Supporting Information. Crystal surface mediated structure transformation of kinetic framework. composed of multi-interactive ligand TPHAP and Co(II)

Size: px
Start display at page:

Download "Supporting Information. Crystal surface mediated structure transformation of kinetic framework. composed of multi-interactive ligand TPHAP and Co(II)"

Transcription

1 Supporting Information Crystal surface mediated structure transformation of kinetic framework composed of multi-interactive ligand TPHAP and Co(II) Yumi Yakiyama, Akira Ueda, Yasushi Morita,* Masaki Kawano* Contents of Supplementary Information: 1. Methods Synthesis of K + TPHAP Syntheses of TPHAP-Co Kin, TPHAP-Co Therm -1 and TPHAP-Co- Therm -2 X-ray crystallographic data S2 S2 S3 2. Figures S1 S11 Fig. S1 ORTEP view of K + TPHAP CH 3 OH S5 Fig. S2 The N HO type hydrogen bonding interactions in a pore of TPHAP-Co Kin S5 Fig. S3 The N HO type hydrogen bonding interactions in a pore of TPHAP-Co Therm -1 S6 Fig. S4 AFM images of the surface of single crystal Co-TPHAP Kin S6 Fig. S5 The bond lengths of HAP skeletons in TPHAP-Co Kin crystal S7 Fig. S6 The bond lengths of HAP skeletons in two thermodynamically more stable crystals S7 Fig. S7 IR spectrum of K + TPHAP S8 Fig. S8 The face index of TPHAP-Co Kin crystal and the model picture S8 Fig. S9 The crystal structure of TPHAP-Co Therm -2 S9 Fig. S10 Temperature-dependent X-ray diffraction pattern change of TPHAP-Co Therm -1 S9 Fig. S11 The simulated void spaces of TPHAP-Co systems S10 Fig. S12 The CCD 2D-images of TPHAP-Co Kin crystals and the capillary pictures before and after in situ study S11 3. Reference S12 S1

2 Methods All chemicals and reagents were used as received. All reactions were performed at ambient temperature in air. UV/vis spectra were recorded on a Shimadzu UV/Vis-NIR scanning spectrophotometer UV-3600 PC using methanol solution (1.0 x 10 5 M). IR spectra were recorded on a Varian 670-IR FT-IR spectrometer in KBr pellets. The diffraction data for K + TPHAP were collected on a Bruker APEX II QUAZAR instrument in house. The diffraction data for TPHAP-Co Kin, TPHAP-Co Therm -1, and TPHAP-Co Therm -2 were collected on a RIGAKU/MSC Mercury CCD X-ray diffractometer with a synchrotron radiation ( = Å) at PF-AR (NW2A beamline) of the High Energy Accelerator Research Organization (KEK). The structures were solved by direct methods (SHELXS-97) and refined by full-matrix least squares calculations on F 2 (SHELXL-97) using the SHELX-TL program package. Elemental analyses were performed at Pohang University of Science and Technology. AFM images collection of TPHAP-Co Kin crystals AFM images of TPHAP-Co Kin crystals were measured on a VEECO Dimension 3100+Nanoscope V (Version 7.0) at National Center for Nanomaterials Technology (NCNT, Korea). After shaking the crystallization tube, we immediately picked up the single crystals and casted on a Si wafer after washing with EtOH twice. The images in 5 min or 10 min after shaking were also measured in the same way. Powder X-ray diffraction of TPHAP-Co crystals In situ powder X-ray diffraction of TPHAP-Co Kin crystals: Dozens of single crystals of TPHAP-Co Kin were loaded into a 0.7 mm capillary with a mother solution of the crystallization. In situ powder data were collected at 25 C on a Bruker APEX II QUAZAR instrument in house: the X-ray beam size, 100 m; scan, 360 rotation; exposure time, 180 sec. The 2D diffraction images were integrated with the FIT2D program to generate 1D powder diffraction data S1 If a mother solution of the crystallization for TPHAP-Co Kin was not provided enough, crystal transformation was not completed, leading to mixture of TPHAP-Co Kin and TPHAP-Co Therm -1. During diffraction measurement, a capillary was regularly shuffled by moving -axis to provide the mother solution to crystals and promote structure transformation smoothly. Temperature-dependent X-ray diffraction pattern change of TPHAP-Co Therm -1: Dozens of single crystals of TPHAP-Co Therm -1 were loaded into a 0.7 mm capillary with a mother solution of the crystallization. The crystals were collected and measured at 25 C firstly, then heated at 40 C for 12 h. The image data were collected at 25 C on a Bruker APEX II QUAZAR instrument in house: the X-ray beam size, 100 m; scan, 360 rotation; exposure time, 180 sec. The 2D diffraction images were integrated with the FIT2D program to generate 1D powder diffraction data. Synthesis of potassium 2,5,8-tri-(4 -pyridyl)-1,3,4,6,7,9-hexaazaphenalenate, K + TPHAP : 4-pyridylamidine hydrochloride (9.10 g, 57.7 mmol) and potassium tricyanomethanide (1.50 g, 11.6 mmol) were placed in a Teflon-lined stainless autoclave and heated at 200 ºC for 16 h. At this stage, a NMR yield of the product is about 62%. A 2M HCl aqueous solution was added to the reaction S2

