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1 ICOBTE 2015 FUKUOKA ABSTRACT BOOK 13th International Conference on the Biogeochemistry of Trace Elements New Frontiers in Trace Elements Research and Management July 12-16, 2015 Fukuoka International Congress Center Fukuoka, Japan ICOBTE 2015 Secretariat: c/o ISS, INC. Mita MT Bldg. 8F, Mita, Minato-ku, Tokyo Japan
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3 Back ICOBTE 2015 FUKUOKA 089 Cadmium Removal from Saline Soil Suspension by Ti Nanoparticles S. Aryabod 1, A. Fotovat 1, R. Khorasani 1 and M.H. Entezari 2 1 Department of Soil Science, Faculty of Agriculture, Ferdowsi University of Mashhad (FUM), Iran; 4 Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad (FUM), Iran Immobilization of cadmium in contaminated soils is one of the decontamination techniques to improve soil quality. TiO 2 nanoparticles are useful additive to bind cadmium. This study examines the impact of ionic strength and index cations on Cd-DTPA in a calcareous soil. The availability of Cd in soil and nano- TiO 2 suspensions was tested as a function of ionic strength (10, 100 and 200 mm NaCl or CaCl 2) in two soil to solution ratios (1:5 and 1:20) and different amounts of nanoparticles (0, 1 and 5% w/w). From Cd-DTPA measurements, we found that nano-tio 2 increased Cd-DTPA in NaCl treatments, whereas Cd-DTPA was not influenced by nano-tio 2 in CaCl 2 treatments. For example, in soil to solution ratio of 1:20 and in 200 mm NaCl solution, the extent of Cd-DTPA increased from 3.54 to 5.56 mg kg -1 as the nanoparticle dosage was increased from 0% to 5%. In contrast, in CaCl 2 suspension adjusted to an ionic strength of 200 mm, Cd-DTPA in 5% nano-tio 2 concentration and in blank treatment (without TiO 2 nanoparticle) was 2.77 and 2.81 mg kg -1, respectively. Moreover, in all ionic strength treatments, after two weeks incubation time, soluble Cd decreased and ph increased in supernatant liquid in the presence of nano-tio 2. However, in the presence of CaCl 2 solution, adsorption of cadmium to nanoparticles was less than of NaCl suspensions. For example, in soil to solution ratio of 1:20, reduction of soluble cadmium in 5% nano-tio 2 amount in comparison to blank treatment (without nano-tio 2) in suspensions adjusted to ionic strength of 200 mm of NaCl and CaCl 2, was 47% and 8%, respectively Increase of Cd-DTPA in NaCl treatments was attributed to greater stability of nanoparticles as well as greater Cd adsorption to nano-tio 2 surfaces in Na + in comparison to Ca 2+ electrolytes. Cd-DTPA was unaffected by increasing the salt concentrations from 10 to 200 mm NaCl or CaCl 2, whereas enhance of the salt concentrations increased soluble Cd and decreased ph of supernatant solutions. This indicates that under the range of ionic strength used in this study, stability of nanoparticles as well as Cd adsorption to nano-tio 2 was not influenced. Our observations showed that nano-tio 2 can remove soluble cadmium from soil suspension in the presence of both index cations. Furthermore, as the range of ionic strength applied in this study coincides with and also covers the range of most normal soils, it may be concluded that influence of nano-tio 2 on Cd-DTPA is mainly depended on type of index cation rather than electrolyte concentration. 425
