledgements
More informationFernando O. Raineri. Office Hours: MWF 9:30-10:30 AM Room 519 Tue. 3:00-5:00 CLC (lobby).
Fernando O. Raineri Office Hours: MWF 9:30-10:30 AM Room 519 Tue. 3:00-5:00 CLC (lobby). P1) What is the reduction potential of the hydrogen electrode g bar H O aq Pt(s) H,1 2 3 when the aqueous solution
More informationAnalytical Topics to Consider in preparation for the MFAT/GRE
Analytical Topics to Consider in preparation for the MFAT/GRE 1. Solutions and Measurement: (CHEM 222) Describe the steps in a chemical analysis Know the meaning and use of the following solution concentrations.
More informationBIG IDEAS. Reaction Kinetics Reactants must collide to react. Conditions surrounding a reaction determine its rate.
Area of Learning: SCIENCE Chemistry Grade 12 Ministry of Education BIG IDEAS Dynamic Equilibrium Solubility Equilibrium Acids and Bases Oxidation-Reduction Some chemical reactions are reversible and proceed
More informationCurrent based methods
Current based methods Amperometric and voltammetric sensors More significant influence on analytical parameters (sensitivity, selectivity, interferences elimination) kind of method, potential range, electrode
More informationContents. Foreword by Darrell H. Reneker
Table of Foreword by Darrell H. Reneker Preface page xi xiii 1 Introduction 1 1.1 How big is a nanometer? 1 1.2 What is nanotechnology? 1 1.3 Historical development of nanotechnology 2 1.4 Classification
More informationELECTROCHEMISTRY. Chapter INTRODUCTION
Chapter 2 ELECTROCHEMISTRY 2.1 INTRODUCTION The goal of this chapter is to elucidate the fundamental characteristics and technological significance of electrochemical cells. A comprehensive review on the
More informationCHEMISTRY 12 COURSE OUTLINE
Abbotsford Traditional Secondary School CHEMISTRY 12 COURSE OUTLINE 2013-2014 Teacher E-mail: Website: Room: Required Materials: Mr. Macphail andrew_macphail@sd34.bc.ca http://start.sd34.bc.ca/amacphail
More informationChap. 4 AQUEOUS RXNS. O H δ+ 4.1 WATER AS A SOLVENT 4.2 AQUEOUS IONIC REACTIONS. Page 4-1. NaOH(aq) + HCl(g) NaCl(aq) +H 2 O
Chap. AQUEOUS RXNS.1 WATER AS A SOLVENT Describe solution composition in terms of molarity Describe strong and weak electrolyte solutions, including acids and bases Use ionic equations to describe neutralization
More informationConstruction and Application of Electrolytic Cell for Iodine Determination
Construction and Application of Electrolytic Cell for Iodine Determination Nasrullah Shah *1, Muhammad Bilal Arian 1, Wajid Ali Khan 1 1 Department of Chemistry, Abdul Wali Khan University Mardan, Pakistan
More informationCHEMISTRY 12 SYLLABUS
CHEMISTRY 12 SYLLABUS Online 2013 Mrs. Lockwood Email: klockwood@sd43.bc.ca District: http://www.sd43.bc.ca/col/10-12/courses/pages/courselist.aspx RATIONALE: Chemistry is the science, which deals with
More informationUnit C1: Chemistry in our world Page 1 of 5
Unit C1: Chemistry in our world Page 1 of 5 Lesson Specification learning outcomes Edexcel 360 Science Specification match Edexcel 360 Science GCSE Science Students Book page reference Additional information
More informationS4 CHEMISTRY SUMMARY NOTES
S4 CHEMISTRY SUMMARY NOTES 1. The Mole One mole of a substance = GRAM FORMULA MASS e.g. H 2 SO 4 RAM from databook pg.7 2H 2 x 1 = 2 1S 1 x 32 = 32 4O 4 x 16 = 64 98g Mass = number of moles x Mass of 1
More informationCHAPTER 5 REVIEW. C. CO 2 D. Fe 2 O 3. A. Fe B. CO
CHAPTER 5 REVIEW 1. The following represents the process used to produce iron from iron III oxide: Fe 2 O 3 + 3CO 2Fe + 3CO 2 What is the reducing agent in this process? A. Fe B. CO C. CO 2 D. Fe 2 O 3
More informationProgramme of Assessment: Physical Science NCS Gr 10/2014
Programme of Assessment: Physical Science NCS Gr 10/2014 Task Date Scope SBA task: Chemistry 30/01/2014 Heating and cooling curve of water Informal class test 1 07/02/2014 States of matter, Atomic structure,
More informationYEAR 10- Chemistry Term 1 plan
YEAR 10- Chemistry Term 1 plan 2016-2017 Week Topic Learning outcomes 1 1. The particulate nature of matter State the distinguishing properties of solids, liquids and gases. Describe the structure of solids,
More informationBOROUGH OF MANHATTAN COMMUNITY COLLEGE City University of New York Department of Science
on the specific course section and instructor. Different sections of the same course may require different Web Page. Modifications of the grading system presented here will be communicated by the instructors
More informationThe Nature of Redox. Both oxidation and reduction processes occur together. Each half of the full redox reaction is a. Oxidizing and Reducing Agents
V. ELECTROCHEMISTRY V.1 INTRODUCTION TO OXIDATION AND REDUCTION Key Question: How are electrons gained or lost? ELECTROCHEMISTRY is the study of oxidation and reduction reactions in which chemical species
More informationCHAPTER-5 CYCLIC VOLTAMETRIC STUDIES OF NOVEL INDOLE ANALOGUES PREPARED IN THE PRESENT STUDY
CHAPTER-5 CYCLIC VOLTAMETRIC STUDIES OF NOVEL INDOLE ANALOGUES PREPARED IN THE PRESENT STUDY Page No. 175-187 5.1 Introduction 5.2 Theoretical 5.3 Experimental 5.4 References 5. 1 Introduction Electrochemical
More information