3 mixture and washed with ethyl acetate. After removing ethyl acetate, the aqueous layer was neutralized with a 5M KOH aqueous solution. The resultant solid was collected and purified with MeOH/ethyl acetate to give the salt as brownish yellow powder (2.23 g, 43%). m.p. > 300 C; 1 H NMR: = 8.39 (d, 6H, J = 20 Hz), 8.77 (d, 6H, J = 20 Hz); 13 C NMR: = 10.76, , , , , ; UV/Vis (methanol): max = 326 nm; elemental analysis calcd (%) for C 23 H 17.2 N 9 O 1.6 K (=C 22 H 12 N 9 K(CH 3 OH)(H 2 O) 0.6 ): C, 57.04; H, 3.58; N, Found: C, 56.66; H, 3.40; N, Synthesis of Co II network of [Co(TPHAP ) 2 (CH 3 OH) 2 (H 2 O)] 3C 6 H 5 NO 2 HNO 3 5H 2 O (TPHAP-Co Kin ): The single crystals were grown from a double-layered solution consisting of a methanol solution of Co(NO 3 ) 2 6H 2 O (131.5 mm) as the top layer, and a nitrobenzene/methanol solution (volume ratio: nitrobenzene:methanol = 7:1) of K + TPHAP (12.8 mm) as the bottom layer at 14 C. After 1 day, pale red crystals were grown. As keeping more than 2 days or giving a shock can cause the transformation to TPHAP-Co Therm -1, all crystals are collected at this moment. The isolated yield was 21% yield (based on the amount of K + TPHAP ). This low yield comes from the high reactivity of TPHAP-Co Kin. Elemental analysis calcd (%) for C 64 H 60 N 22 O 17 Co(=(C 22 H 12 N 9 ) 2 (Co)(CH 3 OH) 2 (C 6 H 5 NO 2 ) 3 (HNO 3 )(H 2 O) 6 ): C, 52.35; H, 4.12; N, Found: C, 52.18; H, 3.83; N, Synthesis of single crystal of [Co(NO 3 )(TPHAP )(CH 3 OH) 2 ] CH 3 OH C 6 H 5 NO 2 2HNO 3 H 2 O (TPHAP-Co Therm -1): The single crystals of (TPHAP-Co Therm -1) were prepared by the structural transformation of a kinetic crystal of [Co(TPHAP ) 2 (CH 3 OH) 2 (H 2 O)] 3C 6 H 5 NO 2 HNO 3 5H 2 O, just leaving the crystallization tube for more than two days. The isolated yield is 31% (calculated based on the amount of K + TPHAP ). Elemental analysis calcd (%) for C 31 H 21 N 13 O 15 Co (= (C 22 H 12 N 9 )(Co)(CH 3 OH) 3 (C 6 H 5 NO 2 )(NO 3 )(HNO 3 ) 2 (H 2 O)): C, 42.09; H, 3.53; N, Found: C, 42.22; H, 3.64; N, Synthesis of single crystal of [Co(NO 3 )(TPHAP )(CH 3 OH)] CH 3 OH 2.5(C 6 H 5 NO 2 ) H 2 O (TPHAP-Co Therm -2): The single crystals were grown from a double-layered solution consisting of a methanol solution of Co(NO 3 ) 2 6H 2 O (131.5 mm) as the top layer, and a nitrobenzene/methanol solution (volume ratio: nitrobenzene:methanol = 7:1) of K + TPHAP (12.8 mm) as the bottom layer at 25 C. After 1 day, dark red crystals were grown and isolated in 3.2% yield. Elemental analysis calcd (%) for C 64 H 60 N 22 O 17 Co(=(C 22 H 12 N 9 )(Co)(CH 3 OH) 2 (C 6 H 5 NO 2 ) 2.5 (NO 3 )(H 2 O)): C, 51.80; H, 3.49; N, Found: C, 51.75; H, 3.31; N, X-ray crystallographic data for K + TPHAP : C 23 H 16 KN 9 O, Mr = , crystal dimensions mm 3, tetragonal, space group P4 2 /n, a = (2), b = (2), c = 9.635(1) Å, V = (6) Å 3, Z = 8, calcd = g cm 3, = 2.94 cm 1, T = 173 C, 6324 unique reflections out of 8203 with I > 2 (I), 359 parameters, 1.38 < < o, final R factors R 1 = and wr 2 = , GOF = S3

4 X-ray Crystallographic data for [Co(TPHAP ) 2 (CH 3 OH) 2 (H 2 O)] 3C 6 H 5 NO 2 HNO 3 5H 2 O (TPHAP-Co Kin ): C H 35 N O Co, M r = , crystal dimensions mm 3, Orthorhombic, space group Pca2 1, a = (5), b = (1), c = (4) Å, V = (2) Å 3, Z = 4, calcd = g cm 3, = 3.28 cm 1, T = 183 C, unique reflections out of with I > 2 (I), 950 parameters, 1.98 < < o, final R factors R 1 = and wr 2 = , GOF = X-ray Crystallographic data for [Co(NO 3 )(TPHAP )(CH 3 OH) 2 ] CH 3 OH C 6 H 5 NO 2 2HNO 3 H 2 O (TPHAP-Co Therm -1): C 54 H 412 N 21 O 13 Co 2, M r = , crystal dimensions mm 3, Orthorhombic, space group Pnc2, a = (3), b = (5), c = (1) Å, V = (1) Å 3, Z = 2, calcd = g cm 3, = 5.76 cm 1, T = 183 C, 9066 unique reflections out of with I > 2 (I), 481 parameters, 1.98 < < o, final R factors R 1 = and wr 2 = , GOF = X-ray Crystallographic data for [Co(NO 3 )(TPHAP )(CH 3 OH)] CH 3 OH 2.5(C 6 H 5 NO 2 ) H 2 O (TPHAP-Co Therm -2): C H 24 N O Co, M r = , crystal dimensions mm 3, monoclinic, space group P2 1 /n, a = (3), b = (3), c = (3) Å, V = (1) Å 3, Z = 4, calcd = g cm 3, = 4.96 cm 1, T = 183 C, 7919 unique reflections out of with I > 2 (I), 891 parameters, 2.45 < < o, final R factors R 1 = and wr 2 = , GOF = CCDC (K + TPHAP ), (TPHAP-Co Kin ), (TPHAP-Co Therm -1) and (TPHAP-Co Therm -2) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via S4

5 Fig. S1 ORTEP view of K + TPHAP CH 3 OH at 50% probability. A methanol molecule is coordinating K + as a crystal solvent. C, H: white, N: blue, O: red, K: purple. Fig. S2 The N HO type hydrogen bonding interactions in a pore of TPHAP-Co Kin. distances are Å (green), Å (blue), (red) Å, (pink) Å, (orange) Å. The N O S5