4 ICOBTE 2015 FUKUOKA ABSTRACT BOOK 13th International Conference on the Biogeochemistry of Trace Elements New Frontiers in Trace Elements Research and Management July 12-16, 2015 Fukuoka International Congress Center Fukuoka, Japan Masami Nanzyo, Takashi Someya and Shinjiro Kanazawa Editors Local Organizing Committee (Japan) The International Society of Trace Element Biogeochemistry (ISTEB) Co-hosted by the Japanese Society of Soil Science and Plant Nutrition (JSSSPN) and International Union of Soil Sciences (IUSS)
5 13 th ICOBTE Conference Organization Chair Shinjiro Kanazawa Kyushu University Vice-Chair Toru Fujiwara University of Tokyo Vice-Chair Yoshizumi Ishino Kyushu University Secretariat-in-Chief Takashi Someya Saga University Local organizing committee (Japan) Senior Conference Advisors Mitsuo Chino Toshiaki Tadano Takuya Marumoto Hiroshi Saito Nobuo Tsuchida Takashi Kosaki Tokyo University Hokkaido University Yamaguchi University Nagasaki University Tokyo Medical and Dental University Tokyo Metropolitan University Committee Members Keiko Aoshima Yusuke Arakawa Tomohito Arao Susumu Asakawa Haruyuki Atomi Koichi Fujie Naoki Harada Tomoyoshi Hashimoto Ryusuke Hatano Hiroyuki Hattori Kazuyuki Inubushi Sonoko Ishino Kozo Iwasaki Hagino Hospital National Agriculture and Food Research Organization National Institute for Agro-Environmental Sciences Nagoya University Kyoto University Yokohama National University Niigata University National Agriculture and Food Research Organization Hokkaido University Akita Prefectural University Chiba University Kyushu University Kochi University 4
6 F 244 SS SS SS7-6 Q. H. Fan 421 SS12-8 M. Farid 129 SS10-28 M. P. Faucon 369 SS4-17 B. Fayard 158 SS13-10 A. Faz 414 SS S-9, P S-9, P-19 X. Feng 113 TS3-3 Plenary Lecture 3 S. Fendorf 464 SS2-9 A. Fernandez-Martinez 026 SS13-1 L. Février 440 SS SS7-13 H. A. Fileto-Pérez 486 SS1-20 S. Fiore 326 SS4-12 S. Fischer 269 SS3-14 D. E. Fletcher 523 TS, P-22 M. P. F. Fontes 464 SS2-9 A. Fotovat 089 S-13, P-3 J. Foulon 509 SS9-1 M. Francová 487 S-6, P-2 A. E. Franks 207 SS1-4 S. Fränzle 214 TS2-6 S. Frelon 455 SS7-13 H. Frérot 349 SS3-11 T. Fresno 357 SS9-6 W. Friesl-Hanl 178 SS9-16 T. Frohne 203 SS1-2 E. Frossard 448 SS3-3 S. Fuji 514 S-5, P-13 H. Fujihara 252 SS5-7 K. Fujii 403 S-10, P-8 M. Fujii 314 SS3-7 S. Fujimaki 152 SS S-3, P SS10-14 S. Fujimura 076 S-5, P S-5, P-8 T. Fujino 513 S-5, P-27 H. Fujishiro 056 SS8-6 H. Fujita 184 SS7-11 K. Fujiwara 123 S-5, P-14 T. Fujiwara 285 SS10-4 T. Fukai 328 S-10, P-2 M. Fukuda 381 SS S-5, P-23 S. Fukuoka 382 SS3-2 H. Funaki 435 S-5, P-15 F. Furlan 498 S-3, P-19 J. Furukawa 243 S-5, P SS5-16 M. Furuya 385 S-12, P-4 G M. Gabarrón 416 S-9, P-17 L. Gabon 182 SS9-20 S. Galaup 371 SS2-20 M. Galende 178 SS9-16 W. Galland 178 SS SS9-20 Ch. D. Ganzha 125 SS7-18 H. Gao 194 TS3-2 L. Garbinski 044 SS10-10 C. Garbisu 280 SS S-9, P-8 L. Garcia-Sanchez 244 SS SS5-23 B. E. García-Caballero 486 SS1-20 G. J. Gareth 439 TS, P-20 C. Garnier 248 SS SS4-3 J. Garnier-Laplace 474 SS5-22 H. Gattringer 333 SS9-10 A. Gauthier 364 SS4-4 C. Germain 489 SS11-15 A. Ghafoor 147 S-4, P-7 A. Gianoncelli 325 SS12-9 R. Gilbin 440 SS SS7-13 R. Gjelsvik 525 SS5-26 R. N. Glud 305 SS1-3 M. Goderniaux 126 SS3-13 C. Godé 349 SS3-11 V. Golosov 028 SS SS5-20 M. A. Gonze 365 SS SS
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