6 Fig. S3 The N HO type hydrogen bonding interactions in a pore of TPHAP-Co Therm -1. The N O distances are Å (red), Å (sky blue). Fig. S4 AFM images of the surface of single crystal Co-TPHAP Kin : a) immediately after shaking the crystallization tube, b) after 5 min, c) after 10 min. Scan area 10 m 10 m. S6

7 Fig. S5 The bond lengths of HAP skeletons in TPHAP-Co Kin in units of Å. Bidentate TPHAP Monodentate TPHAP C6 N (4) C20 N (4) C28 N (5) C42 N (4) C6 N (4) C20 N (4) C28 N (5) C42 N (4) C12 N (4) C22 N (4) C34 N (5) C44 N (5) C12 N (4) C22 N (4) C34 N (5) C44 N (5) C18 N (4) C19 C (5) C40 N (5) C41 C (4) C18 N (4) C20 C (4) C40 N (5) C42 C (5) C19 N (4) C21 C (4) C41 N (4) C43 C (5) C19 N (4) C41 N (5) Fig. S6 Å. The bond lengths of HAP skeletons in TPHAP-Co Themo -1 and TPHAP-Co Themo -2 in units of TPHAP-Co Themo -1 TPHAP-Co Themo -2 C6 N (4) C20 N (4) C6 N (4) C20 N (3) C6 N (4) C20 N (4) C6 N (3) C20 N (3) C12 N (4) C22 N (4) C12 N (3) C22 N (3) C12 N (4) C22 N (3) C12 N (3) C22 N (3) C18 N (4) C19 C (4) C18 N (3) C19 C (3) C18 N (4) C20 C (4) C18 N (3) C20 C (4) C19 N (4) C21 C (4) C19 N (3) C21 C (3) C19 N (3) C19 N (4) S7

8 Fig. S7 IR spectrum of K + TPHAP. C=N stretching vibration is observed at 1593 cm 1. Fig. S8 The face index of TPHAP-Co Kin crystal and the model picture of the crystal clipping by (0 1 2) (blue) and (0 1 1) (red) plane. S8

9 Fig. S9. The crystal structure of TPHAP-Co Therm -2. a) From a axis with H-bonding interactions. N O distances are Å (black broken line). b) From c axis. Fig. S10. Temperature dependent X-ray diffraction change of TPHAP-Co Therm -1. The powder plots were obtained by integration of CCD 2D-image data. Simulated powder diffraction: dotted line, TPHAP-Co Therm -1; dashed line, TPHAP-Co Therm -2. S9

10 Fig. S11. The simulated void spaces of TPHAP-Co systems using contact surface calculated on Mercury 3.0. TPHAP-Co Kim, 43.0% ( Å 3 ), cavity dimension: 7.4 Å 10.3 Å; TPHAP-Co Therm -1, 30.0% ( Å 3 ), cavity dimension: 4.9 Å 7.4 Å; TPHAP-Co Therm -2, 47.8% ( Å 3 ), cavity dimension: 11.3 Å 2.4 Å. Probe size: 1.2 Å. S10

11 Electronic Supplementary Material (ESI) for Chemical Communications Fig. S12. The CCD 2D-images of TPHAP-CoKin crystals and the capillary pictures before and after in situ study. S11

12 Reference S1) A. P. Hammersley, FIT2D V Reference manual V6.0, Proceedings of the ESRF International Report No. ESRF98HA01T, ESRF, Grenoble, S12

Supplementary Information. Crystallinity-dependent enhancement of ionic conductivity on multi-interactive molecular materials

Supplementary Information. Crystallinity-dependent enhancement of ionic conductivity on multi-interactive molecular materials Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supplementary Information Crystallinity-dependent enhancement of ionic conductivity on multi-interactive

More information

Electronic Supplementary Information. Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts

Electronic Supplementary Information. Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts Electronic Supplementary Information Pd(diimine)Cl 2 Embedded Heterometallic Compounds with Porous Structures as Efficient Heterogeneous Catalysts Sheng-Li Huang, Ai-Quan Jia and Guo-Xin Jin* Experimental

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Anion-induced Ag I self-assemblies with electron

More information

All materials and reagents were obtained commercially and used without further

All materials and reagents were obtained commercially and used without further Reversible shrinkage and expansion of a blue photofluorescene cadmium coordination polymer and in situ tetrazole ligand synthesis Hong Deng,* a Yong-Cai Qiu, a Ying-Hua Li, a Zhi-Hui liu, a Rong-Hua Zeng,

More information

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Information (ESI) S1 Experimental Section: Materials and methods: All commercially available chemicals were used as supplied without further purification. The Q[5] was synthesized

More information

Selective total encapsulation of the sulfate anion by neutral nano-jars

Selective total encapsulation of the sulfate anion by neutral nano-jars Supporting Information for Selective total encapsulation of the sulfate anion by neutral nano-jars Isurika R. Fernando, Stuart A. Surmann, Alexander A. Urech, Alexander M. Poulsen and Gellert Mezei* Department

More information

Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster

Rare double spin canting antiferromagnetic behaviours in a. [Co 24 ] cluster Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Rare double spin canting antiferromagnetic behaviours in a [Co 24 ] cluster Guang-Ming Liang, Qing-Ling

More information

An unprecedented 2D 3D metal-organic polyrotaxane. framework constructed from cadmium and flexible star-like

An unprecedented 2D 3D metal-organic polyrotaxane. framework constructed from cadmium and flexible star-like Electronic Supplementary Information An unprecedented 2D 3D metal-organic polyrotaxane framework constructed from cadmium and flexible star-like ligand Hua Wu, a,b Hai-Yan Liu, a Ying-Ying Liu, a Jin Yang,*

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 A rare case of a dye co-crystal showing better dyeing performance Hui-Fen Qian, Yin-Ge Wang,

More information

A Sumanene-based Aryne, Sumanyne

A Sumanene-based Aryne, Sumanyne A Sumanene-based Aryne, Sumanyne Niti Ngamsomprasert, Yumi Yakiyama, and Hidehiro Sakurai* Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871

More information

Selective gas and vapor sorption and magnetic sensing by an. isoreticular mixed-metal-organic framework

Selective gas and vapor sorption and magnetic sensing by an. isoreticular mixed-metal-organic framework Supporting Information (SI) for the manuscript: Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework Jesús Ferrando-Soria, Pablo Serra-Crespo, Martijn

More information

Supplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient

Supplementary Material (ESI) for CrystEngComm. An ideal metal-organic rhombic dodecahedron for highly efficient Supplementary Material (ESI) for CrystEngComm An ideal metal-organic rhombic dodecahedron for highly efficient adsorption of dyes in an aqueous solution Yuan-Chun He, Jin Yang,* Wei-Qiu Kan, and Jian-Fang

More information

Reversible dioxygen binding on asymmetric dinuclear rhodium centres

Reversible dioxygen binding on asymmetric dinuclear rhodium centres Electronic Supporting Information for Reversible dioxygen binding on asymmetric dinuclear rhodium centres Takayuki Nakajima,* Miyuki Sakamoto, Sachi Kurai, Bunsho Kure, Tomoaki Tanase* Department of Chemistry,

More information

Supporting Information. Integration of accessible secondary metal sites into MOFs for H 2 S removal

Supporting Information. Integration of accessible secondary metal sites into MOFs for H 2 S removal Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers. This journal is the Partner Organisations 2014 Supporting Information Integration of accessible secondary metal sites into MOFs

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Single-Crystal-to-Single-Crystal Transformation of an Anion Exchangeable

More information

Prabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra*

Prabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra* Supporting Information Ferrocenyl BODIPYs: Synthesis, Structure and Properties Prabhat Gautam, Bhausaheb Dhokale, Shaikh M. Mobin and Rajneesh Misra* Department of Chemistry, Indian Institute of Technology

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Supporting Information Significant enhancement of conductance for a hybrid layered molybdate semiconductor

More information

Supporting Information

Supporting Information Supporting Information Manuscript Title: Synthesis of Semibullvalene Derivatives via Co 2 (CO) 8 -Mediated Cyclodimerization of 1,4-Dilithio-1,3-butadienes Corresponding Author: Zhenfeng Xi Affiliations:

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information Thermally Reversible Single-Crystal to Single-Crystal Transformation of Mononuclear to Dinuclear Zn(II) Complexes By[2+2] Cycloaddition Reaction Raghavender Medishetty,

More information

Supplemental Information. Point-of-Use Detection of Amphetamine-Type. Stimulants with Host-Molecule-Functionalized. Organic Transistors

Supplemental Information. Point-of-Use Detection of Amphetamine-Type. Stimulants with Host-Molecule-Functionalized. Organic Transistors Chem, Volume 3 Supplemental Information Point-of-Use Detection of Amphetamine-Type Stimulants with Host-Molecule-Functionalized Organic Transistors Yoonjung Jang, Moonjeong Jang, Hyoeun Kim, Sang Jin Lee,

More information

in a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)]

in a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)] Supporting Information Stepwise and Hysteretic Sorption N 2, O 2, CO 2, and H 2 Gases in a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)] Hye Jeong Park and Myunghyun Paik Suh Contribution from

More information

Synthesis of Vinyl Germylenes

Synthesis of Vinyl Germylenes Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Material for Synthesis of Vinyl Germylenes Małgorzata Walewska, Judith Baumgartner,*

More information

Supporting Information

Supporting Information Supporting Information Wiley-VCH 2007 69451 Weinheim, Germany Crystal-to-Crystal Transformation between Three Cu(I) Coordination Polymers and Structural Evidence for Luminescence Thermochromism Tae Ho

More information

1G (bottom) with the phase-transition temperatures in C and associated enthalpy changes (in

1G (bottom) with the phase-transition temperatures in C and associated enthalpy changes (in Supplementary Figure 1. Optical properties of 1 in various solvents. UV/Vis (left axis) and fluorescence spectra (right axis, ex = 420 nm) of 1 in hexane (blue lines), toluene (green lines), THF (yellow

More information

Benzene Absorption in a Protuberant-Grid-Type Zinc(II) Organic Framework Triggered by the Migration of Guest Water Molecules

Benzene Absorption in a Protuberant-Grid-Type Zinc(II) Organic Framework Triggered by the Migration of Guest Water Molecules Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Benzene Absorption in a Protuberant-Grid-Type Zinc(II)

More information

Total Synthesis of Gonytolides C and G, Lachnone C, and. Formal Synthesis of Blennolide C and Diversonol

Total Synthesis of Gonytolides C and G, Lachnone C, and. Formal Synthesis of Blennolide C and Diversonol . This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry Total Synthesis of Gonytolides C and G, Lachnone C, and Formal Synthesis

More information

Department of Chemistry, Tianjin University, Tianjin , P. R. China Tel:

Department of Chemistry, Tianjin University, Tianjin , P. R. China   Tel: Electronic Supplementary Information Analysis of factors governing the formation of single-stranded helical coordination polymers from a macrocyclic metalloligand and Ca 2+, Mn 2+, Fe 2+, Co 2+, Ni 2+,

More information

Supporting Information

Supporting Information Supporting Information Highly Selective Carbon Dioxide Sorption in an Organic Molecular Porous Material Hyunuk Kim, Yonghwi Kim, Minyoung Yoon, Soyoung Lim, Se Min Park, Gon Seo, Kimoon Kim*, National

More information

From Double-Shelled Grids to Supramolecular Frameworks

From Double-Shelled Grids to Supramolecular Frameworks Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 From Double-Shelled Grids to Supramolecular Frameworks Jianfeng Wu, Mei Guo, Xiao-Lei Li, Lang

More information

White Phosphorus is Air-Stable Within a Self-Assembled Tetrahedral Capsule

White Phosphorus is Air-Stable Within a Self-Assembled Tetrahedral Capsule www.sciencemag.org/cgi/content/full/324/5935/1697/dc1 Supporting Online Material for White Phosphorus is Air-Stable Within a Self-Assembled Tetrahedral Capsule Prasenjit Mal, Boris Breiner, Kari Rissanen,

More information

1. General Experiments... S2. 2. Synthesis and Experiments... S2 S3. 3. X-Ray Crystal Structures... S4 S8

1. General Experiments... S2. 2. Synthesis and Experiments... S2 S3. 3. X-Ray Crystal Structures... S4 S8 Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Gate-Opening upon CO 2 Adsorption on a Metal Organic

More information

Hydrogen Bonded Dimer Stacking Induced Emission of Amino-Benzoic Acid Compounds

Hydrogen Bonded Dimer Stacking Induced Emission of Amino-Benzoic Acid Compounds Electronic Supplementary Information (ESI) Hydrogen Bonded Dimer Stacking Induced Emission of Amino-Benzoic Acid Compounds Tianlei Zhou, Feng Li, Yan Fan, Weifeng Song, Xiaoyue Mu, Hongyu Zhang* and Yue

More information

Magnetic Metal-Organic Framework Exhibiting Quick and. Selective Solvatochromic Behavior Along With The Reversible

Magnetic Metal-Organic Framework Exhibiting Quick and. Selective Solvatochromic Behavior Along With The Reversible Magnetic Metal-Organic Framework Exhibiting Quick and Selective Solvatochromic Behavior Along With The Reversible Crystal-to-Amorphous-to-Crystal Transformation Peng Hu,, Lei Yin,, Angelo Kirchon,, Jiangli

More information

Supporting Information. Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, and Ming-Liang Tong*

Supporting Information. Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, and Ming-Liang Tong* Supporting Information Wheel-shaped nanoscale 3d-4f {Co II 16Ln III 24} clusters (Ln = Dy and Gd) Ze-Min Zhang, Lu-Yi Pan, Wei-Quan Lin, Ji-Dong Leng, Fu-Sheng Guo, Yan-Cong Chen, Jun-Liang Liu, and Ming-Liang

More information

Supporting Information. Product control by halide ions of ionic liquids in the ionothermal syntheses. of Ni-(H)BTC metal-organic frameworks

Supporting Information. Product control by halide ions of ionic liquids in the ionothermal syntheses. of Ni-(H)BTC metal-organic frameworks Supporting Information Product control by halide ions of ionic liquids in the ionothermal syntheses of Ni-(H)BTC metal-organic frameworks Ling Xu, a Shihai Yan, a Eun-Young Choi, a Jin Yong Lee, a and

More information

Redox-Responsive Complexation between a. Pillar[5]arene with Mono ethylene oxide Substituents. and Paraquat

Redox-Responsive Complexation between a. Pillar[5]arene with Mono ethylene oxide Substituents. and Paraquat Redox-Responsive Complexation between a Pillar[5]arene with Mono ethylene oxide Substituents and Paraquat Xiaodong Chi, Min Xue, Yong Yao and Feihe Huang* MOE Key Laboratory of Macromolecular Synthesis

More information

[Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents

[Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents [Ag-Ag] 2+ Unit-Encapsulated Trimetallic Cages: One-pot Syntheses and Modulation of Argentophilic Interactions by the Uncoordinated Substituents Guo-Xia Jin,,a Gui-Ying Zhu,,a Yan-Yan Sun, c Qing-Xiu Shi,

More information

Manganese-Calcium Clusters Supported by Calixarenes

Manganese-Calcium Clusters Supported by Calixarenes Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2014 Manganese-Calcium Clusters Supported by Calixarenes Rebecca O. Fuller, George A. Koutsantonis*,

More information

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) Enhancing stability and porosity of penetrated

More information

Halogen halogen interactions in diiodo-xylenes

Halogen halogen interactions in diiodo-xylenes Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) for CrystEngComm. This journal is The Royal Society

More information

Cu(I)-MOF: naked-eye colorimetric sensor for humidity and. formaldehyde in single-crystal-to-single-crystal fashion

Cu(I)-MOF: naked-eye colorimetric sensor for humidity and. formaldehyde in single-crystal-to-single-crystal fashion Supporting Information for Cu(I)-MOF: naked-eye colorimetric sensor for humidity and formaldehyde in single-crystal-to-single-crystal fashion Yang Yu, Xiao-Meng Zhang, Jian-Ping Ma, Qi-Kui Liu, Peng Wang,

More information

Spin Transition and Structural Transformation in a

Spin Transition and Structural Transformation in a Supporting Information for Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex Ying Guo, Xiu-Long Yang, Rong-Jia Wei, Lan-Sun Zheng, and Jun Tao* State Key Laboratory of Physical

More information

Supplemental Information

Supplemental Information Supplemental Information Template-controlled Face-to-Face Stacking of Olefinic and Aromatic Carboxylic Acids in the Solid State Xuefeng Mei, Shuanglong Liu and Christian Wolf* Department of Chemistry,

More information

Synthesis of Tetra-ortho-Substituted, Phosphorus- Containing and Carbonyl-Containing Biaryls Utilizing a Diels-Alder Approach

Synthesis of Tetra-ortho-Substituted, Phosphorus- Containing and Carbonyl-Containing Biaryls Utilizing a Diels-Alder Approach Synthesis of Tetra-ortho-Substituted, Phosphorus- Containing and Carbonyl-Containing Biaryls Utilizing a Diels-Alder Approach Bradley O. Ashburn and Rich G. Carter* and Lev N. Zakharov Department of Chemistry,

More information

Supplementary Information

Supplementary Information Supplementary Information Tuning the Luminescence of Metal-Organic Frameworks for Detection of Energetic Heterocyclic Compounds Yuexin Guo, Xiao Feng,*, Tianyu Han, Shan Wang, Zhengguo Lin, Yuping Dong,

More information

Dynamics of Caged Imidazolium Cation Toward Understanding The Order-Disorder Phase Transition and Switchable Dielectric Constant

Dynamics of Caged Imidazolium Cation Toward Understanding The Order-Disorder Phase Transition and Switchable Dielectric Constant Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electonic Supporting Information Dynamics of Caged Imidazolium Cation Toward Understanding

More information

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information (ESI) A Large Spin, Magnetically Anisotropic, Octanuclear

More information

Supporting Information

Supporting Information Supporting Information New Hexaphosphane Ligands 1,3,5-C 6 H 3 {p-c 6 H 4 N(PX 2 ) 2 } 3 [X = Cl, F, C 6 H 3 OMe(C 3 H 5 )]: Synthesis, Derivatization and, Palladium(II) and Platinum(II) Complexes Sowmya

More information

SUPPLEMENTARY INFORMATION

SUPPLEMENTARY INFORMATION SUPPLEMENTARY INFORMATION Selective Sorption of Oxygen and Nitric Oxide by an Electron-Donating Flexible Porous Coordination Polymer Satoru Shimomura, 1 Masakazu Higuchi, 2 Ryotaro Matsuda, 3,4 Ko Yoneda,

More information

Supporting Information

Supporting Information Supporting Information Three-dimensional frameworks of cubic (NH 4 ) 5 Ga 4 SbS 10, (NH 4 ) 4 Ga 4 SbS 9 (OH) H 2 O, and (NH 4 ) 3 Ga 4 SbS 9 (OH 2 ) 2H 2 O. Joshua L. Mertz, Nan Ding, and Mercouri G.

More information

A water-stable zwitterionic dysprosium carboxylate metal organic. framework: a sensing platform for Ebolavirus RNA sequences

A water-stable zwitterionic dysprosium carboxylate metal organic. framework: a sensing platform for Ebolavirus RNA sequences Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 A water-stable zwitterionic dysprosium carboxylate metal organic framework: a sensing platform

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supporting Information Sulfonato-imino copper(ii) complexes : fast and general Chan-

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supporting Information Rare metal-ion metathesis of tetrahedral Zn(II) core of a noncentrosymmetric

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information One 1D anionic coordination polymer showing

More information

Efficient, scalable and solvent-free mechanochemical synthesis of the OLED material Alq 3 (q = 8-hydroxyquinolinate) Supporting Information

Efficient, scalable and solvent-free mechanochemical synthesis of the OLED material Alq 3 (q = 8-hydroxyquinolinate) Supporting Information Efficient, scalable and solvent-free mechanochemical synthesis of the OLED material Alq 3 (q = 8-hydroxyquinolinate) Xiaohe Ma, Gin Keat Lim, Kenneth D.M. Harris, David C. Apperley, Peter N. Horton, Michael

More information

Reversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether

Reversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether Supplementary Information Reversible uptake of HgCl 2 in a porous coordination polymer based on the dual functions of carboxylate and thioether Xiao-Ping Zhou, a Zhengtao Xu,*,a Matthias Zeller, b Allen

More information

Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties

Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties Supporting Information Microporous Manganese Formate: A Simple Metal-Organic Porous Material with High Framework Stability and Highly Selective Gas Sorption Properties Danil N. Dybtsev, Hyungphil Chun,

More information

High-Connected Mesoporous Metal Organic Framework

High-Connected Mesoporous Metal Organic Framework Supporting Information High-Connected Mesoporous Metal Organic Framework Xiaojun Gu, a Zhang-Hui Lu a,b and Qiang Xu* a,b a National Institute of Advanced Industrial Science and Technology (AIST), Ikeda,

More information

Supporting Information. Table of Contents

Supporting Information. Table of Contents Supporting Information Selective Anion Exchange and Tunable Luminescent Behaviors of Metal-Organic Framework Based Supramolecular Isomers Biplab Manna, Shweta Singh, Avishek Karmakar, Aamod V.Desai and

More information

A Mixed Crystal Lanthanide Zeolite-like Metal-Organic. Framework as a Fluorescent Indicator for Lysophosphatidic. Acid, a Cancer Biomarker

A Mixed Crystal Lanthanide Zeolite-like Metal-Organic. Framework as a Fluorescent Indicator for Lysophosphatidic. Acid, a Cancer Biomarker Supporting Information for A Mixed Crystal Lanthanide Zeolite-like Metal-Organic Framework as a Fluorescent Indicator for Lysophosphatidic Acid, a Cancer Biomarker Shi- Yuan Zhang,, Wei Shi, *, Peng Cheng,

More information

Supplementary Information

Supplementary Information Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supplementary Information A Novel Single-Side Azobenzene-Grafted Anderson-Type Polyoxometalate

More information

Electronic Supporting Information

Electronic Supporting Information Electronic Supporting Information Solid-State Coexistence of {Zr 12 } and {Zr 6 } Zirconium Oxocarboxylate Clusters Iurie L. Malaestean, Meliha Kutluca Alıcı, Claire Besson, Arkady Ellern and Paul Kögerler*

More information

Electronic supplementary information (ESI)

Electronic supplementary information (ESI) Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information (ESI) Two novel organic phosphorous-based MOFs:

More information

Supporting Information

Supporting Information Supporting Information Unprecedented solvent-dependent sensitivities in highly efficient detection of metal ions and nitroaromatic compounds by a fluorescent Ba MOF Rongming Wang, Xiaobin Liu, Ao Huang,

More information

Supporting Information

Supporting Information Supporting Information Activation of Ene-Diamido Samarium Methoxide with Hydrosilane for Selectively Catalytic Hydrosilylation of Alkenes and Polymerization of Styrene: an Experimental and Theoretical

More information

the multiple helices

the multiple helices Supporting Information A 3D porous metal-organic framework containing nanotubes based on the multiple helices Lei Hou,* Li-Na Jia, Wen-Juan Shi, Li-Yun Du, Jiang Li, Yao-Yu Wang* and Qi-Zhen Shi Key Laboratory

More information

Intensely luminescent gold(i) phosphinopyridyl clusters: visualization of unsupported aurophilic interactions in solution

Intensely luminescent gold(i) phosphinopyridyl clusters: visualization of unsupported aurophilic interactions in solution Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2017 Supplementary Information Intensely luminescent gold(i) phosphinopyridyl clusters:

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting Information A cage-based cationic body-centered tetragonal metal-organic framework:

More information

Supporting Information

Supporting Information Supporting Information A Sn IV -Porphyrin-Based Metal-Organic Framework for the Selective Photo-Oxygenation of Phenol and Sulfides Ming-Hua Xie, Xiu-Li Yang, Chao Zou and Chuan-De Wu* Department of Chemistry,

More information

Supporting Information for the Article Entitled

Supporting Information for the Article Entitled Supporting Information for the Article Entitled Catalytic Production of Isothiocyanates via a Mo(II) / Mo(IV) Cycle for the Soft Sulfur Oxidation of Isonitriles authored by Wesley S. Farrell, Peter Y.

More information

Supporting Information Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure

Supporting Information Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure Supporting Information Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure Thais Grancha, Marta Mon, Francesc Lloret, Jesús Ferrando-Soria,* Yves Journaux, Jorge Pasán,

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 205 Supporting Information Synthesis and Structures of N-Arylcyano-β-diketiminate Zinc Complexes

More information

Supporting Information

Supporting Information Supporting Information Selective Metal Cation Capture by Soft Anionic Metal-Organic Frameworks via Drastic Single-crystal-to-single-crystal Transformations Jian Tian, Laxmikant V. Saraf, Birgit Schwenzer,

More information

Supporting Information for

Supporting Information for Supporting Information for Nickel(I)-mediated transformations of carbon dioxide in closed synthetic cycles: reductive cleavage and coupling of CO 2 generating Ni I CO, Ni II CO 3 and Ni II C 2 O 4 Ni II

More information

Supplementary Information

Supplementary Information Supplementary Information Eco-Friendly Synthesis of 2,3-Dihydroquinazolin-4(1H)-ones Catalyzed by FeCl 3 /Al 2 O 3 and Analysis of Large 1 H NMR Diastereotopic Effect Isabel Monreal, a Mariano Sánchez-Castellanos,

More information

College of Materials Science and Engineering, Nanjing Tech University, Nanjing , P. R. China

College of Materials Science and Engineering, Nanjing Tech University, Nanjing , P. R. China Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Extra thermostable one-dimensional organic-inorganic hybrid perovskite [N-methyldabconium]PbI 3

More information

Iron Complexes of a Bidentate Picolyl NHC Ligand: Synthesis, Structure and Reactivity

Iron Complexes of a Bidentate Picolyl NHC Ligand: Synthesis, Structure and Reactivity Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supplementary Information for Iron Complexes of a Bidentate Picolyl HC Ligand: Synthesis,

More information

Supplementary data. Controlled crystallization of mixed-ligand complexes of. 1,3-bis(4-pyridyl)propane-N,N -dioxide with metal(ii) thiocyanates:

Supplementary data. Controlled crystallization of mixed-ligand complexes of. 1,3-bis(4-pyridyl)propane-N,N -dioxide with metal(ii) thiocyanates: Supplementary data Controlled crystallization of mixed-ligand complexes of 1,3-bis(4-pyridyl)propane-N,N -dioxide with metal(ii) thiocyanates: isostructurality in coordination networks bearing different

More information

Magnetic Ordering in TCNQ-Based Metal-Organic Frameworks With Host-Guest Interactions

Magnetic Ordering in TCNQ-Based Metal-Organic Frameworks With Host-Guest Interactions Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers. This journal is the Partner Organisations 215 Magnetic Ordering in TCNQ-Based Metal-Organic Frameworks With Host-Guest Interactions

More information

From co-crystals to functional thin films: photolithography using the [2+2] photodimerization

From co-crystals to functional thin films: photolithography using the [2+2] photodimerization From co-crystals to functional thin films: photolithography using the [2+2] photodimerization Suman Ghorai, a,b Joseph C. Sumrak, a,b Kristin M. Hutchins, a Dejan-Krešimir Bučar, a Alexei V. Tivanski,

More information

SUPPORTING INFORMATION

SUPPORTING INFORMATION Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2017 1 SUPPORTING INFORMATION Synthesis of urea derivatives via reductive carbon dioxide fixation

More information

Supporting Information

Supporting Information Supporting Information tert-butylzinc Hydroxide as Efficient Predesigned Precursor of ZnO Nanoparticles Wojciech Bury, Elżbieta Krajewska, Michał Dutkiewicz, Kamil Sokołowski, Iwona Justyniak, Zbigniew

More information

Supporting Information Reagents. Physical methods. Synthesis of ligands and nickel complexes.

Supporting Information Reagents. Physical methods. Synthesis of ligands and nickel complexes. Supporting Information for Catalytic Water Oxidation by A Bio-inspired Nickel Complex with Redox Active Ligand Dong Wang* and Charlie O. Bruner Department of Chemistry and Biochemistry and Center for Biomolecular

More information

Supporting Information for. an Equatorial Diadduct: Evidence for an Electrophilic Carbanion

Supporting Information for. an Equatorial Diadduct: Evidence for an Electrophilic Carbanion Supporting Information for Controlled Synthesis of C 70 Equatorial Multiadducts with Mixed Addends from an Equatorial Diadduct: Evidence for an Electrophilic Carbanion Shu-Hui Li, Zong-Jun Li,* Wei-Wei

More information

Supporting Information

Supporting Information Supporting Information Exploring the detection of metal ions by tailoring the coordination mode of V-shaped thienylpyridyl ligand in three MOFs Li-Juan Han,, Wei Yan, Shu-Guang Chen, Zhen-Zhen Shi, and

More information

Supplementary Information. Two Cyclotriveratrylene Metal-Organic Frameworks as Effective Catalysts

Supplementary Information. Two Cyclotriveratrylene Metal-Organic Frameworks as Effective Catalysts Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supplementary Information Two Cyclotriveratrylene Metal-Organic Frameworks as Effective

More information

Supplementary Figure S1 a, wireframe view of the crystal structure of compound 11. b, view of the pyridinium sites. c, crystal packing of compound

Supplementary Figure S1 a, wireframe view of the crystal structure of compound 11. b, view of the pyridinium sites. c, crystal packing of compound a b c Supplementary Figure S1 a, wireframe view of the crystal structure of compound 11. b, view of the pyridinium sites. c, crystal packing of compound 11. 1 a b c Supplementary Figure S2 a, wireframe

More information

Interpenetrated metal-organic frameworks of self-catenated four-connected mok nets

Interpenetrated metal-organic frameworks of self-catenated four-connected mok nets Supporting Information for Interpenetrated metal-organic frameworks of self-catenated four-connected mok nets Yun Gong a,b, Yu-Chao Zhou b, Tian-Fu Liu a, Jian Lü a, *, Davide M. Proserpio c, and Rong

More information

Supporting Information. for. Angew. Chem. Int. Ed Wiley-VCH 2004

Supporting Information. for. Angew. Chem. Int. Ed Wiley-VCH 2004 Supporting Information for Angew. Chem. Int. Ed. 246736 Wiley-VCH 24 69451 Weinheim, Germany 1 Challenges in Engineering Spin Crossover. Structures and Magnetic Properties of six Alcohol Solvates of Iron(II)

More information

Supporting Information

Supporting Information Supporting Information Distinct Mechanoresponsive Luminescence, Thermochromism, Vapochromism and Chlorine Gas Sensing by a Solid-State Organic Emitter S1 Figure S1. 1 H NMR (in CDCl 3 ) spectra of as synthesized

More information

,

, 2013. 54, 6. 1115 1120 UDC 548.737:547.12 CHARACTERIZATION AND CRYSTAL STRUCTURES OF SOLVATED N -(4-HYDROXY-3-NITROBENZYLIDENE)-3-METHYLBENZOHYDRAZIDE AND N -(4-DIMETHYLAMINOBENZYLIDENE)-3-METHYLBENZOHYDRAZIDE

More information

SUPPORTING INFORMATION

SUPPORTING INFORMATION SUPPORTING INFORMATION Table of Contents S1 1. General materials and methods S2 2. Syntheses of {Pd 84 } and {Pd 17 } S3-S4 3. MS studies of {Pd 84 }, {Pd 17 } and the two-component reactions S5-S6 4.

More information

High-Performance Semiconducting Polythiophenes for Organic Thin Film. Transistors by Beng S. Ong,* Yiliang Wu, Ping Liu and Sandra Gardner

High-Performance Semiconducting Polythiophenes for Organic Thin Film. Transistors by Beng S. Ong,* Yiliang Wu, Ping Liu and Sandra Gardner Supplementary Materials for: High-Performance Semiconducting Polythiophenes for Organic Thin Film Transistors by Beng S. Ong,* Yiliang Wu, Ping Liu and Sandra Gardner 1. Materials and Instruments. All

More information

Controllable Growth of Bulk Cubic-Phase CH 3 NH 3 PbI 3 Single Crystal with Exciting Room-Temperature Stability

Controllable Growth of Bulk Cubic-Phase CH 3 NH 3 PbI 3 Single Crystal with Exciting Room-Temperature Stability Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Controllable Growth of Bulk Cubic-Phase CH 3 NH 3 PbI

More information

Co(I)-Mediated Removal of Addends on the C60 Cage and Formation of Monovalent Cobalt Complex CpCo(CO)(η 2 -C60)

Co(I)-Mediated Removal of Addends on the C60 Cage and Formation of Monovalent Cobalt Complex CpCo(CO)(η 2 -C60) Supporting Information Co(I)-Mediated Removal of Addends on the C60 Cage and Formation of Monovalent Cobalt Complex CpCo(CO)(η 2 -C60) Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, and Yasujiro

More information

Supporting Information

Supporting Information Supporting Information Strongly Fluorescent Hydrogel as a Blue-Emitting anomaterial: An Approach toward Understanding Fluorescence-Structure Relationship Tae Ho Kim, Joobeom Seo, Soo Jin Lee, Shim Sung

More information

Electronic Supplementary Information for Sulfur, Oxygen, and Nitrogen Mustards: Stability and Reactivity

Electronic Supplementary Information for Sulfur, Oxygen, and Nitrogen Mustards: Stability and Reactivity Electronic Supplementary Information for Sulfur, Oxygen, and Nitrogen Mustards: Stability and Reactivity Contents Qi-Qiang Wang, Rowshan Ara Begum, Victor W. Day, Kristin Bowman-James* Department of Chemistry,

More information

Electronic Supplementary Information for: Gram-scale Synthesis of a Bench-Stable 5,5 -Unsubstituted Terpyrrole

Electronic Supplementary Information for: Gram-scale Synthesis of a Bench-Stable 5,5 -Unsubstituted Terpyrrole Electronic Supplementary Information for: Gram-scale Synthesis of a Bench-Stable 5,5 -Unsubstituted Terpyrrole James T. Brewster II, a Hadiqa Zafar, a Matthew McVeigh, a Christopher D. Wight, a Gonzalo

More information

Hassan Osseili, Debabrata Mukherjee, Klaus Beckerle, Thomas P. Spaniol, and Jun Okuda*

Hassan Osseili, Debabrata Mukherjee, Klaus Beckerle, Thomas P. Spaniol, and Jun Okuda* Supporting Information Me6TREN-Supported Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Synthesis, Structure, and Reactivity Hassan Osseili, Debabrata Mukherjee, Klaus Beckerle, Thomas

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Catalytic performance of Keplerate polyoxomolybdates in green epoxidation of alkenes with hydrogen

More information